羧酸盐型双子表面活性剂的合成及性能研究

以月桂酰氯、乙二胺与丁二酸酐为原料合成了一种羧酸盐型双子(gemini)表面活性剂。采用IR、1 HNMR对中间产物和目标产物进行结构表征,并考察了合成所得羧酸盐型gemini表面活性剂的表面活性。结果表明:合成产物即为目标产物。合成产物的临界胶束浓度为0.027mmol/L,比普通单链表面活性剂低2～3个数量级,表面张力最低可降至29.5mN/m。     

纳米材料对藻细胞毒性效应及致毒机理

纳米材料因其独特的性质被广泛应用于生物医疗、光学工程、催化等领域。随着纳米材料的生产量逐年增大,越来越多的纳米粒子被释放到水生生态环境中,其生态毒性效应影响也备受人们的关注。本文根据纳米材料的分类总结了不同种类纳米材料对水生生态系统的初级生产者藻类的毒性效应,归纳了纳米材料影响藻类毒性大小的主要因素,如纳米材料的物理化学性质、水体性质和藻种等,并探讨了纳米材料对藻类的致毒机理,如金属离子溶出、氧化损伤和遮光效应等,最后总结展望了纳米毒理学研究的发展方向,以期为纳米材料对藻类的毒性研究提供一定的理论依据。     

济南市土壤中酞酸酯的分析与分布

本文对济南市土壤中酞酸酯污染的重点地区进行了比较详细的研究，初步掌握了酞酸酯在土壤中分布状况及分布规律。     

A Screening Test for the Determination of Ethylene Sensitivity

Ethephon, which releases ethylene within plant tissues after application, was chosen to perform assessments of the relative sensitivity of crops to ethylene and to determine which stages of plant development were most sensitive. The species chosen were: barley, wheat, oats, canola and field pea, all of which are important crops in the province of Alberta, Canada. Plants were treated with ethephon at one of 7 different stages. Plants were assessed for their vegetative and reproductive growth, including height, biomass, yield and seed quality. Visual symptoms were photographed and documented to compare them with symptoms caused by ethylene applied as a gas. It was concluded that in barley, wheat and canola the late vegetative and early reproductive stages were most sensitive, at least when sensitivity was defined as reductions in yield and quality. As for field pea, ethephon had no effect on yield but did cause increased numbers of pods, which in certain conditions could lead to increased yields. Significant effects on vegetative growth were only observed in the early vegetative stages of development but with no effects on yield. The screening protocol successfully identified sensitive cultivars and growth stages for further investigation of the effects of ethylene exposure.     

pH值对凯氏蒸馏法氨氮检出量的影响分析研究

土壤、肥料中的氨氮测定常用2mol·L^-1KC浸提一蒸馏法一酸滴定的方法进行测定,其中蒸馏是最关键和最重要的一个环节。以污泥堆肥样品为例,利用统计学原理,研究了汽提蒸馏过程中pH对氨氮检出量的影响。结果显示：pH值在6．5—11．0范围内与氨氮的检出系数是显著的正相关关系（相关系数r=0．9891）;回归方程在0．05的水平下是非常显著的,拟合度很好。进一步做残差和预测分析可以得出：pH值在6．5～10．0范围内,预测值和测定值的符合度更好。     

中日农村环境管理对比及对中国的启示

日本与我国在历史上同属传统的东亚小农经济国家,在社会、经济、文化等方面的发展历程和存在的问题具有共通性。日本的农村生态环境管理随社会经济发展不断调整适应,政府也数次推动乡村振兴。对比研究中日两国农村环境管理及其背后的社会经济因素,虽然两国在农村环境管理上有相似性,但也有较大不同,我国不能完全照搬日本的农村环境管理体制机制,必须走一条适应我国国情的特色道路,循序渐进推进农业农村污染防治。在开展农村环保工作的具体举措上,日本也有较多可借鉴之处:一是以完善的法规政策体系保障农村环境管理;二是以精准的财政补贴支撑农村环境管理;三是以科学的规划和技术标准体系服务农村环境管理;四是以规范的行业和市场服务体系推动农村环境管理;五是以亲民务实的环境宣传教育助力农村环境管理。     

集中供热工程实施前后大气环境影响对比分析研究

采暖期的大气环境质量与供热方式息息相关,集中供热是提高我国环境空气质量的一种可行办法。以定西市临洮县集中供热项目为例,结合拟建项目的建设特点,利用环评软件——AERMOD预测模式分析实施集中供热工程前后以大气为主的环境影响的差异,用以说明集中供热工程的实施具有巨大的环境效益。分析表明:集中供热减少了SO2、NO X烟尘的排放量,对环境的改善将起到良好的作用。     

公路路网建设项目声环境影响评价研究

以甘肃省某市新区基础设施建设中的路网建设为例,根据公路路网的交通参数、道路地形地貌条件、路面设施等,利用导则推荐模式预测路网噪声贡献值。该新区路网中道路距离多在500m以上,不论道路平行还是相交,噪声影响以主干道为主,以次干道为辅,相互影响;根据路网噪声环境影响的特点,提出切实可行的声环境影响减缓措施。     

Nitrogen removal from landfill leachate via ex situ nitrification and sequential in situ denitrification

Ex situ nitrification and sequential in situ denitrification represents a novel approach to nitrogen management at landfills. Simultaneous ammonia and organics removal was achieved in a continuous stirred tank reactor (CSTR). The results showed that the maximum nitrogen loading rate (NLR) and the maximum organic loading rate (OLR) was 0.65 g N l^?1 d^?1 and 3.84 g COD l^?1 d^?1, respectively. The ammonia and chemical oxygen demand (COD) removal was over 99% and 57%, respectively. In the run of the CSTR, free ammonia (FA) inhibition and low dissolved oxygen (DO) were found to be key factors affecting nitrite accumulation. In situ denitrification was studied in a municipal solid waste (MSW) column by recalculating nitrified leachate from CSTR. The decomposition of MSW was accelerated by the recirculation of nitrified leachate. Complete reduction of total oxidized nitrogen (TON) was obtained with maximum TON loading of 28.6 g N t^?1 TS d^?1 and denitrification was the main reaction responsible. Additionally, methanogenesis inhibition was observed while TON loading was over 11.4 g N t^?1 TS d^?1 and the inhibition was enhanced with the increase of TON loading.     

调理剂对污泥中石油降解速率的影响

试验研究了添加不同调理剂及不同量调理剂对污泥中石油生物降解的影响。结果表明：添加调理剂可以显著地提高石油生物降解速率；几种调理剂之间比较，以木为最好，蛭石次之，稻草再次之。添加６％的调理剂，在室温下培养１２０ｄ，污泥中石油残留量减少了近７０％。