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971.
能源是现代社会发展的重要基础,其在社会经济发展中占有不可替代的地位。以四川省统计年鉴及相关数据资料为基础,参考美国能流图绘制了四川省2010年的能流图,并对四川省2005~2010年间的能源输入、输出、消耗,以及相应的污染物排放进行了分析,分析发现:近年来能源消费总量增长迅速,年均增长率达10.8%,能源对外依存度较高,尤其是石油。能源消耗结构有待进一步优化,传统化石能源所占比重偏高,2010年达77.18%。同时构建了能源-社会经济-环境复合系统能流分析指标,分析了2005~2010年四川省能源、经济、环境两两子系统及三者系统之间的协调度,结果显示:四川省能源-经济-环境系统协调度不断上升,2010年三者综合协调度0.97238。最后根据能流分析、污染物排放水平、协调度分析等结果,提出了四川省能源发展战略、能流的优化管理、节能减排等对策建议。 相似文献
972.
973.
Xiaojiao Chen Minjian Chen Bo Xu Rong Tang Xiumei Han Yufeng Qin Bin Xu Bo Hang Zhilei Mao Weiwei Huo Yankai Xia Zhengfeng Xu Xinru Wang 《Chemosphere》2013
Widespread use of phenols has led to ubiquitous exposure to phenols. In experimental animals, phenols increased resorptions, reduced live litter size and fetal body weights. However, there are limited epidemiological evidences of the relationships between exposure to phenols and pregnancy outcomes. We evaluated the associations between parental urinary levels of various phenols and spontaneous abortion in a Chinese population residing in the middle and lower reaches of the Yangtze River. A case-control study was conducted that included 70 case couples with medically unexplained spontaneous abortion and 180 control couples who did not have a history of spontaneous abortion and had at least one living child. Both parental urinary phenols were measured by ultra-high performance liquid chromatography-tandem mass spectrometry including bisphenol A (BPA), benzophenone-3 (BP-3), 2,3,4-trichlorophenol (2,3,4-TCP), pentachlorophenol (PCP), 4-n-octylphenol (4-n-OP) and 4-n-nonylphenol (4-n-NP). Compared with the low exposure group, there was an increased risk of spontaneous abortion with high paternal urinary PCP concentration [odds ratio (OR) = 2.09, 95% Confidence Interval (CI), 1.05–4.14], and maternal exposure to 4-n-OP and alkylphenol(s) also significantly increased the risk of spontaneous abortion (OR = 2.21, 95% CI, 1.02–4.80; OR = 2.81, 95% CI, 1.39–5.65, respectively). Our study firstly provides the evidence that paternal PCP exposure, maternal 4-n-OP and alkylphenol(s) exposure are associated with spontaneous abortion in humans. 相似文献
974.
The goal of this study was to identify promising new biomarkers of phenanthrene by identifying differentially expressed proteins in Eisenia fetida after exposure to phenanthrene. Extracts of earthworm epithelium collected at days 2, 7, 14, and 28 after phenanthrene exposure were analyzed by two dimensional electrophoresis (2-DE) and quantitative image analysis. Comparing the intensity of protein spots, 36 upregulated proteins and 45 downregulated proteins were found. Some of the downregulated and upregulated proteins were verified by MALDI-TOF/TOF-MS and database searching. Downregulated proteins in response to phenanthrene exposure were involved in glycolysis, energy metabolism, chaperones, proteolysis, protein folding and electron transport. In contrast, oxidation reduction, oxygen transport, defense systems response to pollutant, protein biosynthesis and fatty acid biosynthesis were upregulated in phenanthrene-treated E. fetida. In addition, ATP synthase b subunit, lysenin-related protein 2, lombricine kinase, glyceraldehyde 3-phosphate dehydrogenase, actinbinding protein, and extracellular globin-4 seem to be potential biomarkers since these biomarker were able to low levels (2.5 mg kg−1) of phenanthrene. Our study provides a functional profile of the phenanthrene-responsive proteins in earthworms. The variable levels and trends in these spots could play a potential role as novel biomarkers for monitoring the levels of phenanthrene contamination in soil ecosystems. 相似文献
975.
Yingyi Zhang Senchao Lai Zhen Zhao Fobang Liu Hongwei Chen Shichun Zou Zhiyong Xie Ralf Ebinghaus 《Chemosphere》2013
An intensive campaign was conducted in September 2012 to collect surface water samples along the tributaries of the Pearl River in southern China. Thirteen perfluoroalkyl acids (PFAAs), including perfluorocarboxylates (PFCAs, C4–C11) and perfluorosulfonates (PFSAs, C4, C6–C8, and C10), were determined using high-performance liquid chromatography/negative electrospray ionization–tandem mass spectrometry (HPLC/(-)ESI–MS/MS). The concentrations of total PFAAs (ΣPFAAs) ranged from 3.0 to 52 ng L−1, with an average of 19 ± 12 ng L−1. The highest concentrations of ΣPFAAs were detected in the surface water of the Dong Jiang tributary (17–52 ng L−1), followed by the main stream (13–26 ng L−1) and the Sha Wan stream (3.0–4.5 ng L−1). Perfluorooctanoate (PFOA), perfluorobutane sulfonate (PFBS), and perfluorooctane sulfonate (PFOS) were the three most abundant PFAAs and on average accounted for 20%, 24%, and 19% of ΣPFAAs, respectively. PFBS was the most abundant PFAA in the Dong Jiang tributary, and PFOA was the highest PFAA in the samples from the main stream of the Pearl River. A correlation was found between PFBS and PFOA, which suggests that both of these PFAAs originate from common source(s) in the region. Nevertheless, the slope of PFBS/PFOA was different in the different tributaries sampled, which indicates a spatial difference in the source profiles of the PFAAs. 相似文献
976.
A human health risk assessment of rare earth elements in soil and vegetables from a mining area in Fujian Province,Southeast China 总被引:1,自引:0,他引:1
Contaminated food through dietary intake has become the main potential risk impacts on human health. This study investigated concentrations of rare earth elements (REEs) in soil, vegetables, human hair and blood, and assessed human health risk through vegetables consumption in the vicinity of a large-scale mining area located in Hetian Town of Changting County, Fujian Province, Southeast China. The results of the study included the following mean concentrations for total and bio-available REEs of 242.92 ± 68.98 (135.85–327.56) μg g−1 and 118.59 ± 38.49 (57.89–158.96) μg g−1 dry weight (dw) in agricultural soil, respectively, and total REEs of 3.58 ± 5.28 (0.07–64.42) μg g−1 dw in vegetable samples. Concentrations of total REEs in blood and hair collected from the local residents ranged from 424.76 to 1274.80 μg L−1 with an average of 689.74 ± 254.25 μg L−1 and from 0.06 to 1.59 μg g−1 with an average of 0.48 ± 0.59 μg g−1 of the study, respectively. In addition, a significant correlation was observed between REEs in blood and corresponding soil samples (R2 = 0.6556, p < 0.05), however there was no correlation between REEs in hair and corresponding soils (p > 0.05). Mean concentrations of REEs of 2.85 (0.59–10.24) μg L−1 in well water from the local households was 53-fold than that in the drinking water of Fuzhou city (0.054 μg L−1). The health risk assessment indicated that vegetable consumption would not result in exceeding the safe values of estimate daily intake (EDI) REEs (100−110 μg kg−1 d−1) for adults and children, but attention should be paid to monitoring human beings health in such rare earth mining areas due to long-term exposure to high dose REEs from food consumptions. 相似文献
977.
通过静态实验研究溴代十六烷基吡啶(CPB)改性沸石和天然沸石对废水中Hg^2+的吸附特性,探讨了吸附动力学、吸附平衡和吸附热力学机制。研究表明:Langmuir方程能较好地描述2种沸石对Hg^2+的吸附,CPB改性沸石对Hg^2+的吸附率得到显著提高。实验条件下,改性沸石对Hg^2+的吸附率从67.5%提高到98.9%,吸附容量从0.521mg/g提高到3.07mg/g。利用准一级动力学方程、假二级动力学方程、颗粒内扩散模型和Elovich方程分别对动力学过程进行拟合,发现2种沸石对Hg^2+的吸附均满足假二级动力学方程,且离子的颗粒内扩散对整个吸附过程有影响。动力学拟合、D-R方程拟合和热力学研究综合表明:2种沸石对Hg^2+的吸附既存在化学吸附又存在物理吸附,吸附吉布斯自由能变(△G^0)、焓变(△H^0)、熵变(△S^0)均小于0,反应为自发的放热反应,低温有利于吸附的进行。 相似文献
978.
为探讨高效选择性回收污泥厌氧消化液中磷的离子交换方法,采用静态实验和动态实验研究了4种阴离子交换树脂(D213、D202、D301和DSQ)的磷回收性能,筛选了适合富磷污泥厌氧消化液选择性磷回收的高交换容量树脂。实验结果表明,D213、D202、D301和DSQ 4种树脂对正磷浓度为70 mg/L的厌氧消化液进行动态处理时,其最大穿透体积分别为3、7、17和90 BV;DSQ树脂磷交换容量远高于其他3种树脂,达到6 860 mg P/L湿树脂,是目前报道的高磷交换容量树脂的3~4倍;DSQ树脂能有效地抵抗厌氧消化液中有机质和硫酸根等阴离子的干扰;用NaOH溶液再生DSQ树脂并回收磷,磷洗脱率超过96%,洗脱液是高浓度含磷液,可作为磷矿石的优质替代品。研究表明,DSQ树脂是一种高效选择性分离磷的树脂,适用于污泥厌氧消化液的磷回收。 相似文献
979.
3种载体固定化菌藻共生系统脱氮除磷效果的对比 总被引:1,自引:0,他引:1
采用3种不同载体(海藻酸钠、聚乙烯醇、复合载体),分别将小球藻和栅藻与活性污泥固定成菌藻共生系统,制成菌藻凝胶小球,单独菌、单独藻的凝胶小球,用于处理人工污水。结果表明,(1)复合载体固定的菌藻共生系统氮磷去除效果最好,PVA载体的脱氮除磷效果次于复合载体优于海藻酸钠;(2)固定化菌藻共生系统的脱氮除磷效果明显优于单独固定菌和单独固定藻,固定菌的效果较差;(3)3种载体包埋下的固定化小球藻的脱氮除磷效果均较相同载体固定化的栅藻效果好。 相似文献
980.
介绍了国内外烟气脱硫催化剂的研究现状,研究了金属氧化物负载型催化剂对烟气脱硫性能的影响。以活性炭(AC)为载体,选用8种不同的金属硝酸盐作为浸渍液,采用等体积浸渍法制备金属氧化物负载型催化剂。以脱硫效果较好的Fe2O3/AC为例,研究了不同焙烧温度、金属负载量以及焙烧时间对催化剂脱硫性能的影响。实验结果表明,Fe2O3/AC催化剂脱硫率随着金属负载量的增加呈递增趋势,最优金属负载量为10.0%(质量分数);脱硫率随着焙烧温度的增加显著提高,最优焙烧温度为350℃;脱硫率随着焙烧时间的增加而提高,最优焙烧时间为3.0h。 相似文献