土壤污染物的生态毒理效应和风险评估研究进展

环境生态风险评估（ERA）流程已经被纳入全球环境政策中,既用于规范新化学物质的授权和营销（前瞻性环境生态风险评估）,也用于评估潜在的污染场地（回顾性环境生态风险评估）。将土壤生态毒理学应用于风险评估,能阐明有毒物质对土壤生态系统中生命有机体的危害程度与范围。笔者主要介绍了应用评估因子法和物种敏感度分布法对基于效应数据进行的外推与估算,并综述了欧美等主要国家和地区的土壤生态风险评估框架、相关法律法规及其实施情况等,为中国开展土壤污染物生态毒理效应和风险评估等相关研究提供参考。     

饮用水源微生物快速检测技术的发展及应用

微生物是威胁饮用水安全的首要问题,水环境微生物快速检测技术的开发和应用是推动饮用水源微生物快速检测和水质安全预警技术发展的保障。随着对水质微生物污染快速检测和准确预警新要求的提出,水环境中微生物在线检测和预警技术得到了越来越多的开发和应用。笔者总结了水环境常见微生物检测方法和技术的发展,重点讨论了饮用水源微生物快速检测技术的发展和应用,根据各项技术的应用和推广使用程度,将其归纳为常用快速检测技术、潜在适用快速检测技术和新型快速检测技术等类别,并详细阐述了一些应用较广的技术,以期为构建水质微生物污染早期预警系统提供参考。     

Polystyrene nanoplastics affect growth and microcystin production of Microcystis aeruginosa

Nanoplastics are widely distributed in freshwater environments, but few studies have addressed their effects on freshwater algae, especially on harmful algae. In this study, the effects of polystyrene (PS) nanoplastics on Microcystis aeruginosa (M. aeruginosa) growth, as well as microcystin (MC) production and release, were investigated over the whole growth period. The results show that PS nanoplastics caused a dose-dependent inhibitory effect on M. aeruginosa growth and a dose-dependent increase in the aggregation rate peaking at 60.16% and 46.34%, respectively, when the PS nanoplastic concentration was 100 mg/L. This caused significant growth of M. aeruginosa with a specific growth rate up to 0.41 d^?1 (50 mg/L PS nanoplastics). After a brief period of rapid growth, the tested algal cells steadily grew. In addition, the increase in PS nanoplastics concentration promoted the production and release of MC. When the PS nanoplastic concentration was 100 mg/L, the content of the intracellular (intra-) and extracellular (extra-) MC increased to 199.1 and 166.5 μg/L, respectively, on day 26, which was 31.4% and 31.1% higher, respectively, than the control. Our results provide insights into the action mechanism of nanoplastics on harmful algae and the potential risks to freshwater environments.

     

好氧颗粒污泥处理青霉素废水研究

青霉素在其生产过中产生大量的废水,其COD值较高,生化性较差,成分复杂,微生物难以降解,其处理技术是世界性难题。文章采用以葡萄糖模拟废水培养的好氧颗粒污泥为接种体,经青霉素废水逐步驯化后,使其完全处理青霉素废水。实验结果表明,应用好氧颗粒污泥技术,处理青霉素废水,COD,NH3_N,TP去除率较高,具有很好的处理效果。     

Bioanalytical and instrumental analysis of thyroid hormone disrupting compounds in water sources along the Yangtze River

Thyroid hormone (TH) agonist and antagonist activities of water sources along the Yangtze River in China were surveyed by a green monkey kidney fibroblast (CV-1) cell-based TH reporter gene assay. Instrumental analysis was conducted to identify the responsible thyroid-active compounds. Instrumentally derived l-3,5,3′-triiodothyronine (T₃) equivalents (T₃-EQs) and thyroid receptor (TR) antagonist activity equivalents referring to dibutyl phthalate (DBP-EQs) were calculated from the concentrations of individual congeners. The reporter gene assay demonstrated that three out of eleven water sources contained TR agonist activity equivalents (TR-EQs), ranging from 286 to 293 ng T₃/L. Anti-thyroid hormone activities were found in all water sources with the TR antagonist activity equivalents referring to DBP (Ant-TR-EQs), ranging from 51.5 to 555.3 μg/L. Comparisons of the equivalents from instrumental and biological assays suggested that high concentrations of DBP and di-2-ethylhexyl phthalate (DEHP) were responsible for the observed TR antagonist activities at some locations along the Yangtze River.     

2种再生水深度处理工艺对有毒有机污染物去除效果的评价研究

采用固相萃取(SPE)技术和气相色谱/质谱联用(GC/MS)的方法对2个再生水厂的进水和不同深度处理工艺出水中的有毒有机污染物进行了定性和定量分析,讨论了这2种不同再生水深度处理工艺对有毒有机污染物的去除效果.结果表明,厌氧/缺氧/好氧(A2/O)+连续微滤技术(CMF)+加氯消毒处理工艺和水解酸化+膜生物反应器(MB...     

沸石改性及其去除水中氨氮的实验研究

通过实验研究了沸石改性条件及其对水中氨氮吸附去除的影响。结果表明,加热改性与无机酸改性不能显著提高沸石对氨氮的吸附量。利用NaOH改性的最佳浓度为1 mol/L,此条件下对氨氮吸附量可提高到650.68 mg/kg,为天然沸石的2.82倍。利用无机盐改性时,对氨氮吸附效果最好的是NaCl改性沸石,其次为KCl改性沸石与CaCl₂改性沸石。随着NaCl溶液浓度和改性时间的增加,改性沸石对氨氮的吸附量显著增加,可达天然沸石的3～4倍;在NaCl浓度为150 g/L与改性时间为18 h条件下,改性沸石对氨氮吸附量可达887.35 mg/kg,为天然沸石的3.84倍。     

重点污染行业实施环境管理体系绩效评价指标体系构建及应用

本文针对重点污染行业特点,从能资源消耗、综合利用、环境污染和社会反响四个方面构建了重点污染行业实施环境管理体系绩效评价指标体系,并以化工行业为研究对象,评估了14家企业体系实施前与实施后的绩效。结果表明,实施环境管理体系,有利于提高企业环境效益。     

不同含碳量天然气脱碳方案选择

分析国内外常用脱碳方法和各油气田不同含碳量天然气脱碳实例,比较各种脱碳方案的操作条件、适用范围以及优缺点,给出不同含碳量天然气的脱碳方案:当含碳量为2%～10%时可选用常规醇胺法、热碳酸钾法、物理-化学吸收法、变压吸附法;当含碳量为10%～30%时可选用活化MDEA法、热碳酸钾法、物理吸收法、物理-化学吸收法;当含碳量为30%～70%时可选用改良热碳酸钾法、物理吸收法、物理-化学吸收法、膜分离法+常规醇胺法、膜分离法+热碳酸钾法;当含碳量大于70%时可选用低温分离法、膜分离法+化学吸收法。