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351.
以可持续发展相关理论为基础,利用系统工程的理论和方法建立了河北省县域可持续发展指标体系及其评价标准,并在全省范围应用,对全省136个县(市)可持续发展能力做出了评价。结合评价结果,阐述了河北省县域可持续发展能力的特征,提出了河北省县域可持续发展的方向和思路。 相似文献
352.
353.
Anping Zhang Xuemei Xie Jing Ye Chunmian Lin Xiaoyan Hu 《Environmental Chemistry Letters》2011,9(3):369-373
In recent years, the stereoselective toxicity of chiral organophosphorus pesticides has received increasing attention from
environmental toxicology scientists. In an attempt to explore the stereoselective effects of chiral organophosphorus pesticides
on non-target organisms and enzymes, this work investigated the stereoselective toxicity and inhibition of malathion, malaoxon
and isomalathion on Daphnia magna and on acid α-naphthyl acetate esterase extracted from wheat flour, respectively. Toxicity differences were observed between
the two enantiomers of malathion and malaoxon and among the four stereoisomers of isomalathion in the LC50 values on D. magna and the IC50 values on acid α-naphthyl acetate esterase. Enantiomers with (R)-configuration in all the tested compounds showed
higher toxicity to D. magna than their (S)-forms and racemic forms. Racemic malaoxon and isomalathion showed the strongest inhibition on acid α-naphthyl
acetate esterase compared to their respective enantiomers and stereoisomers. 相似文献
354.
采用部分溃坝模型与堰流相交算法计算溃坝最大流量,并基于四次抛物线概化方法得到溃坝洪水的流量过程线;利用洪峰展平法将洪水波概化为三角形,对洪水演进过程进行模拟,分析溃口宽度和溃口形态对洪水演进过程的影响;研究考虑不同溃坝条件下对溃坝洪水的到时、最大流量、水深和洪水历时等洪水演进的主要参数的快速估算方法,以实现对地震可能引发不同溃坝事件危害性的快速评估。 相似文献
355.
Jingjing Jiang Jiaying Gao Shu Niu Xingyue Wang Tianren Li Shengda Liu Yanhong Lin Tengfeng Xie Shuangshi Dong 《环境科学学报(英文版)》2021,33(8):147-160
The extensive use of tetracycline hydrochloride (TCH) poses a threat to human health and the aquatic environment. Here, magnetic p-n Bi2WO6/CuFe2O4 catalyst was fabricated to efficiently remove TCH. The obtained Bi2WO6/CuFe2O4 exhibited 92.1% TCH degradation efficiency and 50.7% and 35.1% mineralization performance for TCH and raw secondary effluent from a wastewater treatment plant in a photo-Fenton-like system, respectively. The remarkable performance was attributed to the fact that photogenerated electrons accelerated the Fe(III)/Fe(II) and Cu(II)/Cu(I) conversion for the Fenton-like reaction between Fe(II)/Cu(I) and H2O2, thereby generating abundant ?OH for pollutant oxidation. Various environmental factors including H2O2 concentration, initial pH, catalyst dosage, TCH concentration and inorganic ions were explored. The reactive oxidation species (ROS) quenching results and electron spin resonance (ESR) spectra confirmed that ?O2? and ?OH were responsible for the dark and photo-Fenton-like systems, respectively. The degradation mechanisms and pathways of TCH were proposed, and the toxicity of products was evaluated. This work contributes a highly efficient and environmentally friendly catalyst and provides a clear mechanistic explanation for the removal of antibiotic pollutants in environmental remediation. 相似文献
356.
Jin Xie Xiao-Dong Niu Jiao-Jiao Xie Kai-Qiang He Meng-Dan Shi Su-Juan Yu Chun-Gang Yuan Jing-Fu Liu 《环境科学学报(英文版)》2021,33(10):1-7
The distribution and chemical speciation of arsenic (As) in different sized atmospheric particulate matters (PMs), including total suspended particles (TSP), PM10, and PM2.5, collected from Baoding, China were analyzed. The average total mass concentrations of As in TSP, PM10, and PM2.5 were 31.5, 35.3, and 54.1 µg/g, respectively, with an order of PM2.5 >PM 10 > TSP, revealing that As is prone to accumulate on fine particles. Due to the divergent toxicities of different As species, speciation analysis of As in PMs is further conducted. Most of previous studies mainly focused on inorganic arsenite (iAsIII), inorganic arsenate (iAsV), monomethylarsonate (MMA), and dimethylarsinate (DMA) in PMs, while the identification and sensitive quantification of trimethylarsine oxide (TMAO) were rarely reported. In this study, a high-performance liquid chromatography coupled to inductively coupled plasma mass spectrometry system was optimized for As speciation including TMAO in PMs. An anion exchange column was used to separate MMA, DMA and iAsV, while a cation exchange column to separate TMAO and iAsIII. Results showed that iAsV was the dominate component in all the samples, corresponding to a portion of 79.2% ± 9.3% of the total extractable species, while iAsIII, TMAO and DMA made up the remaining 21%. Our study demonstrated that iAsIII accounted for about 14.4% ± 11.4% of the total extracted species, with an average concentration of 1.7 ± 1.6 ng/m3. It is worth noting that TMAO was widely present in the samples (84 out of 97 samples), which supported the assumption that TMAO was ubiquitous in atmospheric particles. 相似文献
357.
废水中氨氮的去除与利用 总被引:21,自引:0,他引:21
化学沉淀剂可去除废水中的氨氮,并得到有用复合肥MgNH4PO4。探讨了诸反应对氨氮去除率的影响。 相似文献
358.
359.
用二氧化氯降解废水中的苯胺类化合物(2)──降解机理的探讨 总被引:5,自引:0,他引:5
本文在上文(1)的基础上,进一步研究了经二氧化氯处理前后BOD_5/COD的变化规律,其比值大于或接近0.3.其降解产物有醌及醌的氧化产物和NHI.对苯胺及二氧化氯来说其.反应级数为1,整个反应为二级反应. 相似文献
360.
从含油废水中筛选分离到1株原油降解菌XD-1,鉴定为假单胞菌(Pseuomonas sp.).初步实验表明菌XD-1具有较强的产表面活性剂乳化原油的作用,对该菌的产表面活性剂性能进行了研究.实验证明,菌XD-1所产表面活性剂为脂肽类物质,菌在生长对数期产表面活性剂,表面活性剂的产生为生长相关型;充足的碳源是产表面活性剂的必需条件,菌利用原油为碳源时能持续大量地产表面活性剂;原油和尿素为产表面活性剂的最适碳源和氮源,菌XD-1产表面活性剂的最佳营养培养基组成为葡萄糖10 g,尿素4 g,磷酸二氢钾1 g,微量元素液4 mL,水1 L,pH 8.0. 相似文献