MODELING THE BUILDUP AND WASHOFF OF POLLUTANTS ON URBAN WATERSHEDS1

ABSTRACT: A model for urban stormwater quality was developed in this study. The basis for the model is the process by which pollutants build up on the watershed surface. For the wet climate of the study site, it was assumed that there exists an interval of time over which the pollutant buildup equals the pollutant washoff (no accumulation of pollutant). The buildup model was represented by a linear function of the antecedent dry time. The buildup function was then linked with a pollutant washoff model represented by a power function of the storm runoff volume. Various time intervals for no net accumulation were tested to calibrate the model. The model was calibrated to observed data for two small urban basins in Baton Rouge, Louisiana, and model results were used to analyze the behavior of phosphorus concentrations in storm runoff from these basins over a long period of time.     

WASTE LOADINGS FROM A FRESHWATER ATLANTIC SALMON FARM IN SCOTLAND1

ABSTRACT: Recent studies suggest that waste generation from the freshwater phase of Atlantic salmon (Salmo salar L.) production varies considerably on an annual basis. A fish farm on the West Coast of Scotland was visited regularly during a two-year period to determine inflow and outflow water quality. Waste output budgets of suspended solids (SS), biochemical oxygen demand (BOD), total nitrogen (TN), total phosphorus (TP), total ammonia nitrogen (TAN = NH₃+NH₄⁺), dissolved reactive phosphorus (DRP) and total phosphorus (TP) were produced. The annual waste loadings obtained were 71 kg TN t fish^?1 yr^?1 (one year of data only), 10.9–11.1 kg TP t fish^?1 yr^?1, 1.2–2.1 kg DRP t fish^?1 yr^?1, 422–485 kg BOD₅ t fish^?1 yr^?1, 327–337 kg SS t fish^?1 yr^?1, and 30–35 kg TAN-N t fish^?1 yr^?1. Simple linear regression models relating waste parameter production to water temperature and feeding regime were developed. When compared to existing data for other salmonid production systems, greater ranges of daily waste loadings were observed. Wide variations in concentrations of these parameters during a daily cycle were also observed, suggesting that mass balance estimates of waste production will provide more robust estimates of waste output than frequent monitoring of outflow water quality.     

TOPHAZOP: a knowledge-based software tool for conducting HAZOP in a rapid, efficient yet inexpensive manner

Hazard and operability (HAZOP) studies constitute an essential step in the risk analysis of any chemical process industry and involve systematic identification of every conceivable abnormal process deviation, its causes and abnormal consequences. These authors have recently proposed optHAZOP as an alternative procedure for conducting HAZOP studies in a shorter span of time than taken by conventional HAZOP procedure, with greater accuracy and effectiveness [Khan, F. I. and Abassi, S. A., optHAZOP. An effective and efficient technique for hazard identification and assessment Journal of Loss Prevention in the Process Industries, 1997, 10, 191–204]. optHAZOP consists of several steps, the most crucial one requires use of a knowledge-based software tool which would significantly reduce the requirement of expert man-hours and speed up the work of the study team. TOPHAZOP (Tool for OPTmizing HAZOP) has been developed to fulfil this need.

The TOPHAZOP knowledge-base consists of two main branches: process-specific and general. The TOPHAZOP framework allows these two branches to interact during the analysis to address the process-specific aspects of HAZOP analysis while maintaining the generality of the system. The system is open-ended and modular in structure to make easy implementation and/or expansion of knowledge. The important features of TOPHAZOP and its performance on an industrial case study are described.     

Prevention of musculoskeletal complaints in nursing: Aims, approach and content of an ergonomic-educational programme

In 1992 a comprehensive health-promotion project was initiated in seven nursing-homes in the Netherlands. This project was designed to implement an ergonomic-educational programme, with the intention of reducing physical workload and to bring about safe working in order to prevent work-related musculoskeletal complaints. After a period of external support, employees of the nursing-homes should be able to proceed with the programme independently. In this paper the content of the programme and its underlying strategies and theories are described. So far, the programme has got off to a good start in all the nursing-homes. Positive effects of the programme could be demonstrated and guidelines and protocols for safe working were introduced. However, it is as yet too early for definitive conclusions to be drawn regarding the aspect of continuity.     

Thermal and mechanical properties of poly(lactic Acid) and poly(ethylene/butylene Succinate) blends

In this study, blends of poly (lactic acid) (PLA) with poly(ethylene/butylene succinate) (Bionolle) have been investigated for their thermal and mechanical properties as a function of the concentration of Bionolle. Differential scanning calorimetry (DSC), dynamic mechanical analysis (DMA), and tensile tests were used to characterize the blends. From the results of the DMA and DSC, it was found that this blend system was not miscible within the compositions studied. DSC results showed that adding Bionolle aids in crystallization of PLA. It was observed that increasing the Bionolle concentration led to a slight increase in the strain-at-break of the blends but a decrease in the Young’s modulus and ultimate tensile strength. Biaxially oriented films showed an increase in tensile strength, modulus, and strain-at-break.     

Pressure- volume- temperature relationships of soy protein isolate/starch plastic

The use of pressure-volume-temperature (PVT) studies in processing of a biodegradable plastic composition made from soy protein isolate and corn starch is described. The ability of PVT measurements to predict the combined effects of pressure, volume, and temperature effects is demonstrated. The results show that the PVT relations of the plastic can be predicted by using a regression analysis similar to the Tait equations of state. A change in slope of the PVT curves was observed at around 80‡C, which is ascribed to the glass-transition process of the plastic. Evidence of onset of thermal degradation of the plastic was observed at ca. 160‡C under 0 to 200 MPa isobaric pressure. This thermal degradation precluded determination of the crystal melting point of the plastic.     

Design parameters for fixed bed reactors of activated carbon developed from fertilizer waste for the removal of some heavy metal ions

Activated carbon, developed from fertilizer waste, has been used for the removal of Hg²⁺, Cr⁶⁺, Pb²⁺, and Cu²⁺. Mass transfer kinetic approach has been successfully applied for the determination of various parameters necessary for designing a fixed-bed absorber. Parameters selected are the length of the (PAZ) primary adsorption zone (δ), total time involved for the establishment of primary adsorption zone (t_x), mass rate of flow to the absorber (F_m), time for primary adsorption zone to move down its length (t_δ), amount of adsorbate adsorbed in PAZ from breakpoint to exhaustion (M_s), fractional capacity (f), time of initial formation of PAZ (t_f) and per cent saturation of column at break point. Chemical regeneration has been achieved with 1 M HNO₃.     

Getting the ‘pulse’ of your employees: the use of cardiovascular research in better understanding behavior in organizations

Cardiovascular disease has severe consequences for both individual betterment and organizational health. Yet, organization‐based cardiovascular research remains quite limited. This commentary addresses this void by integrating research dating from the famous Hawthorne experiments with current medical science. It then suggests future organizational research on cardiovascular health and recommends use of specific composite cardiovascular measures to advance our understanding of the organizational implications of cardiovascular disease. Copyright © 2006 John Wiley & Sons, Ltd.