矿化垃圾床＋三维电极／电Fenton法处理老龄垃圾渗滤液

提出以二级矿化垃圾床为预处理单元,串联三维电极／电Fenton处理老龄垃圾渗滤液的组合工艺。矿化垃圾床处理后渗滤液中COD、氨氮、总磷、色度的去除率分别为80．55％、88．47％、98．32％和87．53％。通过单因素实验和正交实验,确定了三维电极／电Fenton法最佳工艺条件。经该组合工艺后,渗滤液中COD、氨氮、总磷和色度的最高去除率分别可达97．08％、95．24％、99．55％和96．92％,其中COD、总磷、色度这3个指标低于《生活垃圾填埋场污染控制标准》（GB16889．2008）表2规定的排放标准,为该组合工艺在实际中的应用提供重要理论依据。     

膜电解法在线再生酸性蚀刻液及回收铜新技术

采用极化曲线法研究了酸性蚀刻液阴、阳极电化学行为,并构建了离子膜电解反应体系,考察了在线再生酸性蚀刻液及回收铜的效果。结果表明,阳极氧化过程发生浓差极化,存在极限电流密度,Cu＋含量越高,极限电流密度越大;阴极还原分4步反应进行,存在极限电流密度;强化溶液传质可有效提高阴、阳极极限电流密度,有利于避免电解过程中析出氯气和氢气;在线实验表明,通过监控阳极液ORP,可避免析出氯气;分步降低电流电解有利于避免析出氢气,形成致密的金属铜块;在电流为9～24A范围内分4步电解23．5h可再生酸性蚀刻液23．5L,同时电沉积回收510g铜,纯度高达99．98％。阴极电流效率达到95．2％,吨铜电耗3251kWh。电解过程中无氯气和氢气析出,无废液排放,表明膜电解法在线再生酸性蚀刻液具有良好的应用前景。     

云母钛珠光颜料的应用研究

介绍了一种不使用有机溶剂获得云母钛珠光颜料、水性金属效果云母钛珠光浆、珠光涂料的环保型制备工艺和性能.采用液相沉积法获得了不同厚度的纳米TiO2薄膜包覆层而显示银白、金、红、紫、蓝、绿等各种色彩的系列珠光云母颜料;应用珠光云母颜料与分散剂等水性助剂混合,获得了水性金属效果云母钛珠光浆的制备工艺;应用云母钛珠光浆与乳液配合,获得了云母钛珠光涂料的制备工艺.制备的云母钛珠光涂料系列多彩,白度高、反射率大、珠光效果好,硬度、附着力、耐候性等指标优异.     

Soil-atmosphere trace gas exchange in semiarid and arid zones

A review is presented on trace gas exchange of CH4, CO, N2O, and NOx arising from agriculture and natural sources in the world's semiarid and arid zones due to soil processes. These gases are important contributors to the radiative forcing and the chemistry of the atmosphere. Quantitative information is summarized from the available studies. Between 5 and 40% of the global soil-atmosphere exchange for these gases (CH4, CO, N2O, and NOx) may occur in semiarid and arid zones, but for each of these gases there are fewer than a dozen studies to support the individual estimates, and these are from a limited number of locations. Significant differences in the biophysical and chemical processes controlling these trace gas exchanges are identified through the comparison of semiarid and arid zones with the moist temperate or wet/dry savanna land regions. Therefore, there is a poorly quantified understanding of the contribution of these regions to the global trace gas cycles and atmospheric chemistry. More importantly, there is a poor understanding of the feedback between these exchanges, global change, and regional land use and air pollution issues. A set of research issues is presented.     

基于社会保障功能的耕地保有量测算——以北京市房山区为例

在大城市郊区,社会保障体系还不完善,农民主要依靠土地来保障基本生活。因此,进行基于社会保障功能的耕地保有量的预测研究,对保障社会经济稳定、可持续发展有着重要的理论和现实意义。以北京市房山区为例,利用历年统计数据,从社会保障的角度上提出了耕地保有量测算方法,预测了耕地保有量,并将现状和上轮规划进行了比较。结论表明,北京市房山区非农建设占用耕地的速度趋于缓和,数量有所下降。     

中国污泥堆肥产业发展模式的探讨

本文介绍了我国污泥堆肥产业现状、技术发展方向、相关标准规范;比较了污泥堆肥项目的建设运营与污水处理的不同之处;通过唐山西郊项目的成功运行,说明污泥堆肥项目在运作良好的情况下完全可以实现运营平衡,结合资源化处置的污染治理项目也有可能实现效益产出.     

邹平县大气降水酸度影响因素分析

应用灰色理论,以2002,2003,2004,2005,2006连续五年为时间序列点,取大气降水pH值为参考因素,取大气中SO2、NOx、TSP、降尘的浓度为比较因素进行关联分析。灰关联度矩阵表明：邹平县大气降水酸度的最大影响因素是SO2,其次降尘的影响也不容忽视。     

Reaction pathways of dimethyl phthalate degradation in TiO2-UV-O2 and TiO2-UV-Fe(VI) systems

The photocatalytic degradation of dimethyl phthalate (DMP) in aqueous TiO₂ suspension under UV illumination has been investigated using oxygen (O₂) and ferrate (Fe(VI)) as electron acceptors. The experiments demonstrated that Fe(VI) was a more effective electron acceptor than O₂ for scavenging the conduction band electrons from the surface of the catalyst. Some major intermediate products from DMP degradation were identified by HPLC and GC/MS analyses. The analytical results identified dimethyl 3-hydroxyphthalate and dimethyl 2-hydroxyphthalate as the two main intermediate products from the DMP degradation in the TiO₂–UV–O₂ system, while in contrast phthalic acid was found to be the main intermediate product in the TiO₂–UV–Fe(VI) system. These findings indicate that DMP degradation in the TiO₂–UV–O₂ and TiO₂–UV–Fe(VI) systems followed different reaction pathways. An electron spin resonance analysis confirmed that hydroxyl radicals existed in the TiO₂–UV–O₂ reaction system and an unknown radical species (most likely an iron–oxo species) is suspected to exist in the TiO₂–UV–Fe(VI) reaction system. Two pathway schemes of DMP degradation in the TiO₂–UV–O₂ and TiO₂–UV–Fe(VI) reaction systems are proposed. It is believed that the radicals formed in the TiO₂–UV–O₂ reaction system preferably attack the aromatic ring of the DMP, while in contrast the radicals formed in the TiO₂–UV–Fe(VI) reaction systems attack the alkyl chain of DMP.     

水安全及城市水安全研究进展与趋势

归纳和总结国内外水安全及城市水安全相关研究实践及其所用的评价指标体系,并对几种常用模型与方法的应用情况及其各自的特点进行分析,针对目前水安全及城市水安全研究中存在的主要问题,指出水安全及城市水安全进一步研究的方向:从自然、生态环境、社会经济、人文4个基本方向,以系统性、持续性、动态性和层次性4个特征为基础,分析水安全及城市水安全的概念与内涵;根据研究区域特征及其主要水安全问题建立评价指标体系;以研究者对各个模型的理解程度及驾驭能力为准则选用或改造现有模型与方法;针对加强城市应急水源地建设、突发性水安全事件应急预案、湿润地区水安全等问题开展研究。     

基于三角模糊数的民航企业“管理”安全综合评价模型研究

在对我国民航企业安全管理的现状和常用的安全评价方法进行分析的基础上,提出并建立了民航企业"管理"安全模糊综合评价模型。首先,从组织管理、风险管理、安全保证、安全促进4个方面对民航企业安全管理的内容和特点进行分析,在此基础上建立民航企业"管理"安全评价指标体系;然后,根据三角模糊数理论和模糊综合评价理论建立民航企业"管理"安全模糊综合评价模型;通过上述指标体系和评价模型从而达到对民航企业"管理"安全进行评价的目的。最后,给出了一个应用实例,其评价结果表明:该模型具有很强的实用性和借鉴价值。