排序方式: 共有42条查询结果,搜索用时 218 毫秒
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装配式建筑精装修可能会应用甲醛、苯、氡气、氨气和TVOC等大量有害物质,从而产生空气污染、光污染、噪声污染、水污染等,严重影响室内环境,危害人体健康,虽然国家下发相关条例,效果并不显著。对装配式建筑精装修如何污染室内环境进行研究,分别分析了甲醛、苯、氡气、氨气和TVOC这些装修材料的危害能力、对室内环境的污染能力以及对人体健康的损害,通过研究发现装修材料会造成严重污染,必须要加以重视,采取一定措施治理,营造出一个舒适的生活环境。 相似文献
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The interaction of Zn and Cu with dissolved organic matter (DOM) is a significant physicochemical process affecting their sorption as well as mobility in soil. The objective of this study was to examine the influence of DOM from corn straw on the sorption of Zn and Cu by loess through batch adsorption technique. The sorption isotherms of Zn and Cu could be well described by the Freundlich equation, and the partition distribution coefficient (k) in the presence of DOM was reduced by 86% for Zn and 58% for Cu, as compared to the control receiving no DOM, suggesting that DOM had a stronger inhibitory effect on Zn sorption than that of Cu. In addition, the sorption of metal increased with an increase in pH for loess, with maximum inhibition on metal sorption observed at pH > 7.6 for Zn and pH > 5.5 for Cu in the absence ofDOM but Cu sorption of DOM was suddenly decreased with an increase of pH at pH > 7.9 in the presence of DOM. At a DOM concentration of <200 mg L?1, sorption of Zn and Cu was reduced by 46% for Zn and 32% for Cu with an increase in DOM concentration. 相似文献
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Xiaoyan Zhang Yaoguo Wu Sihai Hu Cong Lu Hairui Yao 《Environmental science and pollution research international》2014,21(13):8271-8283
Soil organic matter (SOM) releasing with dissolved organic matter (DOM) formed in solution was confirmed in a sediment/water system, and the effects of SOM releasing on the sorption of phenanthrene on sediments were investigated. Inorganic salt (0–0.1 mol L?1 NaCl) was used to adjust SOM releasing, and two sediments were prepared, the raw sediment (S1) from Weihe River, Shann’xi, China, and the eluted sediments with and without DOM supernatant remained, termed as S2a and S2b, respectively. The FTIR and 1H NMR analysis indicate that the low molecular weight hydrophilic SOM fraction released prior to the high molecular weight hydrophobic fraction. As a response, phenanthrene sorption kinetics on S1 showed atypical and expressed as three stages: rapid sorption, pseudo sorption with partial desorption, and slow sorption, thus a defined “sorption valley” occurred in kinetic curve. In all cases, partition dominates the sorption, and sorption capacity (Kd) ranked as S2b > S1 > S2a. Compared with the alterations of sediment characters, DOM solubilization produced by SOM releasing exhibited a greater inhibitory effect on sorption with a relative contribution of 0.67. Distribution coefficients (Kdoc) of PHE into DOM clusters were 2.10?×?104–4.18?×?104 L kg?1, however a threshold concentration of 6.83 mg L?1 existed in DOM solubilization. The study results will help to clarify PAHs transport and their biological fate in a sediment/water system. 相似文献
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淄博孝妇河流域孔隙水流酸盐污染特征及其形成 总被引:1,自引:0,他引:1
分析1989~1996年孔隙水的化学资料,总结出了研究区孔隙水硫酸盐污染的特点,借助原状土柱试验探明,孔隙水中污染组分来源于农业灌溉污水。农灌的频率与强度及大气降水的特点共同决定了本区孔隙水污染特征的形成。因此,停止或减少污灌量是改善地下水环境的有效且经济的方法。 相似文献
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Chemical properties of dissolved organic matter derived from sugarcane rind and the impacts on copper adsorption onto red soil 总被引:1,自引:0,他引:1
Sihai Hu Yaoguo Wu Na Yi Shuai Zhang Yuanjing Zhang Xu Xin 《Environmental science and pollution research international》2017,24(27):21750-21760
Dissolved organic matter (DOM), as the most active organic carbon in the soil, has a coherent affinity with heavy metals from inherent and exogenous sources. Although the important roles of DOM in the adsorption of heavy metals in soil have previously been demonstrated, the heterogeneity and variability of the chemical constitution of DOM impede the investigation of its effects on heavy metal adsorption onto soil under natural conditions. Fresh DOM (FDOM) and degraded DOM (DDOM) from sugarcane rind were prepared, and their chemical properties were measured by Fourier-transform infrared spectrometry (FTIR), excitation-emission matrix (EEM) fluorescence spectroscopes, nuclear magnetic resonance (NMR), and molecular weight distribution (MWD). They were also used in batch experiments to evaluate their effects on the adsorption of Cu(II) onto farmland red soil. Based on our results, the chemical structure and composition of DDOM greatly varied; compared with FDOM, the C/O ratio (from 24.0 to 9.6%) and fluorescence index (FI) (from 1.4 to 1.0) decreased, and high molecular weight (>10 kDa) compounds increased from 23.18 to 70.51%, while low molecular weight (<3 kDa) compounds decreased from 56.13 to 12.13%; aromaticity and humification degree were markedly enhanced. The discrepancy of FDOM and DDOM in terms of chemical properties greatly influenced Cu(II) adsorption onto red soil by affecting DOM-Cu(II) complex capacity. The FDOM inhibited the adsorption of Cu(II), while DDOM promoted adsorption, which was significantly influenced by soil pH. Maximum adsorption capacity (Q m) was 0.92 and 5.76 mg g?1 in the presence of FDOM and DDOM, respectively. The adsorption process with DDOM could be better described by the Langmuir model, while that with FDOM was better described by the Freundlich model. The impacts caused by the dynamic changes of the chemical properties of DOM under natural conditions should therefore be considered in the risk assessment and remediation of soils contaminated with heavy metals. 相似文献
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有机碳与水合金属氧化物对反硝化条件下河流沉积层中苯胺降解的影响 总被引:3,自引:1,他引:3
采集渭河沉积物及西安某自备井的地下水,沉积物采用逐级分离法处理后,进行厌氧微宇宙实验,研究反硝化条件下河流沉积层中苯胺降解及有机碳与水合金属氧化物的影响.结果表明,硝酸盐为50、300或400mg·L-1,沉积物中的原有或外加的有机碳都对苯胺降解具有抑制作用;去碳沉积物、去碳去金属沉积物实验中,硝酸盐为50mg·L-1时,外加有机碳具有抑制作用,当硝酸盐为300或400 mg·L-1时则有促进作用.去碳沉积物与去碳去金属沉积物的实验发现,无论是否有外加有机碳,水合金属氧化物都对河床沉积层中反硝化条件下苯胺降解具有促进作用.机理分析表明,反硝化条件下,河流沉积层中的微生物以生长代谢的方式利用苯胺,使其降解.苯胺降解经过脱氨基过程. 相似文献
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