热分解技术在修复多氯联苯污染土壤中的应用

针对我国土壤中PCBs的污染特点,介绍了一种修复土壤的热分解技术,并详述了该技术的工作流程、影响因素、处理效率等问题。最后对该技术的发展趋势进行了展望,并对其在推广过程中可能遇到的困难进行了分析。     

燃煤电厂SCR烟气脱硝技术的研究

选择性催化还原(SCR)技术是目前燃煤电厂应用最多且最成熟的烟气脱硝技术.介绍了SCR烟气脱硝技术的化学反应机理、工艺流程等,重点对影响SCR法脱硝效率的多种因素进行了深入分析,并对SCR技术的未来研究方向进行了展望.     

生化需氧量测定的方法改进

生化需氧量测定中接种液的制备和稀释倍数的确定是2个关键的步骤,本文提出一种可行的制备接种液的方法,根据实践经验,总结出一种稀释倍数计算方法,适合在实际分析中使用。     

Investigation of heavy metals in sediments and Manila clams Ruditapes philippinarum from Jiaozhou Bay, China

Manila clams (Ruditapes philippinarum) and sediments were collected bimonthly during 2007 at five locations in Jiaozhou Bay near Qingdao, China, to determine heavy metal concentrations and to assess the validation of R. philippinarum as a metal biomonitor. Concentrations of heavy metals in clam soft tissues ranged between 0.75 and 3.31, 0.89 and 15.20, 5.70 and 26.03, 52.12 and 110.33, 10.30 and 72.34, 9.64 and 28.60, and 3.15 and 52.75 μg g^???1 dry weight for Cd, Pb, Cu, Zn, Mn, Cr, and Ni, respectively. Most of the highest values occurred at the northeast bay and the lowest values occurred at the western part. Regarding seasonal variation, relatively high tissue metal concentrations were observed during October or December. A similar pattern was also found in habitat sediments. There was a strong correlation between the concentrations of Cd, Pb, Zn, Mn, Cr, and Ni in soft tissues and surrounding sediments. It is indicated that R. philippinarum could be used as a biomonitor for heavy metal contamination in Jiaozhou Bay.     

Heavy metals in bark of <Emphasis Type="Italic">Pinus massoniana</Emphasis> (Lamb.) as an indicator of atmospheric deposition near a smeltery at Qujiang,China

Goal, Scope and Background Rapid urbanization and the expansion of industrial activities in the past several decades have led to large increases in emissions of pollutants in the Pearl River Delta of south China. Recent reports have suggested that industrial emission is a major factor contributing to the damages in current natural ecosystem in the Delta area. Tree barks have been used successfully to monitor the levels of atmospheric metal deposition in many areas, but rarely in China. This study aimed at determining whether atmospheric heavy metal deposition from a Pb-Zn smeltery at Qujiang, Guangdong province, could be accurately reflected both in the inner bark and the outer bark of Masson pine (Pinus massoniana L.). The impact of the emission from smeltery on the soils beneath the trees and the relationships of the concentrations between the soils and the barks were also analyzed. Methods Barks around the bole of Pinus massoniana from a pine forest near a Pb-Zn smeltery at Qujiang and a reference forest at Dinghushan natural reserve were sampled with a stainless knife at an average height of 1.5 m above the ground. Mosses and lichens on the surface barks were cleaned prior to sampling. The samples were carefully divided into the inner bark (living part) and the outer bark (dead part) in the laboratory, and dried and ground, respectively. After being dry-ashed, the powder of the barks was dissolved in HNO₃. The solutions were analyzed for iron (Fe), manganese (Mn), copper (Cu), zinc (Zn), chromium (Cr), nickel (Ni) and cobalt (Co) by inductively coupled plasmas emission spectrometry (ICP, PS-1000AT, USA) and Cadmium (Cd) and lead (Pb) by graphite furnace atomic absorption spectrometry (GFAAS, ZEENIT 60, Germany). Surface soils (0–10 cm) beneath the sample trees were also collected and analyzed for the selected metals. Results and Discussion Concentrations of the selected metals in soils at Qujiang were far above their environmental background values in the area, except for Fe and Mn, whilst at Dinghushan, they were far below their background values, except for Cd and Co. Levels of the metals, in particular Pb and Zn, in the soils beneath the sample trees at Qujiang were higher than those at Dinghushan with statistical significance. The result suggested that the pine forest soils at Qujiang had a great input of heavy metals from wet and dry atmospheric deposition, with the Pb-Zn smeltery most probably being the source. Levels of Cu, Fe, Mn, Zn, Ni and Pb at Qujiang, both in the inner and the outer bark, were statistically higher than those at Dinghushan. Higher concentrations of Pb, Fe, Zn and Cu may come from the stem-flow of elements leached from the canopy, soil splash on the 1.5 m height and sorption of metals in the mosses and lichens growing on the bark, which were direct or indirect results from the atmospheric deposition. Levels of heavy metals in the outer barks were associated well with the metal concentrations in the soil, reflecting the close relationships between the metal atmospheric deposition and their accumulation in the outer bark of Masson pine. The significant (p<0.01) correlations of Fe-Cu, Fe-Cr, Fe-Pb, Fe-Ni, Pb-Ni, and Pb-Zn in the outer barks at Qujiang again suggested a common source for the metals. The correlation only occurred between Pb and Ni, Cd and Co in the outer barks at Dinghushan, which suggested that those metals must possibly have other uncommon sources. Conclusions Atmospheric deposition of the selected metals was great at Qujiang, based on the levels in the bark of Pinus massoniana and on the concentrations in the soils beneath the trees compared with that at Dinghushan. Bark of Pinus massoniana, especially the outer bark, was an indicator of metal loading at least at the time of sampling. Recommendations and Perspectives The results from this study and the techniques employed constituted a new contribution to the development of biogeochemical methods for environmental monitoring particularly in areas with high frequency of pollution in China. The method would be of value for follow up studies aimed at the assessment of industrial pollution in other areas similar with the Pearl River Delta.     

甲烷-煤尘复合火焰的传播与温度特征

为了揭示甲烷-煤尘复合体系的燃烧特征,利用高速摄像机、超细热电偶、显微镜头等对管道内甲烷-煤尘复合火焰的传播过程及其温度特征进行了试验研究.结果表明,随着煤尘浓度的增加,甲烷-煤尘复合火焰的最高温度及传播速度呈现先增大后减小的趋势; 对于甲烷-煤尘复合火焰,粒径较大的煤尘在较小的浓度达到最高温度,而粒径较小的煤尘则需要在较大的浓度达到最高温度.     

冬季自然通风对住宅室内空气品质的改善性能评价

为获得理想的自然通风方式,以改善寒冷地区住宅冬季室内空气品质、营造舒适的室内环境,采用现场实测和理论分析相结合的方法,对冬季自然通风中的室内外环境参数进行了测试,得到了室外环境参数、人工调节方式对室内环境参数及空气品质的影响特征; 针对舒适与健康的双重要求是寒冷地区住宅冬季通风的主要矛盾这一特点,分别采用临界温度、热舒适性、排污效率、人工调节便捷性等指标对不同方案的通风性能进行了评价.结果表明,采用18 ℃的临界温度可保证采暖所需的热能最低值,同时也有利于抑制甲醛、氨等的释放及挥发速率; 各房间的热舒适性均满足相关规范要求,即本文所列举的这4种方案在执行过程中并没有牺牲房间的热舒适性,只是稍微有些偏凉.方案6的排污效率最高,为88%,方案8次之,方案3最低.这与方案6中两进风口关于回风口对称布置,室内平均空气龄最短有关; 4种方案具有相同的人工调节便捷性.综合各方面因素,方案6为本文最佳通风方案.     

基于人工神经网络理论的建筑物火灾安全评价研究

依据建筑物火灾危险性的影响因素,应用人工神经网络理论及系统安全方法,建立了建筑物火灾危险性的评价指标体系,该方法摆脱了评价过程中的随机性和参评人员主观上的不确定性及其认识上的模糊性等缺点,大大提高了准确性。为了验证评价模型的准确性,将该理论应用到某高校图书馆火灾危险性评价中,快速、准确地得到了安全评价结果,取得了满意效果,为建筑物防火设计以及安全管理提供了可行的依据。     

浅谈外墙保温材料对建筑防火的影响

本文通过对几种外墙保温材料及国内外外墙保温技术的介绍,从中分析出引起建筑耐火极限降低的原因,找到在目前条件下,最适合外墙保温的材料及技术,以降低火灾的发生。     

再生白土无污染生产技术的研究

用低浓度的废酸水对废白土进行活化,并采用洗涤水循环漂洗的方法,对再生白土无污染生产技术进行研究,以期循环利用废白土,保护环境,节约资源。结果表明：废酸水浓度为15％,固液比1：3,酸化时间3h时,再生白土脱色率为98．0％。