基于人工免疫原理的事故预防研究

介绍生物免疫识别模式,分析事故预防过程的实质是抑制潜在危险转化成事故的控制过程,分析比较事故预防与生物免疫识别模式在作用、生存环境、动作触发源等的共性,构建了基于免疫识别模式的事故预防系统并建立了事故预防数学模型;定义事故预防系统的识别率、失效率、误判率并给出了数学表达式,指出监测生产系统各环节状态信息是否符合系统的安全要求就是识别潜在危险的过程,是事故预防的关键,基于人工免疫原理的事故预防数学模型具有较强的健壮性、自适应性和动态防护性等特点。     

关于加强全国环境监测站建设的思考

在分析现状的基础上,提出了加强全国环境监测站建设的对策与建议。     

"九五"期间乌鲁木齐市交通噪声的控制措施及效果

在分析交通噪声影响因素的基础上,对乌鲁木齐市近十年控制交通噪声污染的措施和效果进行了探讨。     

星形大分子液晶在气相色谱分析中的应用研究

将首次合成的偶氮苯硅氧烷类星形液晶大分子化合物用于毛细管柱气相色谱固定液 ,在其相转变温度附近具有良好的选择性 ,成功地分离了二甲酚异构体。     

新疆二噁英类POPs排放现状调查及分析

在对新疆二噁英类POPs排放调查的基础上,归纳了新疆二噁英类污染物的主要来源和分布情况,分析了新疆二噁英类POPs排放源在环境监管中存在的问题,并提出了相应的建议,对今后新疆二噁英类POPs排放的管理、控制和削减有重要意义。     

2008年我国环境保护投资总体特征分析

立足于环保投资数据库,从投资构成、空间分布和行业分布3个方面对我国环保投资进行综合分析。2008年,全国环保投资增幅持续保持较快增长,环保投资弹性系数为1.9,环保投资增速大大超过经济增速,"三同时"项目成为拉动环保投资的主要驱动力。引入了环保投资平衡度的概念,在此基础上对各地区环保投资的合理性进行了初步分析。重点行业环保投资方面,工业治污设施运行费用远远大于同期固定资产投资,一定程度上说明了应对治污运行费用来源给予充分重视,采取措施确保稳定可靠的资金渠道。     

QSARs for the toxicity of polychlorinated dibenzofurans through DFT-calculated descriptors of polarizabilities, hyperpolarizabilities and hyper-order electric moments

DFT-B3LYP method with 6-31G(**) basis set was employed to fully optimize the electronic structures of 135 polychlorinated dibenzofurans and parent compound, namely dibenzofuran. It was demonstrated that polarizability anisotropy and mean polarizability could change sensitively and systematically with chlorine number and substitution pattern. And new quantitative structure-activity relationships (QSARs) focused on the binding affinities of aryl hydrocarbon receptor (AhR), aryl hydrocarbon hydroxylase (AHH) and 7-ethoxyresorufin O-deethylase (EROD) induction potencies of PCDFs were developed. It was concluded that polarizability anisotropy in conjunction with hyperpolarizabilties and hyper-order electric moments, e.g. octupole moments could well interpret the variation of toxicity of different congeners and dispersion interaction should be the leading form among various interactions. Although the terms of hyperpolarizabilities and hyper-order electric moments were not the same significant ones as polarizability anisotropy, the long-range interactions characterized by them should not be ignored in explaining the toxicity.     

Influence of metal ion on sorption of p-nitrophenol onto sediment in the presence of cetylpyridinium chloride

Heavy metals and surfactants have a significant effect on the sorption of organic contaminants. In this study, batch equilibrium experiments were carried out to investigate the influence of Pb(NO(3))(2) on the sorption of p-nitrophenol (PNP) onto sediments in the presence of cationic surfactant cetylpyridinium chloride (CPC). Results indicated that in the complex system containing PNP, Pb(NO(3))(2) and CPC, the sorption of PNP decreased with increasing concentration of Pb(NO(3))(2) due primarily to competing for adsorption sites. Likewise, partitioning of PNP in adsorbed surfactant layers and micelles decreased with increasing level of Pb(NO(3))(2). Moreover, the influence of different metal ions (Pb(2+), Cd(2+), Zn(2+)) was examined and results indicated that the presence of heavy metals inhibited the sorption of PNP in the order: Pb(2+)>Cd(2+)>Zn(2+). The competitive effect of the heavy metals was in agreement with the hydration energy and hydrated radius. The results are believed to provide a useful insight into describing the transport and fate of PNP in natural environments.     

Isolation and characterization of 1,2,4-trichlorobenzene mineralizing Bordetella sp. and its bioremediation potential in soil

A soil which has been polluted with chlorinated benzenes for more than 25 years was used for isolation of adapted microorganisms able to mineralize 1,2,4-trichlorobenzene (1,2,4-TCB). A microbial community was enriched from this soil and acclimated in liquid culture under aerobic conditions using 1,2,4-TCB as a sole available carbon source. From this community, two strains were isolated and identified by comparative sequence analysis of their 16S-rRNA coding genes as members of the genus Bordetella with Bordetella sp. QJ2-5 as the highest homological strain and with Bordetella petrii as the closest related described species. The 16S-rDNA of the two isolated strains showed a similarity of 100%. These strains were able to mineralize 1,2,4-TCB within two weeks to approximately 50% in liquid culture experiments. One of these strains was reinoculated to an agricultural soil with low native 1,2,4-TCB degradation capacity to investigate its bioremediation potential. The reinoculated strain kept its biodegradation capability: (14)C-labeled 1,2,4-TCB applied to this inoculated soil was mineralized to about 40% within one month of incubation. This indicates a possible application of the isolated Bordetella sp. for bioremediation of 1,2,4-TCB contaminated sites.     

Bioavailability to grains of rice of aged and fresh DDD and DDE in soils

DDT had been widely used around the world before 1980s and is still under production and use for non-agricultural purposes in China. Because of their special physicochemical properties, p,p'-DDT and its main metabolites, p,p'-DDD and p,p'-DDE, accumulated and persisted in the environment, presenting potential menace on biota. A green-house study was conducted to determine the bioavailability of p,p'-DDD and p,p'-DDE to grains of rice and the influences of traditional Chinese farming practices on their bioaccumulation. Paddy rice and dry rice were grown in submerged paddy soils and non-submerged upland soils, respectively. Two types of soil, Hydragric Anthrosols (An) and Hydragric Acrisols (Ac), were employed. Bioaccumulation factors (BAFs) of DDE ranged from 0.67 for rice grown in non-submerged An to 0.84 in submerged An in the control group, whilst BAFs were all below 0.04 in experimental groups. BAFs of DDD varied from 1.39 for submerged An to 2.26 for submerged Ac in original soils. In contrast, BAFs were between 0.05 for non-submerged Ac and 0.08 for submerged An in DDD-contaminated soils. Flooding seemed to have two contradictory effects on the DDE/DDD accumulation by rice: on one hand, it made the pollutants more mobile and bioavailable; while on the other hand, it enhanced the degradation and binding of POPs. Adding rice straw to the soils protected DDE from being taken up yet promoted DDD accumulation by rice. Furthermore, the distinct inorganic component of the soils might also play an important role in the environmental activities of POPs.