1952-2016年长江经济带天然与人为氮输入时空演变

过量氮输入是水体氮污染的关键驱动因子，解析氮输入的结构和时空变化模式成为氮素环境管理的重要基础和难点.基于1952—2016年长江经济带各地区氮活动数据，分别构建了天然氮输入和人为氮输入模型，评估了氮输入负荷的时空变化特征.结果表明：①长江经济带氮输入负荷总体越过EKC曲线拐点进入由增长向下降的发展阶段，拐点出现在人均GDP为35777~36299元·人^-1时，发生时间为"十二五"时期，主要原因是化肥和食物输入下降；②氮输入负荷存在显著的时空差异，东部地区表现为倒U型，中部为S型，西部为J型，表明氮负荷存在从东向西的空间转移，西部地区成为氮输入负荷增长的热点地区，这与东部地区化肥施用量下降有关；③人为输入是长江经济带氮输入的主要来源，输入量及其占总输入的比例均呈现显著的增长趋势，空间上表现为从西到东部逐步递增的变化规律，与氮驱动力分布一致；④植被的多年平均固氮量为1771 kg·km^-2·a^-1，其中，非农作物的固氮速率为763 kg·km^-2·a^-1，植被固氮量的年际波动较小，天然输入对长江经济带总体氮输入影响较小.     

Enhanced removal of high-As(Ⅲ) from Cl(-Ⅰ)-diluted SO4(-Ⅱ)-rich wastewater at pH 2.3 via mixed tooeleite and(Cl(-Ⅰ)-free) ferric arsenite hydroxychloride formation

An advanced cost-saving method of removal of high-As(Ⅲ) from SO₄(-Ⅱ)-rich metallurgi cal wastewater has been developed by diluting the SO₄(-Ⅱ) content with As(Ⅲ)-Cl(-Ⅰ)-rich metallurgical wastewater and then by the direct precipitation of As(Ⅲ) with Fe(Ⅲ) at pH2.3.As(Ⅲ) removal at various SO₄(-Ⅱ)/Cl(-Ⅰ) molar ratios and temperatures was investigated The results showed that 65.2–98.2%of As(III) immobilization into solids occurred at the SO₄(Ⅱ)/Cl(-Ⅰ) mo...     

Decomplexation of Cu-1-hydroxyethylidene-1,1-diphosphonic acid by a three-dimensional electrolysis system with activated biochar as particle electrodes

The feasibility of decomplexation removal of typical contaminants in electroplating wastewater, complexed Cu(II) with 1-hydroxyethylidene-1,1-diphosphonic acid (Cu-HEDP), was first performed by a three-dimensional electric reactor with activated biochar as particle electrodes. For the case of 50 mg/L Cu-HEDP, Cu(II) removal (90.7%) and PO initial pH 7, acid-treated almond shell biochar (AASB) addition 20 g/L, and reaction time 180 min, with second-order rate constants of 1.10 × 10⁻³ and 1.94 × 10⁻⁵ min⁻¹respectively. The growing chelating effect between Cu(II) and HEDP and the comprehensive actions of adsorptive accumulation, direct and indirect oxidation given by particle electrodes accounted for the enhanced removal of Cu-HEDP, even though the mineralization of HEDP was mainly dependent on anode oxidation. The performance attenuation of AASB particle electrodes was ascribed to the excessive consumption of oxygen-containing functionalities during the reaction, especially acidic carboxylic groups and quinones on particle electrodes, which decreased from 446.74 to 291.48 µmol/g, and 377.55 to 247.71 µmol/g, respectively. Based on the determination of adsorption behavior and indirect electrochemical oxidation mediated by in situ electrogenerated H₂O₂ and reactive oxygen species (e.g., •OH), a possible removal mechanism of Cu-HEDP by three-dimensional electrolysis was further proposed.     

汽油清净剂的研究应用及进展

随着环保要求的日趋严格及汽车工业的发展创新，开展汽油清净剂的研究和应用工作已势在必行。本文介绍了国内外汽油清净剂的发展过程、应用现状，同时还介绍了将清净分散剂、抗氧防腐剂、减磨剂、防锈剂等添加剂复合而成的汽油清净剂的研制情况。实验结果表明：该剂具有抑制和清除发动机燃燃油系统沉积物的性能，达到国外第三代同类产品的水平。     

地塞米松生产中毒性物质泄漏的定性定量分析

采用预先危险性分析和事故树分析剖地塞米松生产过程中毒物质产生中毒事故的危险性。指出溴甲烷和氟化氢是典型毒物。同时，利用泄漏和扩散模型定量分析它们泄漏所造成的危险性。结果表明：溴甲烷泄漏时，地面轴线浓度可以达到９２．３ｍｇ／ｍ＾３，远大于其急性中毒阈值，并制定了相应的预防性工程措施。     

全球环境问题与当代国际关系

环境问题使人类面临着前所未有的生存与发展的巨大挑战，也深刻影响着当代国际关系的发展和演变。该文对环境问题引起的国家安全，全球环境问题的南北分歧，以及南北矛盾的焦点等几个方面，分别进行了阐述和分析，随着环境总是的国际化和全球化，国际社会把保护环境看成是各国政府的共同义务和责任，而与此同时国际间的环境合与竞争关系也得到了进一步的发展。     

关于环境监理的回思

较系统地回顾环境监理产生的背景及发展历程，阐述环境监理的内涵及实质。     

Adsorptive removal of phosphate by the bimetallic hydroxide nanocomposites embedded in pomegranate peel

This study aimed to fabricate new and effective material for the efficiency of phosphate adsorption. Two types of adsorbent materials, the zirconium hydroxides embedded in pomegranate peel (Zr/Peel) and zirconium-lanthanum hydroxides embedded in pomegranate peel (Zr–La/Peel) were developed. Scanning electronic microscopy (SEM), x-ray photoelectron spectroscopy (XPS) and x-ray diffraction (XRD) were evaluated to give insight into the physicochemical properties of these adsorbents. Zr–La/Peel exceeded the adsorption efficiency of Zr/Peel adsorbents in batch adsorption experiments at the same pH level. The peel as a host can strive to have a strong “shielding effect” to increase the steadiness of the entrenched Zr and La elements. La and Zr are hydroxide metals that emit many hydrogen ions during the hydrolysis reaction, which contribute to protonation and electrostatic attraction. The highest adsorption capacity of La–Zr/Peel for phosphate was calculated to be 40.21 mg/g, and pseudo second-order equation is very well fitted for kinetic adsorption. Phosphate adsorption efficiency was reduced by an increase of pH. With the background of coexisting Cl^?, little effect on adsorption efficiency was observed, while adsorption capacities were reduced by almost 20–30% with the coexistence of ${{\text{SO}}_4}^{2?}$, ${{\text{NO}}_3}^{?}$ and humic acid (HA).     

基于文献计量的PPP研究趋势与热点分析

近年来,我国在能源、农业、交通运输、市政工程、生态建设和环境保护等领域广泛使用政府和社会资本合作(PPP)模式开展建设和运营。为客观地掌握国内外PPP的研究现状,明确当前的研究前沿与热点问题,笔者基于Web of Science核心合集中的SCI和SSCI数据库,采用文献计量工具Histcite Pro对当前国内外PPP研究工作进行了系统的计量学分析与评价。研究结果表明:PPP研究最早开始于1952年,且从1993年开始文献呈现增加趋势;美国、中国和英国在该领域发表文献最多,且国际上具有较强影响力的单位主要集中在美国境内,我国研究实力较强的有香港理工大学、香港大学、清华大学等;基础设施建设、中国PPP项目、风险、绩效、疾病、药物研发、金融、可持续、公共卫生等是该领域的研究热点。     

磁分离除尘的初步实验研究及其机理分析

对磁性粉 尘和非 磁性粉 尘进 行 了磁 分离 实 验研 究。结 果 表明 ，对 磁性 粉尘 ，磁 除尘 效 率可达９９ ％ 以上 ，而对非 磁性粉尘 ，通过粉 尘上磁， 磁除尘效 率可达９ ０ ％ 以 上