全文获取类型
收费全文 | 1204篇 |
免费 | 74篇 |
国内免费 | 526篇 |
专业分类
安全科学 | 86篇 |
废物处理 | 57篇 |
环保管理 | 125篇 |
综合类 | 692篇 |
基础理论 | 225篇 |
污染及防治 | 438篇 |
评价与监测 | 71篇 |
社会与环境 | 50篇 |
灾害及防治 | 60篇 |
出版年
2024年 | 5篇 |
2023年 | 28篇 |
2022年 | 81篇 |
2021年 | 61篇 |
2020年 | 59篇 |
2019年 | 48篇 |
2018年 | 57篇 |
2017年 | 74篇 |
2016年 | 66篇 |
2015年 | 75篇 |
2014年 | 91篇 |
2013年 | 118篇 |
2012年 | 100篇 |
2011年 | 127篇 |
2010年 | 84篇 |
2009年 | 82篇 |
2008年 | 76篇 |
2007年 | 67篇 |
2006年 | 78篇 |
2005年 | 56篇 |
2004年 | 38篇 |
2003年 | 27篇 |
2002年 | 47篇 |
2001年 | 36篇 |
2000年 | 43篇 |
1999年 | 35篇 |
1998年 | 18篇 |
1997年 | 25篇 |
1996年 | 15篇 |
1995年 | 17篇 |
1994年 | 11篇 |
1993年 | 20篇 |
1992年 | 10篇 |
1991年 | 10篇 |
1990年 | 4篇 |
1989年 | 3篇 |
1988年 | 2篇 |
1987年 | 4篇 |
1986年 | 1篇 |
1983年 | 2篇 |
1982年 | 2篇 |
1973年 | 1篇 |
排序方式: 共有1804条查询结果,搜索用时 0 毫秒
21.
Extracellular polymeric substances (EPS) were extracted from Aspergillus fumigatus using cationic exchange resin technique. The EPS were mainly composed of polysaccharide and low quantities of protein and nucleic acid. Biosorption of Cd(II), Pb(II), and Cu(II) of EPS was investigated as a function of pH using differential pulse polarography and the Ruzic model. Results showed that the EPS biosorption capacity determined using either the direct titration curves i?=?f(C M) or the method proposed by Ruzic (Analytica Chimica Acta 140:99–113, 1982) were coincident. Cu(II) had the highest affinity with EPS followed by Pb(II) and Cd(II). The total number of binding sites for Cu(II) and Cd(II) increased with pH in the range of 4.0–7.0. Similar trend was observed for Pb(II) at pH?4.0–5.0, while precipitates were observed at pH?6.0 and 7.0. The conditional binding constants of these three metals displayed low levels of fluctuation with pH and ranged from 4.02?±?0.02 to 5.54?±?0.05. 相似文献
22.
T酸一次洗水初步处理的研究 总被引:4,自引:0,他引:4
采用重氮化-偶合-混凝沉淀和重氮化-混凝沉淀两种方法对T酸一次洗水的初步处理进步了研究。T酸一次洗水经两种方法处理后,COD去除率分别为61.3%、50.5%,色度去除率分别为74.6%、71%。 相似文献
23.
Muhammad Shakeel Muhammad Farooq Wajid Nasim Waseem Akram Fawad Zafar Ahmad Khan Waqar Jaleel Xun Zhu Haichen Yin Shuzhong Li Shah Fahad Saddam Hussain Bhagirath Singh Chauhan Fengliang Jin 《Environmental science and pollution research international》2017,24(17):14537-14550
The diamondback moth, Plutella xylostella, is recognized as a widely distributed destructive insect pest of Brassica worldwide. The management of this pest is a serious issue, and an estimated annual cost of its management has reached approximately US$4 billion. Despite the fact that chemicals are a serious threat to the environment, lots of chemicals are applied for controlling various insect pests especially P. xylostella. An overreliance on chemical control has not only led to the evolution of resistance to insecticides and to a reduction of natural enemies but also has polluted various components of water, air, and soil ecosystem. In the present scenario, there is a need to implement an environmentally friendly integrated pest management (IPM) approach with new management tactics (microbial control, biological control, cultural control, mating disruption, insecticide rotation strategies, and plant resistance) for an alternative to chemical control. The IPM approach is not only economically beneficial but also reduces the environmental and health risks. The present review synthesizes published information on the insecticide resistance against P. xylostella and emphasizes on adopting an alternative environmentally friendly IPM approach for controlling P. xylostella in China. 相似文献
24.
焙烧-酸浸法可有效回收电镀污泥中的有价金属,而污泥的热处理特性是决定能否采用焙烧预处理的重要因素。研究了氧化焙烧和还原焙烧对污泥成分和金属浸出性的影响,并对焙烧前后的污泥进行了金属形态分析和X射线衍射(XRD)分析。结果表明,焙烧预处理实现了污泥减量和金属富集;ES1经氧化焙烧后金属浸出率接近原泥,Cu的浸出率达99%;ES2的还原焙烧效果优于氧化焙烧,特别是Cu的浸出率超过97%,XRD分析发现,还原焙烧过程中金属Cu被还原为铁铜合金;2种焙烧均造成了ES3中目标金属Ni的浸出率的降低;金属浸出性的下降与残渣态的形成有关。 相似文献
25.
H(+)/phenanthrene symporter and aquaglyceroporin are implicated in phenanthrene uptake by wheat (Triticum aestivum L.) roots 总被引:1,自引:0,他引:1
Zhan X Zhang X Yin X Ma H Liang J Zhou L Jiang T Xu G 《Journal of environmental quality》2012,41(1):188-196
Polycyclic aromatic hydrocarbons (PAHs) are ubiquitous organic pollutants that are toxic to human and nonhuman organisms. Dietary intake of PAHs is a dominant route of exposure for the general population because food crops are a major source of dietary PAHs. The mechanism for crop root uptake of PAHs remains unclear. Here we reveal that wheat root uptake of PAHs involves active and passive processes. The passive uptake is mercury and glycerol dependent. Mercury and glycerol inhibit uptake, indicating that aquaglyceroporins sensitive to mercury contribute to passive uptake. Active uptake is mediated by a phenanthrene/H symporter. The electrical response of wheat roots triggered by phenanthrene consists of two sequential phases: depolarization followed by repolarization. The depolarization is phenanthrene concentration dependent, with saturation kinetics that have an apparent of K(m) 10.8 μmol L(-1). As uptake proceeds, external solution pH increase is noticed. Lower pH favors the uptake. Vanadate and 2,4-dinitrophenol suppress the electrical response to phenanthrene and phenanthrene uptake, suggesting that plasma membrane H(+)-ATPase is involved in the establishment of an electrochemical proton gradient acting as a driving force for active uptake. Therefore, it is suggested that aquaglyceroporin and phenanthrene/H symporter are implicated in phenanthrene uptake. Our results provide insight into PAH uptake mechanism in wheat roots that is relevant to strategies for reducing PAH accumulation in wheat for food safety, improving phytoremediation of PAH-contaminated soils or water by agronomic practices and genetic modification to target remedial plants for higher PAH uptake capacity. 相似文献
26.
Solvent-based separation method is presumably an efficient and environmentally beneficial approach for elimination of brominated flame retardants (BFRs) from waste electrical and electronic equipment (WEEE). The overall goal of this study was to evaluate possible effects of organic solvent on the behavior of BFRs during solvent-based processing of WEEE. We initiated a set of batch experiments for examining the rates and possible pathways of transformation of a representative BFR (tetrabromobisphenol A, TBBPA) using acetone, toluene, and methanol as the solvents. Our results showed that toluene and methanol had no effect on the transformation of TBBPA, but approximately 20% of TBBPA (100 mg L−1) was transformed by acetone within 2 h at 50 °C. Analysis of the products with GC-MS showed that two high-molecular-weight products (MW = 586) were major products of the transformation reactions. The role of acetone as a reactant in the transformation of TBBPA was further validated with dueterated acetone. In addition, the effects of co-existing metals in WEEE (i.e., Zn, Cu, and Ni) on the transformation of TBBPA in the solvent systems were investigated. These metals tested were found to greatly enhance the rates of TBBPA transformation. The metal facilitated solvent reactions with TBBPA may lower the extractability of TBBPA by formation of larger and less soluble products, hence potentially increasing the cost for separating the chemical from WEEE. 相似文献
27.
Ge Yuan Chen Chengrong Xu Zhihong Eldridge Simon M. Chan Kwong Yin He Yan He Ji-Zheng 《Environmental science and pollution research international》2010,17(3):807-815
Background, aim, and scope
Current Australian legislation permits the beneficial application of grease trap waste (GTW) to agricultural soil, viewing it as a beneficial source of organic matter and soil conditioner containing no/low amounts of metals or pathogenic organisms. However, little is known about the influence of GTW on soil bacterial community. A field experiment was established at Menangle in south western Sydney in Australia to quantitatively assess the impacts of different types (GTW CO and GTW CL) and amounts of GTW application on the soil bacterial community and diversity. Furthermore, a municipal solid waste (MSW) compost was simultaneously examined to compare against the other organic wastes. Knowledge about the shifts in microbial community structure and diversity following the applications of organic wastes could help to evaluate the ecological consequences on the soil and thus to develop sound regulatory guidelines for the beneficial reuse of organic wastes in agricultural lands. 相似文献28.
Quantifying air pollution attenuation within urban parks: an experimental approach in Shanghai, China 总被引:2,自引:0,他引:2
Yin S Shen Z Zhou P Zou X Che S Wang W 《Environmental pollution (Barking, Essex : 1987)》2011,159(8-9):2155-2163
Parks with various types of vegetations played an important role in ameliorating air quality in urban areas. However, the attenuation effect of urban vegetation on levels of air pollution was rarely been experimentally estimated. This study, using seasonal monitoring data of total suspended particles (TSP), sulfur dioxide (SO(2)) and nitrogen dioxide (NO(2)) from six parks in Pudong District, Shanghai, China, demonstrated vegetations in parks can remove large amount of airborne pollutants. In addition, crown volume coverage (CVC) was introduced to characterize vegetation conditions in parks and a mixed-effects model indicated that CVC and the pollution diffusion distance were key predictors influencing pollutants removal rate. Therefore, it could be estimated by regression analysis that in summer, urban vegetations in Pudong District could contribute to 9.1% of TSP removal, 5.3% of SO(2) and 2.6% of NO(2). The results could be considered for a better park planning and improving air quality. 相似文献
29.
2008年江苏持续性降雪中的水汽和动力抬升机制分析 总被引:1,自引:0,他引:1
2008年1月下旬江苏省出现了历史罕见的持续性暴雪过程,研究发现,降雪量的大小与低空急流的日变化相对应,暴雪过程中700 hPa西南急流对水汽的输送起着重要的作用,作为大尺度天气系统,700 hPa急流的加速发生在降雪量增大之前,其值阈大小与6 h降雪量之间没有对应关系,急流减弱在暴雪结束以后;降雪的发生和发展与南北风的增大和冷暖平流有关,低层偏北风作为冷垫对暖湿气流的抬升和水汽的凝结起到了一定的作用;江苏降雪过程中水汽主要来源于700~500 hPa,低层东风气流对黄海南部的水汽输送非常有限;强降雪的发生与700 hPa水汽通量散度相对应,水汽通量散度辐合增大,降雪量增大;在降雪过程中垂直运动对降雪量的大小有很好的指示意义。 相似文献
30.