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941.
942.
Carbon dioxide emissions have accelerated since the signing of the Kyoto Protocol. This discouraging development may partly
be blamed on accelerating world growth and on lags in policy instruments. However, it also raises serious question concerning
whether policies to reduce CO2 emissions are as effective as generally assumed. In recent years, a considerable number of studies have identified various
feedback mechanisms of climate policies that often erode, and occasionally reinforce, their effectiveness. These studies generally
focus on a few feedback mechanisms at a time, without capturing the entire effect. Partial accounting of policy feedbacks
is common in many climate scenarios. The IPCC, for example, only accounts for direct leakage and rebound effects. This article
attempts to map the aggregate effects of different types of climate policy feedback mechanisms in a cohesive framework. Controlling
feedback effects is essential if the policy measures are to make any difference on a global level. A general conclusion is
that aggregate policy feedback mechanisms tend to make current climate policies much less effective than is generally assumed.
In fact, various policy measures involve a definite risk of ‘backfiring’ and actually increasing CO2 emissions. This risk is particularly pronounced once effects of climate policies on the pace of innovation in climate technology
are considered. To stand any chance of controlling carbon emissions, it is imperative that feedback mechanisms are integrated
into emission scenarios, targets for emission reduction and implementation of climate policy. In many cases, this will reduce
the scope for subsidies to renewable energy sources, but increase the scope for other measures such as schemes to return carbon
dioxide to the ground and to mitigate emissions of greenhouse gases from wetlands and oceans. A framework that incorporates
policy feedback effects necessitates rethinking the design of the national and regional emission targets. This leads us to
a new way of formulating emission targets that include feedback effects, the global impact target. Once the full climate policy feedback mechanisms are accounted for, there are probably only three main routes in climate
policy that stand a chance of mitigating global warming: (a) returning carbon to the ground, (b) technological leaps in zero-emission
energy technology that make it profitable to leave much carbon in the ground even in Annex II countries and (c) international
agreements that make it more profitable to leave carbon in the ground or in forests. 相似文献
943.
A solid phase extraction (SPE) method using pyrenebutyric acid-bonded silica (PYB) as sorbent was developed to determine 23 polychlorinated biphenyls (PCBs) in sewage water by gas chromatography-mass spectrometry (GC-MS). Factors were optimized in SPE procedures including elution solvent, pH, and cartridge burden. The recoveries of 23 PCB congeners were 69.44-111.91% under optimized conditions. Comparisons were also conducted among PYB-SPE, C(18)-SPE and United States Environmental Protection Agency 608 (USEPA608) methods in the analysis of PCBs in sewage water samples. The results showed that the performance of PYB-SPE method was similar with USEPA608 method and better than C(18)-SPE method. Both PYB-SPE and USEPA608 methods were then employed to analyze PCBs in real spiked sewage water samples. The recoveries of PCB congeners determined by PYB-SPE method ranged from 70.6% to 92.4% in real spiked sewage water samples which were identified to be in accordance with USEPA608 method. Limits of detection (LOD) were in the range of 0.06-0.22ngL(-1) for PCB congeners. The optimized PYB-SPE method was successfully applied to the determination of PCBs in sewage water samples. 相似文献
944.
Joseph N.T. Darbah Mark E. Kubiske Katre Kets Anu Sober David F. Karnosky 《Environmental pollution (Barking, Essex : 1987)》2010,158(4):983-19373
Photosynthetic acclimation under elevated carbon dioxide (CO2) and/or ozone (O3) has been the topic of discussion in many papers recently. We examined whether or not aspen plants grown under elevated CO2 and/or O3 will acclimate after 11 years of exposure at the Aspen Face site in Rhinelander, WI, USA. We studied diurnal patterns of instantaneous photosynthetic measurements as well as A/Ci measurements monthly during the 2004-2008 growing seasons. Our results suggest that the responses of two aspen clones differing in O3 sensitivity showed no evidence of photosynthetic and stomatal acclimation under either elevated CO2, O3 or CO2 + O3. Both clones 42E and 271 did not show photosynthetic nor stomatal acclimation under elevated CO2 and O3 after a decade of exposure. We found that the degree of increase or decrease in the photosynthesis and stomatal conductance varied significantly from day to day and from one season to another. 相似文献
945.
Francisca F. del Campo 《Environmental pollution (Barking, Essex : 1987)》2010,158(9):2906-108
Microcystins (MCs) are toxic cyclic heptapeptides produced by various cyanobacteria genera, especially Microcystis. We identified 10 out of 12 MCs produced by three Microcystis aeruginosa strains from cyanobacteria collections, UTEX 2666, UTEX 2670 and UAM 1303, by using two analytical methods: Matrix-assisted Laser Desorption Ionization Time of Flight Mass Spectrometry (MALDI-TOF/MS) and HPLC Photodiode Array Detector coupled to a hybrid Quadrupole Time of Flight Mass Spectrometry (HPLC-PDA-QTOF/MS). MALDI-TOF/MS failed to detect non-polar MCs, such as MC-LY and MC-LW. HPLC-QTOF/MS permitted the accurate identification of most MCs present in methanolic extracts. Besides, three new MCs, namely: [D-Glu(OCH3)6, D-Asp3] MC-LAba, MC-YL and MC-YM were detected by HPLC-QTOF/MS. 相似文献
946.
维生素和酮苷生产废水中难降解污染物的溯源研究 总被引:2,自引:1,他引:1
研究了维生素和酮苷生产过程中各生产工段排水的生物降解特性,评价了各生产工段对生产废水中难降解有机物的贡献率,追溯了可能的难降解特征污染物。结果表明,维生素生产废水中的难降解物质主要来自W1-1、W1-3、W1-5和W1-6生产工段,甲醛、丁烯酮、醛酮聚合物和吡啶可能是导致生产废水难降解的重要原因;酮苷生产废水中的难降解物质主要来自W2-1、W2-3和W2-7生产工段,氯代有机溶剂和苯环类物质可能是导致生产废水难降解的重要原因。建议根据具体生产工段排水的水质特征,有针对性地进行物化处理,提高废水可生化性。 相似文献
947.
Skene KJ Gent JF McKay LA Belanger K Leaderer BP Holford TR 《Atmospheric environment (Oxford, England : 1994)》2010,44(39):5156-5164
An integrated exposure model was developed that estimates nitrogen dioxide (NO(2)) concentration at residences using geographic information systems (GIS) and variables derived within residential buffers representing traffic volume and landscape characteristics including land use, population density and elevation. Multiple measurements of NO(2) taken outside of 985 residences in Connecticut were used to develop the model. A second set of 120 outdoor NO(2) measurements as well as cross-validation were used to validate the model. The model suggests that approximately 67% of the variation in NO(2) levels can be explained by: traffic and land use primarily within 2 km of a residence; population density; elevation; and time of year. Potential benefits of this model for health effects research include improved spatial estimations of traffic-related pollutant exposure and reduced need for extensive pollutant measurements. The model, which could be calibrated and applied in areas other than Connecticut, has importance as a tool for exposure estimation in epidemiological studies of traffic-related air pollution. 相似文献
948.
Jianjun Chen Qi Ying Michael J. Kleeman 《Atmospheric environment (Oxford, England : 1994)》2010,44(10):1331-1340
The UCD/CIT air quality model with the Caltech Atmospheric Chemistry Mechanism (CACM) was used to predict source contributions to secondary organic aerosol (SOA) formation in the San Joaquin Valley (SJV) from December 15, 2000 to January 7, 2001. The predicted 24-day average SOA concentration had a maximum value of 4.26 μg m?3 50 km southwest of Fresno. Predicted SOA concentrations at Fresno, Angiola, and Bakersfield were 2.46 μg m?3, 1.68 μg m?3, and 2.28 μg m?3, respectively, accounting for 6%, 37%, and 4% of the total predicted organic aerosol. The average SOA concentration across the entire SJV was 1.35 μg m?3, which accounts for approximately 20% of the total predicted organic aerosol. Averaged over the entire SJV, the major SOA sources were solvent use (28% of SOA), catalyst gasoline engines (25% of SOA), wood smoke (16% of SOA), non-catalyst gasoline engines (13% of SOA), and other anthropogenic sources (11% of SOA). Diesel engines were predicted to only account for approximately 2% of the total SOA formation in the SJV because they emit a small amount of volatile organic compounds relative to other sources. In terms of SOA precursors within the SJV, long-chain alkanes were predicted to be the largest SOA contributor, followed by aromatic compounds. The current study identifies the major known contributors to the SOA burden during a winter pollution episode in the SJV, with further enhancements possible as additional formation pathways are discovered. 相似文献
949.
R.J. Wichink Kruit W.A.J. van Pul F.J. Sauter M. van den Broek E. Nemitz M.A. Sutton M. Krol A.A.M. Holtslag 《Atmospheric environment (Oxford, England : 1994)》2010,44(7):945-957
New parameterizations for surface–atmosphere exchange of ammonia are presented for application in atmospheric transport models and compared with parameterizations of the literature. The new parameterizations are based on a combination of the results of three years of ammonia flux measurements over a grassland canopy (dominated by Lolium perenne and Poa trivialis) near Wageningen, the Netherlands and existing parameterizations from literature. First, a model for the surface–atmosphere exchange of ammonia that includes the concentration at the external leaf surface is derived and validated. Second, a parameterization for the stomatal compensation point (expressed as Γs, the ratio of [NH4+]/[H+] in the leaf apoplast) that accounts for the observed seasonal variation is derived from the measurements. The new, temperature-dependent Γs describes the observed seasonal behavior very well. It is noted, however, that senescence of plants and field management practices will also influence the seasonal variation of Γs on a shorter timescale. Finally, a relation that links Γs to the atmospheric pollution level of the location through the ‘long-term’ NH3 concentration in the air is proposed. 相似文献
950.