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101.
    
A Fe-Zr binary oxide adsorbent has been successfully synthesized using a co-precipitation method. It showed a better performance for antimonate (Sb(V)) removal than zirconium oxide or amorphous ferric oxide. The experimental results showed that the Fe-Zr adsorbent has a capacity of 51 mg/g at an initial Sb(V) concentration of 10 mg/L at pH 7.0. Sb(V) adsorption on the Fe-Zr bimetal oxide is normally an endothermic reaction. Most of the Sb(V) adsorption took place within 3 hr and followed a pseudo second-order rate law. Co-existing anions such as SO42-, NO3- and Cl- had no considerable effects on the Sb(V) removal; PO34- had an inhibitory effect to some extent at high concentration; while CO_32- and SiO44- showed significant inhibitory effects when they existed in high concentrations. The mechanism of Sb(V) adsorption on the adsorbent was investigated using a combination of zeta potential measurements, XPS, Raman, FT-IR observations and SO42- release determination. The ionic strength dependence and zeta potential measurements indicated that inner-sphere surface complexes were formed after Sb(V) adsorption. Raman and XPS observations demonstrated that both Fe-OH and Zr-OH sites at the surface of the Fe-Zr adsorbent play important roles in the Sb(V) adsorption. FT-IR characterization and SO42- release determination further demonstrated that the exchange of SO42- with Sb(V) also could promote the adsorption process. In conclusion, this adsorbent showed high potential for future application in Sb(V) removal from contaminated water.  相似文献   
102.
以秦皇岛市为例,研究了气候变暖对地表降水量的影响.通过对51年来秦皇岛市气候、降水材料的分析得出结论:秦皇岛市近年来明显变暖,年平均气温上升约2℃,同时气候变干,降水量减少18.3%;气候变化会引起水循环的变化及水资源在时空上的重新分布以及水资源总量的改变,对流域内的水资源量影响十分显著.  相似文献   
103.
Macroinvertebrates are important components of stream ecosystems, and are often used as indicator species for the assessment of river ecology. Numerous studies have shown that substrate is the primary physical environmental variable affecting the taxa richness and density of macroinvertebrates. The aim of this work is to study the effects of the characteristics of streambed substrate, such as grain size, shape, and roughness, on the composition and biodiversity of macroinvertebrates. A field experiment was done on the Juma River, a second-order mountain stream in northern China. Substrata of cobbles, hewn stones, pebbles, coarse sand, and fine sand were used to replace the original gravel and sand bed in a stretch of 30 m in length. The sampling results indicated that the macroinvertebrate assemblage is significantly affected by the grain size, porosity and interstitial dimension of the substrate, while it is rarely affected by the shape and the surface roughness of the experimental substrata. Macroinvertebrate compositions in cobbles and hewn stones were stable and changed least over time. The taxa richness and density of individuals in the substrata of cobbles, hewn stones, and pebbles are much higher than in those of the coarse sand and fine sand.  相似文献   
104.
依据经济合作与发展组织(OECD)关于定量结构-活性关系(QSAR)模型构建和使用导则,通过多元线性回归(MLR)方法建立了一个包含9个描述符的卤代有机化合物鱼类生物富集因子(BCF)的QSAR模型。QSAR模型的调整决定系数R2adj = 0.877,去一法交叉验证系数Q2LOO= 0.873,外部验证系数Q2EXT= 0.757,表明模型具有较好的拟合优度、稳健性和预测能力。采用欧几里德距离方法表征了模型应用域,并对模型进行了机理解释。所构建的模型,可以用于预测应用域内卤代化合物的BCF。  相似文献   
105.
To understand the water purification mechanism of potassium permanganate as a coagulation-aid during the preoxidation process, the microtopography of its reductive products, the newly formed hydrous manganese dioxide and the aged hydrous manganese dioxide, was investigated. The morphology of natural organic matter (NOM) adsorbed by the newly formed hydrous manganese dioxide was also compared with that of NOM alone. By using the tapping mode atomic force microscopy (AFM), the observation results show that the newly formed hydrous manganese dioxide possess a perforated sheet (with a thickness of 0–1.75 nm) as well as some spherical particle structures compared with the hydrous manganese dioxide with 2 h aging time, which demonstrated that the newly formed hydrous manganese dioxide had a large surface area and adsorption capacity. When 1 mmol/L newly formed hydrous manganese dioxide was added, the microtopography of NOM molecules shifted from a loosely dispersed pancake shape (with adsorption height of 5–8.5 nm) to a densely dispersed and uniform spherical structure. These results provide a valid proof that it is the perfect adsorption capability of the newly formed hydrous manganese dioxide that might result in the coagulation aid effect of potassium permanganate preoxidation.  相似文献   
106.
    
Wetland assessment has been a popular field of research worldwide. However, various indicators have been used in wetland assessment for different purposes and backgrounds and also because of the research limitations. Therefore, a more comprehensive, sound, and efficient indicator system is needed for researchers’ referencing to evaluate wetlands. After an extensive review of wetland assessment literatures, the reported indicators were evaluated using the developed assessment system, based on the Analytical Hierarchy Process (AHP) with three main goals: nature protection, function utilization, and sustainable development. Each indicator was evaluated using two methods. The first method was to study the percentage of the indicator application, and the second was to assess the weighted ratios assigned to the indicators according to principles of comparability, typicality, sensibility, and availability. The results of these two methods were compared to study the commonalities and specialties of the indicators. They also showed that some indicators were widely used, including biodiversity, weather and climate, hydrological change, and the output of wetland. On the other hand, other sustainable indicators were easily ignored, such as environmental carrying capacity and wetland planning. Furthermore, an indicator system for wetland assessment was structured and strategized to discuss how to choose indicators for wetland assessment under different conditions. The proposed approach can be used to guide the process of wetland assessments in the future.  相似文献   
107.
    
Phosphorus (P) is a vital nutrient for sustaining natural water productivity. Both particulate and dissolved forms of organic and inorganic P are potentially important sources of bioavailable P for primary and secondary producers. A microcosm system to imitate the bacterial community in Plym river sediment and pore water is described and bacterial uptake rates for inorganic and organic phosphorus are presented in this paper. The aim of this study was to investigate the uptake of two organic phosphorus compounds (phytic acid and D-glucose-6-phosphate) by freshwater bacteria. The bioreactors comprise glass columns packed with two types of small glass beads on which bacterial biofilm can develop. The glass beads with different porosity were introduced to simulate River SPM. The selected P compounds spiked into the inflow of the microcosm, and measured the step change of P concentration in the outflow to investigate the behavior of bacterial uptake of nutrients. The results showed that organic phosphorus was converted into inorganic phosphorus but the conversion rate depended on the type of phosphorus species. One experiment suggested that phytic acid (refractory) could displace phosphate from the biofilm surface; the other experiment showed that D-glucose-6-phosphate (labile) could be hydrolysed and utilized easily by the bacteria. The results also suggested that bacteria might break down the C-P bonds to utilize the carbon. Further experiments should investigate the effect of varying the C:N:P ratio in the microcosm system to determine which nutrient limits bacteria uptake.  相似文献   
108.
This study focused on the water quality of the Guanting Reservoir, a possible auxiliary drinking water source for Beijing. Through a remote sensing (RS) approach and using Landsat 5 Thematic Mapper (TM) data, water quality retrieval models were established and analyzed for eight common water quality variables, including algae content, turbidity, and concentrations of chemical oxygen demand, total nitrogen, ammonia nitrogen, nitrate nitrogen, total phosphorus, and dissolved phosphorus. The results show that there exists a statistically significant correlation between each water quality variable and remote sensing data in a slightly-polluted inland water body with fairly weak spectral radiation. With an appropriate method of sampling pixel digital numbers and multiple regression algorithms, retrieval of the algae content, turbidity, and nitrate nitrogen concentration was achieved within 10% mean relative error, concentrations of total nitrogen and dissolved phosphorus within 20%, and concentrations of ammonia nitrogen and total phosphorus within 30%. On the other hand, no effective retrieval method for chemical oxygen demand was found. These accuracies were acceptable for the practical application of routine monitoring and early warning on water quality safety with the support of precise traditional monitoring. The results show that performing the most traditional routine monitoring of water quality by RS in relatively clean inland water bodies is possible and effective.  相似文献   
109.
Environmental Science and Pollution Research - Current research on prothioconazole (PTC), a broad-spectrum triazole fungicide, mainly focuses on its efficacy and residues; only a few studies have...  相似文献   
110.
SD-MOP整合模型在秦皇岛市生态环境规划中的应用研究   总被引:12,自引:1,他引:12       下载免费PDF全文
针对秦皇岛市区的系统特征,应用SD/MOP整合模型方法对其进行了生态环境系统规划研究.从该市生态系统的结构和功能模拟入手,建立城市生态环境系统动力学模型.通过模型的原始运行和灵敏度分析,寻找出对城市发展影响较大的敏感点及与之相应的参变量,以之为核心建立多目标规划模型,求解MOP模型,获取敏感点最优解集;根据模型的解,针对具体情况设计模拟运行方案,与决策者进行交互,取得系统发展的优化规划方案.并对方案实施后的社会、经济、环境等结果进行了预测.  相似文献   
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