串联毛细管柱气相色谱分析石脑油中微量甲基叔丁基醚

应用Agilent 6890 plus 气相色谱仪(配有FID),把一根50 m×0.25 mm×0.5 μm PEG-20M毛细管色谱柱和一根100 m×0.25 mm×0.5 μm HP-1毛细管色谱柱串接,使得甲基叔丁基醚(MTBE)能和石脑油中其它组分完全分离,解决了石脑油中微量MTBE的测定难题.方法的标准偏差是0.20%,回收率为100%.     

矿区可持续发展能力建设中生态环境管理研究

实现矿区的可持续发展有赖于发展模式的转变,转变传统的生态环境管理的基本观念,提出要完善和优化矿区的生态环境管理体制,建立矿区"环境-资源-经济"信息管理系统和生态环境综合分析决策模型,寓经济发展于环境管理中,寓环境管理建设于经济发展中,寓矿区发展于环境和经济的协调发展之中,推进矿区持续发展,为矿区环境保护和经济发展建立一个和谐的可持续发展模式.     

橡胶工业化学品安全防护

随着对环境、安全和健康意识的加强,人们对于工作场所的安全卫生问题已引起极大的关注.众所周知,橡胶工业对工人的健康存在较大的危害,这主要是在橡胶工业中所采用的大量化学品导致的.本文将就橡胶工业化学品的危害和安全防护的问题进行简要介绍和探讨.     

新型烟气净化装置(LAPD)除尘效率的试验研究

通过单因素试验研究了新型烟气净化装置(LAPD)运行参数变化对除尘效率的影响,结果表明:LAPD的除尘效率随着溢流口液面高度的增大而提高;随着环形管高度的增大而先提高后下降。通过正交试验,建立了LAPD的最佳工况参数标准。     

吸附法油气回收装置中真空泵的安装与调试

简要介绍了济南分公司油气回收装置、真空泵的工作原理以及安装与调试应注意的问题.     

齐鲁乙烯开工锅炉试烧燃料气改造后的降耗减排分析

齐鲁分公司烯烃厂动力开工锅炉是齐鲁分公司燃料油的耗能大户,也是降耗增效和减排的重点.目前,国内市场燃料气(包括焦化干气和少量天然气)价格较为便宜,而且燃烧燃料气能有效降低大气污染物排放.因此完成开工锅炉A、B炉试烧燃料气改造后,可以取得良好经济效益和环保效益.     

Anatomical localization and stereoisomeric composition of <Emphasis Type="Italic">Tribolium castaneum</Emphasis> aggregation pheromones

We report that the abdominal epidermis and associated tissues are the predominant sources of male-produced pheromones in the red flour beetle, Tribolium castaneum and, for the first time, describe the stereoisomeric composition of the natural blend of isomers of the aggregation pheromone 4,8-dimethyldecanal (DMD) in this important pest species. Quantitative analyses via gas chromatography–mass spectrometry showed that the average amount of DMD released daily by single feeding males of T. castaneum was 878 ± 72 ng (SE). Analysis of different body parts identified the abdominal epidermis as the major source of aggregation pheromone; the thorax was a minor source, while no DMD was detectable in the head. No internal organs or obvious male-specific glands were associated with pheromone deposition. Complete separation of all four stereoisomers of DMD was achieved following oxidation to the corresponding acid, derivatization with (1R, 2R)- and (1S, 2S)-2-(anthracene-2,3-dicarboximido)cyclohexanol to diastereomeric esters, and their separation on reversed-phase high-performance liquid chromatography at −54°C. Analysis of the hexane eluate from Porapak-Q-collected volatiles from feeding males revealed the presence of all four isomers (4R,8R)/(4R,8S)/(4S,8R)/(4S,8S) at a ratio of approximately 4:4:1:1. A walking orientation bioassay in a wind tunnel with various blends of the four synthetic isomers further indicated that the attractive potency of the reconstituted natural blend of 4:4:1:1 was equivalent to that of the natural pheromone and greater than that of the 1:1 blend of (4R,8R)/(4R,8S) used in commercial lures.     

A new captorhinid reptile, Gansurhinus qingtoushanensis, gen. et sp. nov., from the Permian of China

Captorhinids, a clade of Paleozoic reptiles, are represented by a rich fossil record that extends from the Late Carboniferous into the Late Permian. Representatives of this clade dispersed from the equatorial regions of Laurasia into the temperate regions of Pangea during the Middle and Late Permian. This rich fossil record shows that there was an evolutionary trend from faunivorous to omnivorous and herbivorous feeding habits within this clade. The discovery of well-preserved captorhinid materials in the Middle Permian of China allows us to determine that the new taxon, Gansurhinus qingtoushanensis, gen. et sp. nov, is a member of Moradisaurinae, a clade of captorhinids with multiple tooth rows arranged in parallel. The presence of this moradisaurine in the Middle Permian of south central Asia leads us to suggest that paleogeographic changes during the Permian, with part of what is today China becoming a large peninsula of Pangea, allowed these early reptiles as well as other terrestrial vertebrates to extend their geographic ranges to this region of the Late Paleozoic supercontinent.     

长三角区域城市间一次污染跨界影响

长三角城市群作为我国三大经济圈之一,高强度的能源消耗致使区域大气污染问题十分突出.为了定量弄清城市之间一次污染传输情况,以长三角15个城市的污染排放清单、MM5气象场为基础,利用CALPUFF空气质量模型,模拟测算了长三角区域内城市间一次污染跨界输送影响.结果显示,环太湖地区的上海、苏州、无锡和常州等地由于自身排放强度...     

邻苯二甲酸二丁酯暴露对雄性大鼠生精细胞功能影响

观察不同剂量的邻苯二甲酸二丁酯(DBP)对成年大鼠生精细胞损伤、端粒酶和端粒酶逆转录酶(TERT)表达影响.对40只健康雄性SD大鼠随机分成4组,分别为500mg·kg-1·d-1、250mg·kg-1·d-1、50mg·kg-1·d-1 3个染毒组和1个对照组,灌胃量为5mL·kg-1体重,灌胃法连续给药6周.对体重...