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11.
12.
Photocatalytic oxidation of gas-phase elemental mercury by nanotitanosilicate fibers 总被引:1,自引:0,他引:1
Photocatalytic fibers were generated from the continuous evaporation of titanium tetraisopropoxide with tetraethyl orthosilicate through a flame burner. The morphology, the crystal form, and the components of the nanotitanosilicate fibers were analyzed by Raman spectroscopy, Field emission-scanning electron microscope, X-ray diffraction, and Brunauer-Emmett-Teller surface area analysis. The nanotitanosilicates prepared by three different carrier gases (air, N(2), and Ar) were tested for their photocatalytic ability to remove/oxidize gas-phase elemental mercury. Under UV black light, the Hg(0) capture efficiencies were 78%, 86%, and 85% for air, N(2), and Ar, respectively. For air, the value was close to 90%, even under household fluorescent light. The Hg(0) capture efficiency by nanotitanosilcate was measured under fluorescent light, UV black light, and sunlight. 相似文献
13.
Haozhi Long Yilin Wang Sijing Chang Guangxiu Liu Tuo Chen Guanghua Huo Wei Zhang Xiukun Wu Xisheng Tai Likun Sun Baogui Zhang 《Environmental monitoring and assessment》2017,189(3):116
The aim of this study was to survey the response of the microbial community to crude oil and the diversity of alkane hydroxylase (alkB) genes in soil samples from the Qinghai-Tibet Plateau (QTP). The enrichment cultures and clone libraries were used. Finally, 53 isolates and 94 alkB sequences were obtained from 10 pristine soil samples after enrichment at 10 °C with crude oil as sole carbon source. The isolates fell into the phyla Proteobacteria, Actinobacteria, and Bacteroidetes, with the dominance of Pseudomonas and Acinetobacter. The composition of degraders was different from polar habitats where Acinetobacter sp. is not a predominant responder of alkane degradative microbial communities. Phylogenetic analysis showed that the alkB genes from isolates and enrichment communities formed eight clusters and mainly related with alkB genes of Pseudomonas, Rhodococcus, and Acinetobacter. The alkB gene diversity in the QTP was lower than marine environments and polar soil samples. In particular, a total of 10 isolates exhibiting vigorous growth with crude oil could detect no crude oil degradation-related gene sequences, such as alkB, P450, almA, ndoB, and xylE genes. The Shannon-Wiener index of the alkB clone libraries from the QTP ranged from 1.00 to 2.24 which is similar with polar pristine soil samples but lower than that of contaminated soils. These results indicated that the Pseudomonas, Acinetobacter, and Rhodococcus genera are the candidate for in situ bioremediation, and the environment of QTP may be still relatively uncontaminated by crude oil. 相似文献
14.
15.
Pei-Yi Lin Yi-Ya Fang Su-Ping Wang Mei-Yun Tai Yuan-Feen Tsai 《Die Naturwissenschaften》2012,99(3):185-189
After extinction, the reappearance of a conditioned response induced by an unconditioned stimulus which is weaker than that
used during the conditioning training indicates that the extinction procedure does not eliminate the original conditioned
memory. Recent studies on fear conditioning have shown that rats exhibited little or no recovery of conditioned responding
if the time interval between fear acquisition and extinction was short, suggesting that the extinction process may erase the
original conditioning trace in this situation. In the present study, a saving experiment was conducted in rats to investigate
whether an aversive response could be recovered following extinction training with different time intervals after acquisition
of conditioned taste aversion (CTA). Male Long–Evans rats developed CTA by associating a 0.2% sucrose solution with malaise
induced by intraperitoneal injection of 4 ml/kg 0.15 M LiCl and were subjected to extinction training with an interval of
5 h (5H group) or 24 h (24H group) after acquisition of CTA. Rats in the 5H group, but not in the 24H group, exhibited no
aversive responding to the sucrose solution followed by the injection of a lower dose of LiCl (1 ml/kg). These findings indicate
that the extinction procedure administered at different time points following the acquisition of CTA affects recovery of extinguished
aversive memory and suggest that an unlearning process may be involved in the mechanisms of CTA extinction with short intervals
between acquisition and extinction. 相似文献
16.
A nonlinear least squares procedure and a log transformation procedure for calculating first-order rate coefficients from experimental concentration-versus-time data were compared using laboratory measurements of the volatilization from water of 1,1,1-trichloroethane and 1,2-dichloroethane and the absorption of oxygen by water. Ratios of the nonlinear least squares to log transformation volatilization and absorption coefficients for 77 tests ranged from 0.955 to 1.08 and averaged 1.01. Comparison of the maximum, minimum, and mean root-mean-square errors of prediction for six sets of coefficients showed that the errors for the nonlinear least squares procedure were almost always smaller than the errors for the log transformation procedure. 相似文献
17.
北京市大气PM2.5中矿物成分的污染特征 总被引:7,自引:1,他引:6
为了解北京市大气细粒子中矿物成分的浓度水平和污染特征,在清华园和车公庄进行了连续1a的PM2.5累积周采样和全样品分析.Al、Si、Ca、Mg和Fe等地壳元素的周变化相似,最大周均浓度均出现在春季有强沙尘天气的一周;其季节变化显著,显示季节性的源排放以及气象条件对矿物成分的含量影响显著.土壤尘的季节平均浓度从夏季逐步上升,至次年春季达到最高(21.1 μg·m-3),表明春季频繁发生的沙尘天气对土壤尘细粒子有重要贡献.大量的建筑活动可能大大增加了北京细粒子中Ca的负荷,应加强其排放控制. 相似文献
18.
Lee TG Hedrick E Biswas P 《Journal of the Air & Waste Management Association (1995)》2002,52(11):1316-1323
The kinetics of Hg chlorination (with HCl) was studied using a flow reactor system with an online Hg analyzer, and speciation sampling using a set of impingers. Kinetic parameters, such as reaction order (alpha), overall rate constant (k'), and activation energy (Ea), were estimated based on the simple overall reaction pathway. The reaction order with respect to C(Hg), k', and Ea were found to be 1.55, 5.07 x 10(-2) exp(-1939.68/T) [(microg/m3)(-055)(s)(-1)]. and 16.13 [kJ/ mol], respectively. The effect of chlorine species (HCl, CH2Cl2) on the in situ Hg capture method previously developed (28) was also investigated. The efficiency of capture of Hg by this in situ method was higher than 98% in the presence of chlorine species. Furthermore, under certain conditions, the presence of chlorine enhanced the removal of elemental Hg by additional gas-phase oxidation. 相似文献
19.
Fisheries catches are known to be widely underreported, and much of their value flows in informal markets. Goods and services that are not directly sold in a market also have a corresponding economic value, here termed ‘shadow value’, which can apply to discarded fish—or those that are consumed but not sold (e.g., subsistence catches). Here, we estimate the monetary value of fisheries catches in Panama that are landed but not reported, or that are discarded at sea; this includes catches from artisanal and industrial fleets, as well as recreational and subsistence fisheries. Based on available data, we estimate that the market and shadow value of unreported catches in Panama in 2010 was around US$92 million, equal to approximately 43% of the total reported landed value. In the case of discarded fish, the shadow value represents the potential but entirely unrealized economic benefit of landing such fish; in the case of unreported landings, unreported market value represents only the first link in the potentially sophisticated informal seafood economy. One must be careful in considering these results for policy. It is possible that, rather than seeking to capture these ‘lost’ benefits, fish that are discarded or unreported should not have been caught at all, for example, if they are juveniles or of threatened species; conversely, unreported subsistence catches are crucial for food security throughout the world. These results help contextualize the scale of unreported fisheries in economic terms, and can inform subsequent policies and strategies to ensure social, ecological, and economic sustainability. 相似文献
20.
环境问题已经引起世界各国政府和全社会的广泛关注。环境保护是利用环境科学的理论和方法,协调人类与自然环境的关系,以保护和改善环境的一切人类活动的总称。本文将首先分析由化学物质引起环境污染的案例,进而给出进行环境友好型的化学科学研究的方法及其重要性,以及通过化学科学的不断发展来解决业已存在的环境污染问题。 相似文献