吡虫啉的生物效应研究

应用不同的生物材料对新型杀虫剂的生态效应进行了研究，吡虫啉对泽蛙蝌蚪，黑斑蛙蝌蚪及青Jiang鱼的急性毒性表明，吡虫啉属于低毒农药，蚕豆根尖微核试验结果呈阴性，揭示其无致突变效应。     

污水处理厂鼓风机控制系统优化改造

绍兴污水处理厂二期工程于2003年投运,污水处理核心部分--好氧系统采用了8台高压鼓风机供气,鼓风机设置就地控制系统和远程控制系统,通过DP总线电缆连接,在运行过程中控制系统出现了一些问题,主要对二期工程鼓风机的使用过程中产生问题进行分析,并对控制系统、控制柜、雷电影响等方面进行了改造,从而确保了鼓风机正常运行.     

对城乡交界处环境与健康问题的思考

城乡交界处是现代农业的重要组成部分。它可以解决城市人口的食物供应问题，增加就业机会，改善城市生态。但是城乡交界处同时也会带来一些新老环境问题，如果没有正确管理和合理的规划，它也会给城市环境造成危害，进而影响人类的健康。本文结合都市农业对环境和人类健康存在的潜在危害做了具体的分析，并提出一些切实可行的管理和控制措施。     

铝质固体废料制取聚合氯化铝及絮凝脱色性能

采用酸溶一步法利用三种铝质固体废料制取了聚合氯化铝。实验表明 :该法生产聚合氯化铝 ,工艺可行 ,产品主要指标满足国家标准 (GB1 5892 95)的要求 ,所制的PAC对模拟染料废水的絮凝效果与用AlCl3.6H2 O制成的聚合氯化铝的相当。     

改进Fenton体系处理蒽醌染料的研究

以活性艳蓝KN-R作为研究对象,用UV/Fenton和solar/Fenton/草酸(H2C O4)体系对其进行处理,对反应体系的影响因素作综合的评价.得到处理蒽醌染料废水的最佳条件:dye(活性艳蓝KN-R):Fe2 :H2O2:H2C2O4为5:1:15:1.5,pH为3.0,反应时间为40 min.在最佳条件下,solar/Fenton/H2C2O4体系脱色率达到100%,COD和TOC去除率分别达到87%和66%以上.改进的Fenton方法能使难降解有机染料迅速脱色,矿化程度较高.并对此体系处理活性艳蓝KN-R废水的脱色过程进行动力学模拟,得到此反应为拟一级反应.     

水泥立窑湿法收尘技术研究的新进展

水泥立窑烟气由于其工况波动大、高温、高湿和高粘性等特点,处理起来难度较大。普通的喷雾技术不能确保达标排放。针对目前徐州地区及全国处理立窑粉尘的现状,有针对性地研究了惯性除尘及文丘里、水浴和塔技术。经过初步实践,某水泥立窑粉尘经三级处理后,排放的粉尘浓度低于150mg／m^3,除尘效率达到98％以上,基本达到环保排放标准;无二次污染,该系统处理排放出的泥浆全部回收用于生产,系统用水可循环使用。为水泥立窑粉尘的治理及研究提供了借鉴。     

城市排水系统管理创新模式的研究

随着排水行业逐步走向市场化,传统的排水系统管理模式已经成为制约排水行业发展的最突出问题。绍兴市排水管理有限公司通过管理模式创新,创建了国内同行中独一无二的以泵站管理标准化为目标的“无人值守,有人巡视”的现代化排水运行管理模式,取得了显著的社会效益和经济效益,为国内排水行业现代化管理树立了典范。     

Effects of earthworm activity on fertility and heavy metal bioavailability in sewage sludge

The potential for using earthworms (Eisenia fetida) to improve fertility and reduce copper and cadmium availability in sewage sludge was tested by laboratory incubation experiments. Results comparing sewage sludge with and without earthworm treatment showed that earthworm activity decreased the contents of organic matter, total nitrogen, but increased the contents of available nitrogen and phosphorus and had no significant effect on the contents of total phosphorus, total potassium and available potassium. After incubation of the sewage sludge with earthworms for 60 days, the contents of Cu and Cd in the earthworms increased with the increase of additional Cu up to 250 mg kg(-1) and Cd up to 10 mg kg(-1). Bioconcentration factors (BCF) were higher than 1 only for Cd when the addition rate was lower than 5 mg kg(-1), which indicates that the earthworms can only accumulate Cd when the concentration of Cd is low in sewage sludge. Bioavailability of Cd and Cu was evaluated by applying sewage sludge with and without earthworm treatment to soil and then growing cabbage plants. The results showed that earthworm treatment increased the biomass of cabbage and decreased the bioaccumulation of Cd and Cu in the cabbage plants.     

Temporal variations and source apportionment of volatile organic compounds at an urban site in Shijiazhuang, China

Shijiazhuang, the city with the worst air quality in China, is suffering from severe ozone pollution in summer. As the key precursors of ozone generation, it is necessary to control the Volatile Organic Compounds (VOCs) pollution. To have a better understanding of the pollution status and source contribution, the concentrations of 117 ambient VOCs were analyzed from April to August 2018 in an urban site in Shijiazhuang. Results showed that the monthly average concentration of total VOCs was 66.27 ppbv, in which, the oxygenated VOCs (37.89%), alkanes (33.89%), and halogenated hydrocarbons (13.31%) were the main composite on. Eight major sources were identified using Positive Matrix Factorization modeling with an accurate VOCs emission inventory as inter-complementary methods revealed that the petrochemical industry (26.24%), other industrial sources (15.19%), and traffic source (12.24%) were the major sources for ambient VOCs in Shijiazhuang. The spatial distributions of major industrial activities emissions were identified by using geographic information statistics system, which illustrated the VOCs was mainly from the north and southeast of Shijiazhuang. The inverse trajectory analysis using Hybrid Single-Particle Lagrangian Integrated Trajectory (HYSPLIT) and Potential Source Contribution Function (PSCF) clearly demonstrated the features of pollutant transport to Shijiazhuang. These findings can provide references for local governments regarding control strategies to reduce VOCs emissions.     

磁性共价有机框架的制备方法研究

磁性共价有机框架（magnetic covalent organic framework,MCOFs）是一种新型多孔结晶有机框架材料,由于其结合了磁性纳米颗粒和共价有机框架（covalent organic frameworks,COFs）的优点,具有比表面积大、热稳定性和化学稳定性良好、饱和磁化强度高等特点,能够快速实现污染物与溶液的分离,弥补了COFs难以分离和回收的缺点,因此在磁性固相萃取、生物检测、传感等方面具有巨大的潜在应用.然而关于MCOFs制备方法的文章鲜见报道,其制备方法根据磁性纳米颗粒与COFs不同的连接形式而不尽相同,根据2011—2019年关于MCOFs的重要文献,综述了目前MCOFs的制备方法,包括包覆法、单体聚合法及原位合成法等,指出了不同制备方法的优缺点,同时探讨了MCOFs今后的发展方向和潜在应用,希望能够为MCOFs研究提供理论依据.包覆法制备条件较温和,保存了磁性纳米颗粒的完整性,是最为广泛应用的一种策略方法;单体聚合法操作简单,但制备条件苛刻,可控性不强;原位合成法制备MCOFs更多依赖于单体聚合法制备的共价三嗪骨架,需要不断开发基于其他类型COFs的MCOFs制备条件.今后MCOFs的制备方法应从材料设计多样性、应用广泛性等方面进行考虑,并向有望实现大规模工业应用方面发展.