Technology innovations and experience curves for nitrogen oxides control technologies

This paper reviews the regulatory history for nitrogen oxides (NOx) pollutant emissions from stationary sources, primarily in coal-fired power plants. Nitrogen dioxide (NO2) is one of the six criteria pollutants regulated by the 1970 Clean Air Act where National Ambient Air Quality Standards were established to protect public health and welfare. We use patent data to show that in the cases of Japan, Germany, and the United States, innovations in NOx control technologies did not occur until stringent government regulations were in place, thus "forcing" innovation. We also demonstrate that reductions in the capital and operation and maintenance (O&M) costs of new generations of high-efficiency NOx control technologies, selective catalytic reduction (SCR), are consistently associated with the increasing adoption of the control technology: the so-called learning-by-doing phenomena. The results show that as cumulative world coal-fired SCR capacity doubles, capital costs decline to approximately 86% and O&M costs to 58% of their original values. The observed changes in SCR technology reflect the impact of technological advance as well as other factors, such as market competition and economies of scale.     

Geostatistical analysis of soil hydrologic properties in a field plot

A 91-m transect was set up in an irrigated field near Las Cruces, New Mexico to obtain soil water tension and water content data to investigate their spatial variability. A total of 455 sampling points were monitored along a grid consisting of 91 stations placed 1 m apart by 5 depths per station (at 0.3, 0.6, 0.9, 1.2 and 1.5 m below the surface). Post-irrigation tension and wetness measurements were recorded over 45 days at 11 time periods. Soil water tension was measured with tensiometers using a hand-held pressure transducer. A neutron probe was used to obtain volumetric water content. Using the observed wetness and tension data, unsaturated hydraulic conductivity values were derived (using a cubic spline function to estimate the gradient), and an exponential model was used to fit the calculated conductivity-tension curves to obtain hydraulic conductivity parameter values. The spatial and temporal variability of wetness, tension, saturated hydraulic conductivity and pore-size distribution parameters, and texture at the 0.3-m depth were examined using geostatistical techniques.The exponential model was found to inadequately describe the hydraulic conductivity/tension relationship for the full range of tension, particularly in the tension range near saturation. The derived values of the saturated hydraulic conductivity parameter were much greater than expected and do not correspond to reasonable saturated hydraulic conductivity values.All of the soil parameters studied exhibited large spatial variability horizontally and vertically in the field. Ranges of dependence determined from semivariogram analysis over the 44-day drainage period are 3–32 m for wetness, 6–34 m for soil water tension, 5–35 m for natural log of saturated hydraulic conductivity parameters, 5–11 m for pore-size distribution parameter, and 8–24 m for percent sand, silt and clay at the 0.3 m depth. An alternate hole-effect model is suggested to describe the texture semivariograms.It was determined that the variance of volumetric water content generally increased at each depth over the measured time periods, which is consistent with certain past field studies and a stochastic analysis of unsaturated flow in heterogeneous soils. Future research is recommended relating soil texture to soil hydrologic parameters with the goal of predicting soil behavior with less extensive sampling schemes.     

MODEL DEVELOPMENT FOR CONJUNCTIVE USE STUDY OF THE SAN JACINTO BASIN,CALIFORNIA1

ABSTRACT: A two-layered confined-unconfined numerical model for flow and mass transport is developed for the San Jacinto Basin. The model structure is determined by the geological structure of the Basin and model parameters are calibrated using 20 years of historical records. The total number of historical head observations used for the flow model calibration is 1,117 and the total number of the estimated parameters is 91. The two-layered transport model is also calibrated using historical water quality records. Sensitivity analysis of the flow model shows that only 68 parameters (out of a total of 91) are relatively sensitive and reliable. However, the unreliable parameters (23 of them) are found to be insensitive and thus not significant to the prediction and management of conjunctive use of surface water and ground water. The developed flow model has been used to study the two proposed artificial recharge scenarios for the San Jacinto Basin. We have found that during a relatively dry condition, an artificial recharge rate of 80 acre-ft/day can be achieved during the recharge period October through January. However, for a relatively wet condition, only 80 percent of the proposed rate can be effectively stored in the Basin during these months.     

Karst Hydrological Processes and Grey System Model1

Hao, Yonghong, Jiaojuan Zhao, Huamin Li, Bibo Cao, Zhongtang Li, and Tian‐Chyi J. Yeh, 2012. Karst Hydrological Processes and Grey System Model. Journal of the American Water Resources Association (JAWRA) 48(4): 656‐666. DOI: 10.1111/j.1752‐1688.2012.00640.x Abstract: The karst hydrological processes are the response of karst groundwater system to precipitation. This study provided a concept model of karst hydrological processes. The hydraulic response time of spring discharge to precipitation includes the time that precipitation penetrates through the vadose zone, and the subsequent groundwater pressure wave propagates to a spring outlet. Due to heterogeneities in karst aquifers, the hydraulic response time is different in different areas. By using grey system theory, we proposed a karst hydrological model that offers a calculation of hydraulic response time, and a response model of spring discharge to precipitation. Then, we applied the models to the Liulin Springs Basin, China. In the south part of the Liulin Springs Basin, where large fields of carbonate rocks outcrop with intensive karstification, the hydraulic response time is one year. In the north, where the Ordovician karst aquifer is covered by Quaternary loess sediments, the response time is seven years. The grey system GM(1,3) response model of spring discharge to precipitation was applied in consideration of the hydraulic response time. The model calibration showed that the average error was 6.55%, and validation showed that the average error was 12.19%.     

COMPARATIVE STUDY OF DROUGHT PREDICTION TECHNIQUES FOR RESERVOIR OPERATION1

ABSTRACT: Predicting the likelihood of a drought markedly enhances the efficiency of reservoir operations. This study applies the kriging method and time series analysis to predict inflows to Shihmen Reservoir in northern Taiwan. A subsequent reservoir operation simulation is employed to determine the drought lead time (DLT), the time before the onset of a drought. A more efficient reservoir operational strategy can be established with the aid of DLT and the probability of successful drought prediction (P s). Simulation results of reservoir operation over a period of three decades demonstrate that, at one month DLT, the kriging approach achieves 0.86 of P s for moderate droughts and 0.94 of P s for severe droughts. The kriging approach generally outperformed the time series approach in terms of DLT, P s of drought prediction, and the number of correctly predicted drought events.     

Paeonol promotes arylamine N‐acetyltransferase activity in human bladder tumor cells

Paeonol was used to determine effects of arylamine N‐acetyltransferase (NAT) activity in human bladder tumor cells. The NAT activity was measured by high performance liquid chromatography assaying for the amounts of N‐acetyl‐2‐aminofluorene (2‐AAF) and N‐acetyl‐p‐amino‐benzoic acid (N‐Ac‐PABA) and remaining 2‐aminofluorene (2‐AF) and p‐aminobenzoic acid (PABA). The NAT activity in human bladder tumor cells was promoted by paeonol in a dose‐dependent manner, i.e. the higher the concentration of paeonol, the higher the promotion of NAT activity. The data also indicated that paeonol increases the apparent values of K_m and K_max from human bladder tumor cells in cytosols and intact cells. This report is the first demonstration to show paeonol did promote human bladder tumor cell NAT activity.     

Metabolism of shallow and deep-sea benthic crustaceans and echinoderms in Hawaii

Little is known about the metabolism of deep-living, benthic invertebrates, despite its importance in estimating energy flow through individuals and populations. To evaluate the effects of depth and broad taxonomic group/locomotory mode, we measured the respiration rates of 25 species of benthic decapod crustaceans and 18 species of echinoderms from the littoral zone to the deep slope of Hawaii. Specimens were collected by hand, trap, or submersible and maintained in the laboratory at temperatures close to ambient temperatures recorded at the time of collection. After acclimatization to laboratory conditions, oxygen consumption was measured for each individual in closed chambers. Overall, crustaceans had higher metabolic rates than echinoderms, and within the crustaceans, caridean shrimps had higher rates than crabs and lobsters. These differences are probably related to locomotory mode and general levels of activity. At in situ environmental temperatures, metabolic rates of deeper-living invertebrates are much lower than those of shallower living species, but this decline is explained by changes in temperature. When the data were compared with similar data sets collected off California and in the Mediterranean, Hawaiian crabs, lobsters, and echinoderms had lower metabolic rates than similar species in the other regions after adjustments for temperature were made. Some of these differences could be methodological. Regional food web models should use broad taxonomic groupings and region-specific data when possible.