天然矿物组合材料渗透反应墙修复地下水镉污染

实验模拟地下环境,以天然矿物材料石灰石、海泡石和膨润土作为可渗透反应墙(PRB)填充材料,采用正交实验法设计了16种可渗透反应器,研究了天然矿物组合材料组配对污染地下水模拟液中镉污染的修复效果、出水pH、有效孔隙度和渗透系数的影响,同时对机理进行了分析。实验结果显示,组合材料对镉去除率达99.8%以上,石灰石对处理效果贡献最大,增加石灰石用量,处理效果明显改善,当石灰石含量为10%及更高时,对含镉1.0 mg/L的污染地下水模拟液处理后镉浓度低于0.7μg/L,达到地下水质量标准GB/T 14848-93规定的II类水质标准;石灰石用量的增加对渗透系数影响不大,但出水pH呈弱碱性(7pH9),随反应时间延长逐渐降低并稳定于8。增加海泡石和膨润土用量对处理效果改善作用不大,但显著降低体系渗透系数,影响透水性。以正交实验直观分析法计算得到修复效果最优的PRB填充材料组配为石灰石/海泡石/膨润土=20/10/2(质量分数)。     

CF-TiO2的制备及其在模拟太阳光下的光催化性能

以十六烷基三甲基溴化铵(CTAB)和氟化钠分别为碳源和氟源,采用溶胶-凝胶法制备了CF-TiO2光催化剂,并对其进行了SEM、XRD、N2吸附、XPS、UV-visDRS和PL表征。研究了CF-TiO2在模拟太阳光下光催化降解亚甲基蓝溶液的活性,并讨论了氟掺杂量以及CTAB加入量对催化性能的影响。结果表明,CF-TiO2为锐钛矿型,孔结构丰富、比表面积大,氟碳共掺后使TiO2光催化剂的禁带宽度变窄为2.40 eV,在可见光区吸收增强,有效提高TiO2在模拟太阳光下的光催化活性,而且当n(F/Ti)(氟钛摩尔比)为0.1,加入碳源CTAB量为2 g时,其光催化活性最好。     

多效膜蒸馏技术浓缩回收废水中的二甲基亚砜

利用具有内部潜热回收功能的气隙式多效膜蒸馏(MEMD)组件对含二甲基亚砜(DMSO)的化纤废水进行了浓缩回收研究,考察了料液中DMSO浓度、进料流量、进料温度和膜侧进口温度对膜通量、造水比、分离因子和回收率的影响。结果表明,多效膜蒸馏可以将DMSO废水浓缩至200~300 g/L;初始浓度为6.2 g/L时,造水比和分离因子最高值分别为12.4和76.0;虽然膜通量、造水比和分离因子均随料液浓度增大而下降,但是当DMSO浓度达到200 g/L时,膜通量、造水比、分离因子仍分别高达3.74 L/(m2·h)、7.1、32.1;在整个浓缩过程中,回收率维持在99.6%以上;当DMSO废水浓缩达到150 g/L以上时,含有少量DMSO的渗透液可作为二次料液继续用MEMD过程浓缩。膜组件在连续运行的1个月内保持了良好的操作性能。该实验研究表明,多效膜蒸馏过程可以高效节能地浓缩回收化纤废水中的DMSO。     

堑秋湖渔业模式对鄱阳湖南矶湿地越冬候鸟种群数量的影响和保育对策

鄱阳湖是我国最大的淡水湖、国际重要湿地。“堑秋湖”是当地老百姓根据鄱阳湖夏涨秋落的规律,在湖底低洼处堑壕沟、围矮堤,以便在秋季退水时截留更多的鱼和水,最后将鱼类资源一网打尽的渔业方式;也是长江流域中下游湖区以及鄱阳湖流域老百姓利用季节性浅水蝶形湖泊中渔业资源最主要的捕鱼和管理方式。采用PRA方法对江西鄱阳湖南矶湿地国家级自然保护区“堑秋湖”历史及现状进行问卷调查,采用样线样点结合方法对越冬候鸟种群数量进行调查分析。研究表明：鄱阳湖南矶湿地国家级自然保护区拥有蝶形湖泊26个,均已承包给个人管理并存在养鱼虾蟹等行为,为典型的“堑秋湖”渔业模式;不同月份越冬候鸟数量变化呈“M”型,不同样线候鸟数量差异较大,而候鸟种类在月份和样线方面差异不大;“堑秋湖”渔业模式对鄱阳湖越冬候鸟的种群数量、分布及栖息地生态功能的发挥存在明显正负面影响。对于建立经济社会可持续发展的“堑秋湖”经营模式进行了探讨,提出了有利于越冬候鸟栖息的保育对策     

基于ASAR GM数据时序特征的农田表层土壤水分的反演

了解农田表层土壤水分的时空变化对反演涝渍害有着十分重要的意义, 针对ASAR GM数据特点提出了在没有地面观测数据地区农田大尺度土壤水分的反演方法,即运用MODIS NDVI数据（空间分辨率为250 m）的农田作物时序特征提取土地利用现状,并以此来校正ASAR GM数据（空间分辨率为1 km）中的混合像素;利用大面积降水后土壤表层湿度水平差异不大的特点,运用非线性回归模型,获取水云模型中的经验系数,运用水云模型将植被和土壤对后向散射的贡献区分开;在获得一个地方长时间土壤后向散射系数空间分布集后,假设其土壤粗糙度不变的情况下,其后向散射系数与土壤表层湿度成正比,运用其时序特征计算出其土壤表层相对体积含水量。运用上述方法,利用79景ASAR GM数据和同时期的MODIS数据,反演了湖北省四湖地区棉田的土壤表层相对体积含水量的时空分布,将其计算值与观测值比较分析后发现,其变化趋势相同、相关系数（R2=0779,n=25）也很高,圴方根误差为963%,表明上述反演方法还是可行了,适用于大尺度农田土壤墒情的反演     

Anatomical and physiological responses of Colorado blue spruce to vehicle exhausts

In order to examine whether the leaves of the Colorado blue spruce (Picea pungens) are damaged or not by traffic pollution, the traits of the anatomy and physiology of its leaves are investigated by exposure to vehicle exhausts in a laboratory experiment lasting 30 days. The results show that both the anatomical structures and physiological traits of the leaves are significantly affected by vehicle exhausts. The anatomical structures, including epidermis, cuticle, palisade, and spongy parenchyma are modified when exposed to the high concentrations (≥0.4 mg/m³) of vehicle exhausts. However, physiological traits such as total chlorophyll content are not changed when exposed to different concentrations of vehicle exhaust. Unlike the total chlorophyll content, the electrical conductivities increased, whereas the POD activities decreased when presented in vehicle exhausts. The present study indicates that the Colorado blue spruce changes its anatomical structures and physiological traits to avoid possible damage by vehicle exhausts.     

Three major nucleolar proteins migrate from nucleolus to nucleoplasm and cytoplasm in root tip cells of Vicia faba L. exposed to aluminum

Results from our previous investigation indicated that Al could affect the nucleolus and induce extrusion of silver-staining nucleolar particles containing argyrophilic proteins from the nucleolus into the cytoplasm in root tip cells of Vicia faba L. So far, the nucleolar proteins involved have not been identified. It is well known that nucleophosmin (B23), nucleolin (C23), and fibrillarin are three major and multifunctional nucleolar proteins. Therefore, effects of Al on B23, C23, and fibrillarin in root tip cells of V. faba exposed to 100 μM Al for 48 h were observed and analyzed using indirect immunofluorescence microscopy and Western blotting. The results from this work demonstrated that after 100 μM of Al treatment for 48 h, B23 and C23 migrated from the nucleolus to the cytoplasm and fibrillarin from the nucleolus to the nucleoplasm. In some cells, fibrillarin was present only in the cytoplasm. Western blotting data revealed higher expression of the three major nucleolar proteins in Al-treated roots compared with the control and that the B23 content increased markedly. These findings confirmed our previous observations.     

Knowledge-based system,equipped with cluster analysis for eco-material selection: an automobile structure case study

The aim of this study is to develop a material selection framework structured around a knowledge-based system (KBS). Specifically, a hybrid data mining technique is employed to extract knowledge from large datasets using cluster analysis techniques; the mined knowledge then serves as the inference logic within the KBS designed for material selection purposes. Cluster analysis results are used as a basis for the tree-based structure of the KBS where if–then rules are developed based on the general cluster properties; that is, inference logic is structured in a way such that it can predict general sustainability characteristics of the material as well as its exact mechanical, cost and physical properties. To develop the structure of the KBS, the selection structure employs sustainable material indices. Additionally, the proposed material selection model of the KBS is purposefully composed of material sustainability, functionality and cost indices. The constructed knowledge is then demonstrated for selecting automobile structural panels.     

多效唑对水仙观赏效果的影响

水仙对多效唑比较敏感,无论浸泡法或叶面喷施法都具有明显的矮化效应,但当浓度≥200mg·l-1时又会产生药害,也有碍观赏;叶面喷施法对水仙矮化效应不如浸泡法,开花期亦迟10·15d;浸泡法的最佳处理浓度是50 mg·l-1;叶面喷施法以浓100-200mg·l-1效应最好,但此法费工费时,操作不便,生产上最好不采用。     

The monitoring results of electromagnetic radiation of 110-kV high-voltage lines in one urban location in Chongqing P.R. China

To understand electromagnetic radiation field strength and its influencing factors of certain 110-kV high-voltage lines in one urban area of Chongqing by measuring 110-kV high-voltage line’s electromagnetic radiation level. According to the methodology as determined by the National Hygienic Standards, we selected certain adjacent residential buildings, high-voltage lines along a specific street and selected different distances around its vertical projection point as monitoring points. The levels of electromagnetic radiations were measured respectively. In this investigation within the frequency of 5–1,000 Hz both the electric field strength and magnetic field strength of each monitoring sites were lower than the public exposure standards as determined by the International Commission on Non-Ionizing Radiation Protection. However, the electrical field strength on the roof adjacent to the high-voltage lines was significantly higher than that as measured on the other floors in the same buildings (p < 0.05). The electromagnetic radiation measurements of different monitoring points, under the same high-voltage lines, showed the location which is nearer the high-voltage line maintain a consistently higher level of radiation than the more distant locations (p < 0.05). Electromagnetic radiation generated by high-voltage lines decreases proportionally to the distance from the lines. The buildings can to some extent shield (or absorb) the electric fields generated by high-voltage lines nearby. The electromagnetic radiation intensity near high-voltage lines may be mitigated or intensified by the manner in which the high-voltage lines are set up, and it merits attention for the potential impact on human health.