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361.
He Genhe Wang Xiaodong Liu Xu Xiao Xiaoyu Huang Shoucheng Wu Jichun 《Russian Journal of Ecology》2018,49(6):524-533
Russian Journal of Ecology - The present study characterized the nutrients availability of three rare earth tailings deserted in different time stages in Southern Jiangxi of China, and revealed the... 相似文献
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Qing Zhao Kebin He Kenneth A. Rahn Yongliang Ma Fumo Yang Fengkui Duan 《Atmospheric environment (Oxford, England : 1994)》2010,44(21-22):2615-2624
Depletion of Si in transported dust has been recognized for many years. It can be used to distinguish between transported and local dust in cities, although it rarely has been. Here we use the variations of the Si/Al ratio in 15 months of continuous PM2.5 samples at Beijing (northern China) and Chongqing (southwestern China) to reveal the seasonal patterns of their dust sources. For both cities, peaks of concentration for Si and Al in PM2.5 corresponded with minima of Si/Al, and could often be linked to pulsed air flow from deserts to the northwest. With significant depletion (up to 80%) and homogeneous distribution at urban and rural sites, Si/Al showed a clear seasonal evolution, which decreased from spring to summer, increased from fall to winter, and collapsed during Chinese Spring Festival, indicating the dominance of transported dust, local fugitive dust and firework influence, respectively. The low ratios implied that desert dust is a common source during spring at Chongqing, whereas its presence during cold season at Beijing was also more frequent than expected. Failing to recognize the depletion of Si may lead to an overestimate of desert dust by 15%–65% when using the average abundance of Al in crust (6%–8%), as in previous studies. The difference in Si/Al ratio between local and transported dust implies that >60% of the dust at Beijing came from outside the city during the springs of 2004–2006. This result can help resolve the contradictory findings on this topic that have been presented earlier. 相似文献
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Jinzhu Ma Yongchun Liu Hong He 《Atmospheric environment (Oxford, England : 1994)》2010,44(35):4446-4453
To further understand the role of substrates on the heterogeneous reactions of polycyclic aromatic hydrocarbons, the reactions of ozone with anthracene adsorbed on different mineral oxides (SiO2, α-Al2O3 and α-Fe2O3) and on Teflon disc were investigated in dark at 20 °C. No reaction between ozone and anthracene on Teflon disc was observed when the ozone concentration was ~1.18 × 1014 molecules cm?3. The reactions on mineral oxides exhibited pseudo-first-order kinetics for anthracene loss, and the pseudo-first-order rate constant (k1,obs) displayed a Langmuir–Hinshelwood dependence on the gas-phase ozone concentration. The adsorption equilibrium constants for ozone (KO3) on SiO2-1, SiO2-2, α-Al2O3 and α-Fe2O3 were (0.81 ± 0.26) × 10?15 cm3, (2.83 ± 1.17) × 10?15 cm3, (2.48 ± 0.77) × 10?15 cm3 and (1.66 ± 0.45) × 10?15 cm3, respectively; and the maximum pseudo-first-order rate constant (k1,max) on these oxides were (0.385 ± 0.058) s?1, (0.101 ± 0.0138) s?1, (0.0676 ± 0.0086) s?1 and (0.0457 ± 0.004) s?1, respectively. Anthraquinone was identified as the main surface product of anthracene reacted with ozone. Comparison with previous research and the results obtained in this study suggest that the reactivity of anthracene with ozone and the lifetimes of anthracene adsorbed on mineral dust in the atmosphere are determined by the nature of the substrate. 相似文献
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可用于水体污染控制的氨氮转化菌筛选及部分降解特性的实验研究 总被引:3,自引:0,他引:3
从南京禄口水产养殖基地淡水鱼塘取淤泥作为分离菌株的土源,采用选择性富集培养法,从中分离到能以硫酸铵为氮源的菌株7株,对7个菌株进行氨氮降解实验,它们氨氮转化率分别为14.8%、19.7%、53.4%、94.2%、29.1%、63.5%和41.7%,其中AN-4菌株的转化率最高且生长良好。通过AN-4菌株16S rRNA基因序列分析以及生理生化方法,鉴定此菌株为克雷伯氏菌属(Klebsiellasp.)。对菌株AN-4转化氨氮的特性及温度、pH值、氨氮初始浓度和菌株接种量对其氨氮转化率的影响研究,结果表明,菌株AN-4降解氨氮的最适条件为:温度为30℃和pH值为8.0;当氨氮初始浓度为30mg/L时,AN-4菌株在24 h内的氨氮降解率可达85%以上,且能耐受高达200 mg/L的氨氮浓度;AN-4活化菌液浓度为108cfu/mL,当接种量为3×106cfu/mL时,AN-4菌株在24 h内的氨氮降解率为87.75%。综合上述结果,符合淡水养殖水环境条件,说明AN-4菌株适合在水产养殖中应用,为将菌株AN-4应用于水产养殖环境修复提供了理论依据。 相似文献
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废弃轮胎制备中孔炭吸附材料工艺及性能研究 总被引:1,自引:0,他引:1
为了解决废弃轮胎造成的资源浪费和环境污染的问题,对以废弃轮胎橡胶为碳的前驱体原料,制备具有高吸附性能中孔炭材料工艺进行了系统的研究。通过XRD、扫描电镜以及比表面积分析,对制备的中孔炭微观结构和性能进行表征,讨论了炭化温度、碱炭比,以及活化温度和活化时间等工艺条件对制备中孔炭的产率、结构和性能的影响。结果表明,通过改变工艺条件制备的中孔炭的孔径分布可以在2~80 nm范围内进行调控。在500℃炭化温度,碱炭比为4∶1,900℃活化1 h的工艺条件下,制备的中孔炭的比表面积为473 m2/g,对甲基橙的最大吸附量达到254 mg/g。 相似文献
370.
采用高锰酸钾预氧化-缺氧/好氧生物铁法处理维生素B1厂乙酰嘧啶生产段实际废水,实验结果表明该组合工艺对嘧啶生产废水具有良好的处理效果:预氧化将嘧啶废水中大分子难降解乙酰嘧啶几乎全部转化为具有饱和碳氢键的小分子有机物,使乙酰嘧啶去除率达90%以上,且COD去除率在40%以上,BOD5/COD由0.17~0.23提高至0.35~0.44。通过与后续A/O生物铁工艺相结合,使COD、TN和氨氮总去除率分别达到93.3%、81.7%和78.6%,出水pH为6.6~7.5。 相似文献