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761.
采用Fenton氧化-序批式膜生物反应器(SBMBR)组合工艺处理干法腈纶废水。结果表明,在废水初始pH值为3.0,H2O2投加量为90.0 mmol/L,Fe2+投加量为20.0 mmol/L,反应时间为2.0 h的条件下,Fenton氧化预处理对腈纶生产废水的COD去除率达到47.0%以上,COD由1 091 mg/L降至560 mg/L,废水的BOD5/COD由0.32升至0.69,废水的可生化性得到显著提高。Fenton处理出水与丙烯腈废水等比例混合后,采用SBMBR进行生化处理,在水力停留时间为24 h,90 min缺氧/150 min好氧交替运行的条件下,COD、NH4+-N和TN的平均去除率分别为71.7%、97.2%和47.4%,碳源不足是限制TN去除效果的主要影响因素。在无外加碳源的条件下,组合工艺处理后出水COD和NH4+-N浓度分别为117 mg/L和1.7 mg/L,出水水质可以稳定达到国家一级排放标准(GB8978-1996)。 相似文献
762.
按照水质情况,将多种来源于不同工业生产过程中的高浓度有机废水划分为高悬浮固体乳化液废水、难生化高浓度有机废水、高悬浮固体不含油有机废水、含铬有机废水和杂质含量较少的乳化液废水5类,分别采用酸化破乳/Fen-ton氧化/混凝/絮凝、Fenton氧化/混凝/絮凝、混凝/絮凝、还原/混凝/絮凝、震动膜过滤技术作为生化预处理技术,并通过小试和中试验证了各技术的效果。实验结果表明,按照上述分类结果,采用不同预处理技术可以得到良好的效果,废水水质明显改善,满足继续生化处理的基本条件。各预处理生产装置处理效果稳定,同时生化系统已经稳定运行120天以上,COD去除率超过90%,出水经过低剂量的Fenton试剂处理后可达到《污水排入城镇下水道水质标准》(CJ343-2012)。 相似文献
763.
764.
川东北地区大型天然气矿藏中硫化氢含量较高,且带有高剧毒性和高腐蚀性,勘探开发难度较大。同时气田所处区域的岩土条件十分脆弱,洪涝、大风、冰雹等气候灾害经常发生,易引发泥石流、滑坡,形成地质灾害。另外气田所在地人口密度大,给勘探开发设施布局和居民安全带来很大困难。文章通过对川东北地区天然气勘探、开发过程中存在的潜在危害进行详细分析,提出风险防范技术与对策,以供参考。 相似文献
765.
766.
767.
淄博市污染聚集,环境质量易受外来因素影响,产业结构不合理,污染物排放量大,排放强度高。但其充分发挥环保的倒逼作用,通过建立健全环保政策法规体系,严格执行高于省及国家标准的地方环保标准,大力发展高新技术和现代服务业,加快改造传统产业,极大地促进了产业结构升级和经济发展方式的转变。 相似文献
768.
Xin Jin Venkataramana Sridhar 《Journal of the American Water Resources Association》2012,48(2):197-220
Jin, Xin and Venkataramana Sridhar, 2012. Impacts of Climate Change on Hydrology and Water Resources in the Boise and Spokane River Basins. Journal of the American Water Resources Association (JAWRA) 48(2): 197‐220. DOI: 10.1111/j.1752‐1688.2011.00605.x Abstract: In the Pacific Northwest, warming climate has resulted in a lengthened growing season, declining snowpack, and earlier timing of spring runoff. This study characterizes the impact of climate change in two basins in Idaho, the Spokane River and the Boise River basins. We simulated the basin‐scale hydrology by coupling the downscaled precipitation and temperature outputs from a suite of global climate models and the Soil and Water Assessment Tool (SWAT), between 2010 and 2060 and assess the impacts of climate change on water resources in the region. For the Boise River basin, changes in precipitation ranged from ?3.8 to 36%. Changes in temperature were expected to be between 0.02 and 3.9°C. In the Spokane River region, changes in precipitation were expected to be between ?6.7 and 17.9%. Changes in temperature appeared between 0.1 and 3.5°C over a period of the next five decades between 2010 and 2060. Without bias‐correcting the simulated streamflow, in the Boise River basin, change in peak flows (March through June) was projected to range from ?58 to +106 m3/s and, for the Spokane River basin, the range was expected to be from ?198 to +88 m3/s. Both the basins exhibited substantial variability in precipitation, evapotranspiration, and recharge estimates, and this knowledge of possible hydrologic impacts at the watershed scale can help the stakeholders with possible options in their decision‐making process. 相似文献
769.
Anaerobic degradation of microcrystalline cellulose: kinetics and micro-scale structure evolution 总被引:1,自引:0,他引:1
The degradation kinetics and micro-scale structure change of microcrystalline cellulose during anaerobic biodegradation were investigated. A modified Logistic model was established to properly describe the kinetics, which showed good fitness and wide applicability for cellulose degradation. A maximum degradation rate of 0.14 g L−1 h−1 was achieved after cultivating for 51.5 h. This result was in good agreement with the scanning electron microscope and X-ray diffraction analysis. Channels of 400-500 nm size started to occur on the crystalline surface of cellulose at around the inflexion time. Accordingly, the crystallinity significantly decreased at this point, indicating a degradation of the crystalline structure zones by anaerobic bacteria. This study offers direct morphological evidence and quantitative analysis of the biodegradation process of cellulose, and is beneficial to a better understanding of the cellulose degradation mechanism. 相似文献
770.
Effect of humic acids on physicochemical property and Cd(II) sorption of multiwalled carbon nanotubes 总被引:1,自引:0,他引:1
Zinc pyrithione is used as an antifouling agent. However, the environmental impacts of zinc pyrithione have recently been of concern. Zinc induces diverse actions during oxidative stress; therefore, we examined the effect of zinc pyrithione on rat thymocytes suffering from oxidative stress using appropriate fluorescent probes. The cytotoxicity of zinc pyrithione was not observed when the cells were incubated with 3 μM zinc pyrithione for 3 h. However, zinc pyrithione at nanomolar concentrations (10 nM or more) significantly increased the lethality of cells suffering from oxidative stress induced by 3 mM H2O2. The application of zinc pyrithione alone at nanomolar concentrations increased intracellular Zn2+ level and the cellular content of superoxide anions, and decreased the cellular content of nonprotein thiols. The simultaneous application of nanomolar zinc pyrithione and micromolar H2O2 synergistically increased the intracellular Zn2+ level. Therefore, zinc pyrithione at nanomolar concentrations may exert severe cytotoxic action on cells simultaneously exposed to chemicals that induce oxidative stress. If so, zinc pyrithione leaked from antifouling materials into surrounding environments would be a risk factor for aquatic ecosystems. Alternatively, zinc pyrithione under conditions of oxidative stress may become more potent antifouling ingredient. 相似文献