家具涂装行业VOCs污染特征分析

研究选取典型家具涂装行业为采样点,对底漆涂装车间、面漆涂装车间、干燥车间和车间有组织排放的VOCs样品进行采集,分析VOCs的污染特征、臭氧生成潜势和恶臭指数。结果表明:底漆和面漆涂装车间的总VOCs浓度分别为3 051.0,2 098.0μg/m~3,车间有组织排放产生的VOCs浓度较低。各生产工艺环节VOCs均以苯系物为主(78.6%~92.4%),车间有组织排放由于活性炭对苯系物的吸附作用,烷烃和烯烃质量分数较其他工艺环节高。底漆、面漆和干燥车间VOCs的臭氧生成潜势较高(7 903.34~18 535.8μg/m~3),敏感性物种均为1,2,4-三甲基苯、邻-二甲苯等苯系物。苯系物的恶臭指数较大,底漆、面漆和干燥车间的恶臭指数高达25.809、12.525和9.076,对二乙基苯、正丙苯、对乙基甲苯的恶臭指数相对较高,存在一定程度的恶臭污染。     

金属氧化物负载γ-Al_2O_3粒子电极对酸性橙Ⅱ的电催化氧化研究

以γ-Al_2O_3作为载体,采用浸渍热分解法制备了Sn、Mn、Cu、Pb单组分氧化物和Sn-Ce-Sb复合氧化物粒子电极。通过对酸性橙II(AOII)的降解实验,以及采用重复试验和扫描电镜(SEM)、紫外光谱扫描等方法,探讨了粒子电极材料的性能。研究结果表明:Sn/γ-Al_2O_3相比于Mn/γ-Al_2O_3、Cu/γ-Al_2O_3、Pb/γ-Al_2O_3等单组分氧化物粒子电极表现出了更好的电催化活性和稳定性。掺杂Ce、Sb后电极表面晶体粒径细小且分布均匀,有利于提高Sn/γ-Al_2O_3粒子电极的性能。电流密度为20 m A/cm2,曝气量0.5 L/min反应条件下,反应3 h后Sn-Ce-Sb/γ-Al_2O_3粒子电极对AOII的去除率为100%,TOC的去除率达84.2%,重复使用5次后TOC去除率仍保持在80%以上。表明Sn-Ce-Sb/γ-Al_2O_3粒子电极具有较好的应用前景。     

From illite/smectite clay to mesoporous silicate adsorbent for efficient removal of chlortetracycline from water

A series of mesoporous silicate adsorbents with superior adsorption performance for hazardous chlortetracycline(CTC) were sucessfully prepared via a facile one-pot hydrothermal reaction using low-cost illite/smectite(IS) clay,sodium silicate and magnesium sulfate as the starting materials.In this process,IS clay was "teared up" and then "rebuilt" as new porous silicate adsorbent with high specific surface area of 363.52 m~2/g(about 8.7 folds higher than that of IS clay) and very negative Zeta potential(- 34.5 mV).The inert Si- O- Si(Mg,Al) bonds in crystal framework of IS were broken to form Si(Al)- O~- groups with good adsorption activity,which greatly increased the adsorption sites served for holding much CTC molecules.Systematic evaluation on adsorption properties reveals the optimal silicate adsorbent can adsorb 408.81 mg/g of CTC(only 159.7 mg/g for raw IS clay) and remove 99.3%(only 46.5%for raw IS clay) of CTC from 100 mg/L initial solution(pH 3.51;adsorption temperature 30℃;adsorbent dosage,3 g/L).The adsorption behaviors of CTC onto the adsorbent follows the Langmuir isotherm model,Temkin equation and pseudo second-order kinetic model.The mesopore adsorption,electrostatic attraction and chemical association mainly contribute to the enhanced adsorption properties.As a whole,the high-efficient silicate adsorbent could be candidates to remove CTC from the wastewater with high amounts of CTC.     

Simultaneous determination of malachite green, enrofloxacin and ciprofloxacin in fish farming water and fish feed by liquid chromatography with solid-phase extraction

An effective and sensitive method for simultaneous analysis of malachite green (MG), enrofloxacin (ENFLX) and ciprofloxacin (CPFLX) by liquid chromatography-diode array detection with solid-phase extraction (SPE) is developed. The conditions of SPE and LC were investigated and optimised. The effective separation of these compounds was achieved using a ZY1104 C18 column (250 × 4.6 mm, 5 μm) with 20 mM tetrabutyl ammonium bromide (pH 3.0)-acetonitrile as mobile phase and gradient elution. The diode array detection was used at 278 nm for ENFLX and CPFLX and at 613 nm for MG. Under the optimal conditions, the method LOD values of MG, ENFLX and CPFLX were 0.01, 0.07 and 0.10 μg L(?-1) for fish farming water samples and 1.5, 10.5 and 15 μg kg(?-1) for fish feed samples, respectively. The relative recoveries of the three analytes were achieved to be 76.7-82.3% with the RSDs (n = 5) of 3.2-4.6% for spiked fish farming water samples and 78.8-93.7% with the RSDs (n = 5) of 3.1-4.8% for spiked fish feed samples.     

硫丹对罗非鱼(Oreochromis aureus×O.niloticus)和草鱼(Ctenopharyngodon idellus)的急性毒性研究

为控制虫害农业上大量使用硫丹,因此硫丹可通过多种途径进入水环境中.养殖环境和水产品中已发现硫丹残留,这给养殖环境和食品安全造成潜在威胁.通过半静态试验方法测定了罗非鱼和草鱼的半致死浓度,并估算了其在水环境中的安全浓度.结果表明,罗非鱼和草鱼的半致死浓度分别为1.97(1.26 -2.87) μg·L-1和2.33(1....     

1695年临汾8级大震成因讨论

根据动态传播断层与同层内横向断层间的相互作用以及异层内深浅断层之间的相互作用讨论了1303年洪洞大震时北北东向震源大幅度错动对临汾北西西向活动断层的致锁作用,由此研究了1695年临汾8级大震形成的原因。最后还讨论了1989年山西大同—阳高中强震发生的成因机制。     

模糊层次综合法用于企业安全性评价

将模糊综合评价与层次分析相结合 ,建立了企业安全模糊层次综合法的评价模型。实践证明 ,这种方法在进行企业的安全性综合评价中是有效的     

漫湾库区生产恢复障碍及其原因

在对漫湾库区调查的基础上，总结了库区生产恢复现状，认为农业生产相应条件恢复不到位，影响土地的持续利用：土地生产力降低，单一的种植业结构和产业结构，经济林与畜牧养殖业因土地被淹没带来萎缩，渔业、旅游业等缺乏规划和移民的参与，表现出库区移民生活水平相对于远迁移民、全县(省)平均下降了。分析了漫湾库区生产恢复的障碍及其原因，并就生产恢复提出一些建议：(1)提升澜沧江梯级开发水电工程中对移民问题的重视，将漫湾电站纳人中央直属电站范畴，统筹安排移民遗留问题，给予资金支持；(2)重新整体规划漫湾库区的移民安置，控制库区土地人口压力；(3)调整产业结构，促成传统种植业人口向林、牧业，向第二、三产业转移；(4)理顺和明确移民方面的责、权、利关系，将生产恢复问题与安置区地方经济发展问题结合起来考虑；(5)建立公众积极参与的决策体制与决策执行机制。     

冶金矿业环境隐患因子识别

本文分析了环境隐患与安全隐患的异同,定义了冶金矿业行业环境隐患的含义,分析了环境隐患与环境事故的关系,提出环境隐患因子识别的原则、范围和方法。根据冶金矿业行业实际生产情况,用LEC法和危险物质辨识方法对冶金矿业环境隐患进行识别,最终指出常见的冶金矿业环境隐患因子。     

黄河流域土壤侵蚀潜在风险及其转化分析

作者在前期研究中,基于流域最小图斑的划分,提出了土壤侵蚀快速评估方法,并在黄河流域的应用中取得了较满意的效果。论文以黄河流域土壤侵蚀强度的评估结果为基础,评估了流域土壤侵蚀的脆弱性。以抗侵蚀年限表征流域土壤侵蚀潜在危险度,结合土壤侵蚀脆弱性分析了流域土壤侵蚀潜在风险。通过与土壤侵蚀强度的对比,指出在流域水土保持和生态保护中,同时考虑土壤侵蚀强度和水土流失潜在风险才能作出更合理的决策。最后,分析了黄河流域中游土壤侵蚀风险向下游洪水风险的转化关系,指出黄河中游高产沙区土壤侵蚀风险转化为下游更高的洪水风险,在泥沙灾害研究中应关注灾害的链式反应。