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831.
为了研究灭活厌氧污泥和活性厌氧污泥对间二氯苯 (m-DCB)的吸附,考察了吸附平衡时间、吸附动力学、吸附等温线、吸附热力学、污泥投加量和pH对吸附m-DCB的影响。结果表明,2种污泥对m-DCB的吸附在1 h内达到平衡。应用伪一级、伪二级反应动力学对实验数据进行验证,表明厌氧污泥吸附m-DCB更符合伪二级反应动力学模型。2种污泥对m-DCB的吸附都可以用Langmuir和Freundlich吸附模型拟合,但Langmuir吸附模型的拟合结果要好于Freundlich模型,且活性厌氧污泥的吸附性能显著高于灭活厌氧污泥。从吸附热力学上看,该吸附为放热反应,低温有利于吸附反应的进行。pH值对2种污泥吸附m-DCB的影响很小。 相似文献
832.
Effect of Tween 80 and beta-cyclodextrin on degradation of decabromodiphenyl ether (BDE-209) by White rot fungi 总被引:2,自引:0,他引:2
The environmental safety of decabromodiphenyl ether (BDE-209), a widely used flame retardant, has been the topic of controversial discussions during the past several years. Degradation of BDE-209 into lower brominated diphenyl ether congeners, exhibiting a higher bioaccumulation potential, has been a critical issue. White rot fungi are known to degrade a wide variety of recalcitrant pollutants. In this work, white rot fungi were used to degrade BDE-209 in liquid culture medium, and the effects of Tween 80 and beta-cyclodextrin on BDE-209 degradation by white rot fungi were evaluated. On the basis of these results, it appears that BDE-209 could be degraded by white rot fungi, and Tween 80 and beta-cyclodextrin can both increase the biodegradation. The best result in Tween 80 experiments was obtained at a Tween 80 concentration of 500mgl(-1) within 10d, which showed 96.5% (w/w) BDE-209 transformed. Tween 80 at a high concentration will restrain the fungal growth and the degradation of BDE-209. However, beta-cyclodextrin had positive effects both on the BDE-209 degradation and the fungal growth. 相似文献
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835.
Contents of inorganic nitrogen (NH4(+)-N and NO3(-)-N) in soil profiles were measured in five typical zones ( including permanently flooded floodplain(B), 1-year floodplain (O), 5-year floodplain (F),10-year floodplain (T), and 100-year floodplain (H) )from Huolin River floodplain in Erbaifangzi, Jilin Province of China, in the soil-defrosted period (Mayof 1999). Contour maps and profile maps were constructed to describe the spatial distributions of NH4(+)-N and NO3(-)-N) in order to identify the influences of flood frequencies on them. Results showed that NH4(+)-N generally increased with depth in soil profiles from the five areas, but NH4(+)-N contents in T or H areas significantly differed from those in other areas. For NO3(-)-N, with the exception that there was a significant cumulative peak (6.77 +/- 0.08 mg kg(-1)) at 15-cm depth (10-20 cm) in B area, no significant difference was observed between NO3(-)-N contents in soil profiles from the other four areas. The horizontal distributions of NH4(+)-N and NO3(-)-N in top soils (0-10 cm) were different in the five areas,which were greatly influenced by flood frequencies. The highest content of NH4(+)-N or NO3(-)-N did not appear in B area but in the floodplain with certain flood frequency. For example, NH4(+)-N content (16.81 mg kg-(1)) in 5-year floodplain wetland was highest, and the highest content of NO3(-)-N(1.69 mg kg(-1)) appeared in 1-year floodplain wetland. In addition, NH4(+)-N contents were significantly correlated with soil pH, and NO3(-)-N contents had significant correlation with inorganic carbon, but there were no significant correlations between inorganic nitrogen and other selected soil properties. 相似文献
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838.
厌氧水解—高负荷生物滤池处理城镇污水的中试研究 总被引:5,自引:0,他引:5
厌氧水解 -高负荷生物滤池是一种利用附着在塑料模块填料上的微生物系统对城镇污水中的污染物质进行降解处理的绿色环保技术。厌氧水解池和高负荷生物滤池采用的塑料模块填料具有高空隙率、高附着面积、高布水性能和抗堵塞的优异性能 ,并无须回流。当厌氧水解池水力停留时间为 4h ,生物滤池水力负荷为 30m3/ (m2 ·d) ,该系统处理城镇污水的CODcr去除率达 75 % - 85 % ,BOD5去除率达 85 % - 95 % ,SS去除率达 85 % -95 % ,处理后出水的上述各项指标均可满足国家二级生物处理排放标准的要求。 相似文献
839.
β-环糊精聚合物微球吸附Pb~(2+)的动力学研究 总被引:3,自引:3,他引:0
以β-环糊精(3-CD)为原料、环氧氯丙烷(ECH)为交联剂,制得β-环糊精聚合物(β-CDP)微球。研究了β-CDP微球对Pb~(2+)的吸附特性和动力学。实验结果表明,β-CDP微球对Pb~(2+)的吸附既符合一级动力学方程,也符合二级动力学方程。β-CDP微球对Pb~(2+)的Langmuir吸附等温线的线性拟合方程为ρ_e/Q_m=0.049 5ρ_0+0.030 3,相关系数为0.993 7;β-CDP微球对Pb~(2+)的Freundlich吸附等温线的线性拟合方程为lgQ_e=0.145 4 lgρ_e+0.970 1,相关系数为0.992 9。 相似文献
840.
介绍了区域组团式水热能综合利用的模式,区域组团式水热能综合利用以节能、降耗、减污、增效为目标,从大型企业、工业园区或镇市三个层面构建包含有工业企业、商业办公区、居民区、污水处理厂、热电厂及水体在内的多主体的水、热、能综合利用网络,形成以水为物质和能量载体的新的利用模式。以污水厂和热泵为中心的江苏恒力集团有限公司(简称恒力集团)的水热能综合利用网络,可实现集团内的废水零排放,回收的能源占恒力集团能源年消耗量的9.4%,年产生效益约4820万元。组团式水热能综合利用的思路为当前我国各行业的节能减排提供了一种新模式。 相似文献