全文获取类型
收费全文 | 9202篇 |
免费 | 668篇 |
国内免费 | 3497篇 |
专业分类
安全科学 | 869篇 |
废物处理 | 546篇 |
环保管理 | 758篇 |
综合类 | 5559篇 |
基础理论 | 1484篇 |
环境理论 | 2篇 |
污染及防治 | 2918篇 |
评价与监测 | 453篇 |
社会与环境 | 387篇 |
灾害及防治 | 391篇 |
出版年
2024年 | 35篇 |
2023年 | 201篇 |
2022年 | 544篇 |
2021年 | 531篇 |
2020年 | 483篇 |
2019年 | 378篇 |
2018年 | 424篇 |
2017年 | 526篇 |
2016年 | 480篇 |
2015年 | 554篇 |
2014年 | 758篇 |
2013年 | 1003篇 |
2012年 | 821篇 |
2011年 | 837篇 |
2010年 | 645篇 |
2009年 | 582篇 |
2008年 | 614篇 |
2007年 | 575篇 |
2006年 | 467篇 |
2005年 | 323篇 |
2004年 | 245篇 |
2003年 | 271篇 |
2002年 | 242篇 |
2001年 | 211篇 |
2000年 | 227篇 |
1999年 | 238篇 |
1998年 | 210篇 |
1997年 | 191篇 |
1996年 | 180篇 |
1995年 | 128篇 |
1994年 | 121篇 |
1993年 | 86篇 |
1992年 | 66篇 |
1991年 | 42篇 |
1990年 | 29篇 |
1989年 | 21篇 |
1988年 | 12篇 |
1987年 | 8篇 |
1986年 | 10篇 |
1985年 | 4篇 |
1984年 | 7篇 |
1983年 | 7篇 |
1982年 | 8篇 |
1981年 | 7篇 |
1978年 | 2篇 |
1973年 | 5篇 |
1972年 | 1篇 |
1971年 | 1篇 |
1969年 | 1篇 |
1957年 | 1篇 |
排序方式: 共有10000条查询结果,搜索用时 265 毫秒
441.
以模拟印染废水和实际印染废水为实验对象,检验了一种新合成有机-无机复合絮凝剂(PST)的絮凝效果。结果表明,PST具有良好的絮凝性能。在受试条件下,絮凝效果与絮凝剂投加量、染料浓度有较大相关性。废水的pH值应用范围较宽;搅拌时间对COD去除率和脱色率没有显著影响。采用PST处理广东省高明市某印染厂的印染废水后,COD去除率为75.16%,脱色率为76.18%,处理效果良好,处理成本明显低于目前市场上普遍使用的聚铝等絮凝剂。 相似文献
442.
生活污水水质对处理工艺的选择、设计参数的选取以及稳定运行十分重要。运用SPSS软件,对四川某中小城镇污水处理厂为期一年的进水指标(水量、COD、氨氮、总磷、pH、SS)进行方差和相关性分析。方差分析结果显示进水量、氨氮和SS在月份和季节之间存在显著性差异,而总磷和pH仅在月份之间存在显著差异,COD在季度和月份之间无显著性差异;指标相关性分析表明,进水量和氨氮之间呈负相关,氨氮和总磷、COD和总磷之间呈正相关,且相关性显著。在此分析的基础上对污水处理厂设计、工艺选择及运行管理提出了一些建议。 相似文献
443.
Shiping Zhou Changqun Duan Wong Hang Gi Michelle Fazhong Yang Xuehua Wang 《环境科学学报(英文版)》2011,23(4):676-680
Toxicities were assessed for a pyrethroid (cypermethrin) and an organophosphate insecticide (chlorpyrifos) individually and in
combination. A series of tests were conducted on di erent responses (acute, chronic, behavioral) of earthworms of species Eisenia
fetida andrei in the ecological risk assessment of these pesticides. The results showed that the toxicity of the mixture of cypermethrin
and chlorpyrifos was significantly higher than either of these pesticides individually, especially on the earthworm’s chronic responses.
At a concentration of 5 mg/kg, the mixture caused significant reductions on the growth and reproduction rates of earthworms, but did
not cause any significant e ect when the individual was tested. The increase in toxicity of the pesticide mixture means that the use of
toxicity data obtained exclusively from single-pesticide experiments may underestimate the ecological risk of pesticides that actually
present in the field. 相似文献
444.
Chemical forms of Zn, Ni, Cu, and Pb in municipal sewage sludge were investigated by adding humus soil to sludge and by
performing sequential extraction procedures. In the final sludge mixtures, Zn and Ni were mainly found in Fe/Mn oxide-bound (F3) and
organic matter/sulfide-bound (F4) forms. For Zn, exchangeable (F1), carbonate-bound (F2), and F3 forms were transformed to F4 and
residual forms (F5). For Ni, F1 and F2 forms were transformed to F1, F2, and F3 forms. Both Cu and Pb were strongly associated with
the stable forms F4 and F5. For Cu, F2 and F3 forms were major contributors, while for Pb, F3 and F4 forms were major contributors to
F5. Humus soil dosage and pH conditions in the sludge were strongly correlated with the forms of heavy metals. Five forms were used
to evaluate metal mobilities in the initial and final sludge mixtures. The mobilities of the four heavy metals studied decreased after 28
days. The metal mobilities in the final sludge mixtures were ranked in the following order: Ni > Zn > Cu = Pb. Leaching tests showed
that the mobilities of Zn and Ni in lower pH conditions (pH 4) were higher than those in higher pH conditions (pH 8). 相似文献
445.
Potential particulate pollution derived from UV-induced degradation of
odorous dimethyl sulfide 总被引:1,自引:0,他引:1
UV-induced degradation of odorous dimethyl sulfide (DMS) was carried out in a static White cell chamber with UV irradiation. The
combination of in situ Fourier transform infrared (FT-IR) spectrometer, gas chromatograph-mass spectrometer (GC-MS), wide-range
particle spectrometer (WPS) technique, filter sampling and ion chromatographic (IC) analysis was used to monitor the gaseous and
potential particulate products. During 240 min of UV irradiation, the degradation e ciency of DMS attained 20.9%, and partially
oxidized sulfur-containing gaseous products, such as sulfur dioxide (SO2), carbonyl sulfide (OCS), dimethyl sulfoxide (DMSO),
dimethyl sulfone (DMSO2) and dimethyl disulfide (DMDS) were identified by in situ FT-IR and GC-MS analysis, respectively.
Accompanying with the oxidation of DMS, suspended particles were directly detected to be formed by WPS techniques. These
particles were measured mainly in the size range of accumulation mode, and increased their count median diameter throughout
the whole removal process. IC analysis of the filter samples revealed that methanesulfonic acid (MSA), sulfuric acid (H2SO4) and
other unidentified chemicals accounted for the major non-refractory compositions of these particles. Based on products analysis and
possible intermediates formed, the degradation pathways of DMS were proposed as the combination of the O(1D)- and the OH- initiated
oxidation mechanisms. A plausible formation mechanism of the suspended particles was also analyzed. It is concluded that UV-induced
degradation of odorous DMS is potentially a source of particulate pollutants in the atmosphere. 相似文献
446.
Soonchul Kwon Maohong Fan Herbert F. M. DaCost Armistead G. Russell 《环境科学学报(英文版)》2011,23(8):1233-1239
Olivine, one of the most abundant minerals existing in nature, is explored as a CO2 carbonation agent for direct carbonation of
CO2 in flue gas. Olivine based CO2 capture is thermodynamically favorable and can form a stable carbonate for long-term storage.
Experimental results have shown that water vapor plays an important role in improving CO2 carbonation rate and capacities. Other
operation conditions including reaction temperature, initial CO2 concentration, residence time corresponding to the flow rate of CO2
gas stream, and water vapor concentration also considerably affect the performance of the technology. 相似文献
447.
The aim of the present work was to produce a polyaluminium ferric silicate chloride (PAFSiC) coagulant from acidic and alkaline
wastewater of purifying graphite by roasting, and subsequently to evaluate coagulation efficiency of the reagent by treating surface
water from the Yellow River as well as municipal wastewater in comparison with the conventional coagulant polyaluminium chloride
(PAC). The PAFSiC coagulant was prepared by co-polymerization. The effects of (Al+Fe)/Si molar ratio, OH/(Al+Fe) molar ratio (i.e.,
value), coagulant dosage and pH value of test suspension on the coagulation behavior of FAFSiC and the stability of the PAFSiC were
also examined. Results showed that PAFSiC performed more efficiently than PAC in removing turbidity, chemical oxygen demand
(COD), and total phosphate (TP). The PAFSiC with a
value of 2.0 and (Al+Fe)/Si ratio of 5 (PAFSiC 2.0/5) showed excellent
coagulation effect for both turbidity and COD, while PAFSiC 1.0/5 was the best for TP. The optimum coagulation pH range of PAFSiC
2.0/5 was 5.0–9.0, slightly wider than that of PAC (6.0–8.0). The process can be easily incorporated into high-purity graphite production
plants, thereby reducing wastewater pollution and producing a valuable coagulant. 相似文献
448.
449.
Preliminary report on methane emissions from the Three Gorges Reservoir in the summer drainage period 总被引:3,自引:0,他引:3
Fei Lu Le Yang Xiaoke Wang Xiaonan Duan Yujing Mu Wenzhi Song Feixiang Zheng Junfeng Niu Lei Tong Hua Zheng Yongjuan Zhou Jiangxiao Qiu Zhiyun Ouyang 《环境科学学报(英文版)》2011,23(12):2029-2033
Considerable variations may exist in CH4 emissions from the Three Gorges Reservoir. 相似文献
450.
针对黄浦江源水砂滤出水,进行了紫外线单独作用的研究,同时对于紫外线与消毒剂联合消毒时消毒剂的投加方式对灭菌作用和消毒副产物的影响进行了研究。实验结果表明:当紫外线剂量达到42 mJ/cm2时出水水质已达到了生活饮用水卫生标准中对细菌总数和大肠杆菌数的要求,且在相同紫外剂量下,高强度时对细菌的灭活效果要好于低强度时的效果;先紫外消毒后消毒剂消毒对于微生物具有很好的杀灭作用,但是不能减少消毒副产物的产生;紫外线和消毒剂同时作用对于微生物的杀灭作用不佳,但是出水的消毒剂余量高,消毒副产物量少,这样有利于出水的安全稳定性;先消毒剂消毒再紫外消毒,发现对于消毒副产物没有多大的降解作用,更浪费了高的紫外剂量。 相似文献