排序方式: 共有88条查询结果,搜索用时 656 毫秒
81.
采用水热法和溶胶凝胶法制备了新型FeTiO3/TiO2纳米异质结复合材料,并明确了最优的掺杂比例(0.5%).随后利用X射线衍射能谱(XRD)、紫外-可见漫反射光谱(UV-Vis DRS)、扫描电镜(SEM)和透射电镜(TEM)等手段对该复合材料进行表征,证实了其结晶度、吸光度随掺杂量的规律性变化.电镜照片显示,该复合材料具有蓬松多孔的微观结构,且晶格条纹清晰、分散度高,有利于光电子的传导.对苯的降解实验表明,相比于纯TiO2,该催化剂的气相可见光催化能力大幅提高,降解率提升了3倍,达到40%,而CO2生成量提升了5倍,超过300 ppm.同时,电化学测试和电子顺磁共振谱(ESR)等均证实,FeTiO3的窄能带能够提高TiO2的光响应,实现可见光激发;而二者的能带相互匹配,有助于转移光生载流子,实现电子-空穴的高效分离,进而其光生电子和自由基生成能力大幅增强,因此,表现出了较强、较稳定的光催化活性. 相似文献
82.
Chen Xingyu Chang Xiaoqiang Zhang Shuaichen Lu Sixian Yang Lan Sun Peng 《Environmental Chemistry Letters》2022,20(5):2773-2779
Environmental Chemistry Letters - Catalyst-free reactions employing renewable resources are needed for sustainable development. For example, biologically important β-keto sulfones have been... 相似文献
83.
Xiaoqiang Gong Jinbiao Li Scott X. Chang Qian Wu Zhengfeng An Chengpeng Huang Xiangyang Sun Suyan Li Hui Wang 《Frontiers of Environmental Science & Engineering》2022,16(3):39
84.
Philippe Vidon Pierre‐Andre Jacinthe Xiaoqiang Liu Katelin Fisher Matthew Baker 《Journal of the American Water Resources Association》2014,50(3):639-652
Little is known about the impact of agricultural legacy on subsurface biogeochemical processes in the years following restoration of riparian wetlands (WLs). More knowledge is also needed on the relative importance of seasons, precipitation events, and inputs of water and nutrients driving nitrogen (N), phosphorus (P), sulfur (S), and greenhouse gas (GHG) (N2O, CO2, CH4) dynamics in these systems. This investigation of a riparian zone comprising a restored WL area and a nonrestored well‐drained alluvium (AL) area in the United States Midwest revealed that despite successful hydrological restoration a decade earlier, biogeochemical conditions in the WL area remained less anoxic than in natural WLs, and not significantly different from those in the AL area. No significant differences in N, P, S, and C compound concentrations or fluxes were observed between the AL and WL areas. Over the duration of the study, nitrate (NO3?) and soluble reactive phosphorus appeared to be primarily driven by hillslope contributions. Ammonium (NH4+), sulfate (SO42?), and CO2 responded strongly to seasonal changes in biogeochemical conditions in the riparian zone, while N2O and CH4 fluxes were most influenced by large rewetting events. Overall, our results challenge overly simplistic assumptions derived from direct interpretation of redox thermodynamics, and show complex patterns of solutes and GHGs at the riparian zone scale. 相似文献
85.
Carbendazim, a systemic benzimidazole fungicide, is applied repeatedly to control of plant diseases including soilborne diseases, over a growing season. Studies were carried out under laboratory conditions to assess the effects of repeated carbendazim applications on its persistence and microbial community in soil. The results indicate that dissipation of carbendazim in soil was accelerated with its application frequency. The degradation rate constant of carbendazim was increased significantly from 0.074 d-1 to 0.79 d-1. The corresponding half-life was shorten markedly from 9.3 d to 0.9 d after four repeated applications. No significant inhibitory effect of carbendazim on soil microbial utilization of the carbon sources was observed after first treatment, but a slight increase in average well color development (AWCD) was shown after second, third, and fourth applications. It suggested that soil microorganisms become adapted to carbendazim after repeated application. Simpson and Shannon indexes of soil microbial community from carbendazim treated soil were also similar to those from the control soil, indicating that the richness and dominant character of soil microorganisms remain unchangeable after repeated application. However, after first, second, and third addition of carbendazim, McIntosh indexes on day 21 were significantly increased as compared with the control, suggesting that balance of soil microorganisms was altered due to the enrichment of the specific carbendazim-adapting strains in soil. 相似文献
86.
吸附材料在水中的分散性对于增加其与吸附质间相互作用,实现污染物的高效去除尤为重要.本文基于分子形态易于调控的石墨相氮化碳二维材料,通过简单的化学处理方法制备成高度分散于水中的溶胶吸附剂(M-C3N4-sol、U-C3N4-sol),通过透射电镜(TEM)、X射线衍射(XRD)、傅里叶变换红外光谱(FTIR)、X射线光电子能谱仪(XPS)、Zeta电位仪(Zeta Potential Analyzer)、比表面积及孔径分布仪(BET)等对其形貌、组成、结构进行了表征.结果表明,氮化碳溶胶呈现纳米级纤维状结构,在水中有着极佳的分散性.相较于原始氮化碳(g-C3N4),溶胶吸附剂对多种重金属离子的吸附去除能力得到大幅度提升,尤其是对Pb2+具有较高的吸附选择性.在298 K时,对Pb2+的吸附在1 min内即可达到平衡,快速吸附过程符合准二级动力学模型和Freundlich等温模型.吸附机理的研究表明,M-C3N4-sol对Pb2+的吸附是在静电引力、离子交换、氨基的表面络合和阳离子-π键的协同作用下完成的.吸附金属离子后,M-C3N4-sol发生脱稳形成易于实现固液分离的沉淀产物,对其进行稀硝酸脱附再生,吸附容量没有明显降低,表明其良好的循环使用性能. 相似文献
87.
Huang Huishen Liang Jun Tang Peng Yu Chuanxiang Fan Haoran Liao Qian Long Jinghua Pan Dongxiang Zeng Xiaoyun Liu Shun Huang Dongping Qiu Xiaoqiang 《Environmental science and pollution research international》2022,29(58):87170-87183
Environmental Science and Pollution Research - Bisphenols are endocrine disruptor chemicals that disrupt thyroid hormone homeostasis. However, evidence on the effects of bisphenol mixtures on... 相似文献
88.
Chen Jiehua Ye Ye Huang Dongping Pan Dongxiang Qiu Xiaoqiang Lei Lei Luo Xingxi Li Jinxiu Wu Kaili Xiao Suyang Liu Shun Zeng Xiaoyun 《Environmental science and pollution research international》2022,29(25):37543-37555
Environmental Science and Pollution Research - Pregnant women are vulnerable to certain environmental agents, one of which is aflatoxin. As one of the most popular aflatoxins, Aflatoxin B1 (AFB1)... 相似文献