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101.
102.
树脂吸附-Fenton试剂氧化法处理水杨醛生产废水 总被引:1,自引:0,他引:1
采用树脂吸附-Fenton试剂氧化法处理水杨醛生产废水。XF-01树脂和XF-02树脂静态吸附水杨醛生产废水时,COD去除率均在85%以上,挥发酚去除率均高于90%。XF-02树脂对水杨醛生产废水的处理效果更佳。动态吸附随废水流量增大,吸附出水的COD和挥发酚质量浓度均增加。适宜的废水流量为15BV,树脂的最佳脱附温度为80℃。在连续4批的吸附-脱附实验中,吸附出水的平均COD约为1200mg/L,平均挥发酚质量浓度小于10mg/L。在Fenton试剂氧化中,铁屑和铁粉的催化效果差别很小,都好于FeSO4·7H2O。以铁屑为催化剂、H2O2溶液加入量为1%时,氧化出水的COD小于150mg/L,挥发酚质量浓度小于0.5mg/L。 相似文献
103.
Alwyn L Furtado Brian N Craig Joshua T Chard Victor A Zaloom Hsing-Wei Chu 《International journal of occupational safety and ergonomics》2007,13(3):227-239
Heat stress on workers working outdoors in the power industry may result in fatigue and deterioration in task performance. This research collected and analyzed data on task performance of workers working indoors and outdoors with and without a cooling suit. The task performance was compared on the basis of heart rate, oxygen consumption, tympanic temperature, subjective responses, productivity, and error rates. Based on One-Way Analysis Of Variance (ANOVA) results, a significantly lower estimated working oxygen consumption was observed (p < .001) when the cooling suit was worn. The productivity was higher while workers wore the cooling suit as compared to no cooling suit (p = .011) whereas the error rates were significantly lower (p < .001). Also a significantly lower self-reported discomfort was observed in the neck and shoulders while working wearing the cooling suit (p = .004). This study concluded that wearing a cooling suit while working outdoors was associated with physiological benefits as well as improved task performance of the study participants. 相似文献
104.
Variations in the chemical properties of landfill leachate 总被引:4,自引:0,他引:4
Landfill leachates were collected and their chemical properties analyzed once every two months over a ten-month period from
the Gin Drinkers' Bay (GDB) and Junk Bay (JB) landfills. The contents of solids, and inorganic and organic components fluctuated
considerably with time. In general, the chemical properties of the two leachates correlated negatively (P<0.05) with the amounts of rainfall prior to the sampling periods. However, magnesium and pH of the leachates remained relatively
constant with respect to sampling time. The JB leachate contained higher average contents of solids and inorganic and organic
matter than those of GDB with the exception of trace metals. Trace metals were present in the two leachates in trace quantities
(<1.0 mg/liter). The concentrations of average ammoniacal nitrogen were 1040 and 549 mg/liter, while chemical oxygen demand
(COD) values were 767 and 695 mg/liter for JB and GDB leachates, respectively. These results suggest that the leachates need
further treatment before they can be discharged to the coastal waters. 相似文献
105.
According to the practice researching and formulating “The Oil Spill Contingency Plan of south Chinese Sea”,this paper analyses and discusses the structure,functions and main contents of marine oil spill contingency planning,programs the organizing and commanding system and emergency response system,and advances the planning and researching method to coordinate comprehensively and to design practically the detailed emergency response steps until to formulate the ease operating programs for the plan implementation(PPI) and the PPI to apply high-techniques supporting emergency administrations and response. 相似文献
106.
利用环境容量进行环境影响评价 总被引:1,自引:0,他引:1
为有效地控制环境污染,目前全国在环境管理过程中已经逐步实施了污染物总量控制,但是在环境影响评价中,却仍然是采用传统的评价方法——浓度控制法,即首先预测出拟建工程对环境所产生的污染物浓度贡献,然后与评价标准比对,如果超出了评价标准,就将污染浓度削减到评价标准之下即可。显然,这是不符合总量控制原则的。为此笔者提出了利用环境容量进行环境影响评价,经验证该评价方法,既符合总量控制又具有简单易行、操作性强、准确可靠等许多优点。 相似文献
107.
Tris(4-chlorophenyl)methanol (TCPM) is a global contaminant of unknown origin that is structurally related to the endocrine modulating pesticides 1,1,1-trichloro-2,2-bis(p-chlorophenyl)ethane (DDT) and Dicofol. Therefore, the potential reproductive toxic effects of TCPM were investigated in sexually mature male Sprague Dawley rats (n = 20) treated with 1.0, 10.0 or 100 ppm of TCPM mixed in the diet for 28 days. The calculated TCPM intake was 0.0, 0.1, 1.2 and 12.4 mg/kg/day, respectively. Serum concentrations of follicle stimulating hormone (FSH) in terminal blood samples were significantly (P < 0.02) elevated in the highest dose group compared to the controls. In contrast, dietary exposure to TCPM had no effect on circulating levels of luteinizing hormone (LH), testosterone (T) and the T/LH ratio. Incubation of MCF-7 cells with increasing concentrations of TCPM failed to either induce proliferation or to block the proliferative effect induced by estradiol indicating that TCPM is neither estrogenic or anti-estrogenic. Relative binding affinity studies using androgen receptors from the prostate revealed that TCPM has a binding affinity comparable to 1,1-dichloro-2,2-bis(p-chlorophenyl)ethylene (p,p'-DDE), the principle metabolite of DDT. In addition, the calculated Ki (0.62 microM) for TCPM is lower than the reported Ki's for the antiandrogenic pesticides p,p'-DDE and vinclozolin. Although TCPM binds with the androgen receptor in vitro, the absence of both an effect on serum T levels and morphological changes in the testis suggests that the mechanism of action for elevated FSH levels seen in vivo may not involve an antiandrogenic effect of TCPM at the dose level used in this study. The no adverse effect level for reproductive effects of TCPM is 10 ppm which is equivalent to a calculated intake of 1.2 mg/kg/day. 相似文献
108.
Sulphoxide, sulphone and mercapturic acid derivatives of isomeric tetrachlorobenzene were synthesized. These compounds and isomers of tetrachlorophenol were characterized by spectroscopic and chromatographic methods. 相似文献
109.
Accumulation and tissue distribution of selected polychlorinated biphenyl congeners in chickens 总被引:1,自引:0,他引:1
Maervoet J Chu SG De Vos S Covaci A Voorspoels S De Schrijver R Schepens P 《Chemosphere》2004,57(1):61-66
During one to three consecutive periods of 2 weeks, broiler chickens (n = 108) received test dies to which different amount of PCBs (7 congeners) were added. The relationship between exposure time and accumulation of individual congeners in different chicken tissues, such as breast, thigh and abdominal fat tissue, was observed. In all tissues, the vast majority of the PCB accumulation occurred during the first 2 weeks of exposures. After that, PCB concentrations only increased in the abdominal fat tissue of the animals. The individual PCBs were distributed differently in the various tissues. While CBs 28, 118, 138, 153 and 180 accumulated in the chickens, CBs 52 and 101 were metabolized, but no methyl sulphone metabolites of these congeners could be detected. Our results provide information on the absorption, tissue distribution and biotransformation of the individual PCB congeners and confirm the structure-activity relationships for metabolism of PCBs in birds, which are different from those in fish or mammalian species. 相似文献
110.
Effects of leachate recirculation on biogas production from landfill co-disposal of municipal solid waste,sewage sludge and marine sediment 总被引:9,自引:0,他引:9
Leachate recirculation is an emerging technology associated with the management of landfill. The impact of leachate recirculation on the co-disposal of three major wastes (municipal solid waste, sewage sludge and sediment dredgings) was investigated using a laboratory column study. Chemical parameters (pH, COD, ammoniacal-N, total-P) and gas production (total gas volume, production rates and concentrations of CH4 and CO2) were monitored for 11 weeks. Leachate recirculation reduced waste-stabilization time and was effective in enhancing gas production and improving leachate quality, especially in terms of COD. The results also indicated that leachate recirculation could maximize the efficiency and waste volume reduction rate of landfill sites. 相似文献