Effects of Cu（Ⅱ） and humic acid on atrazine photodegradation

This work was designed to explore the characteristics of photodegradation of herbicides in the copper-polluted water body. The results showed that Cu(II) alone could induce a photo Fenton-like reaction to enhance the degradation of atrazine, in which hydroxyl radical ( OH) was a main active species. Humic acids restrained atrazine degradation, nevertheless, when introducing Cu(II), the photodegradation was accelerated, in which singlet oxygen (1O2) replaced OH acting as the prevailing species. A feasible mechanism for the photochemical process was also proposed, which is helpful for better understanding the environmental photochemistry of atrazine in the copper-polluted water.     

锅炉烟囱高度设置合理性论证的实例分析

污染物高烟囱排放对改善污染物对地面的影响是很明显的,但是过高的烟囱不仅对企业投资是一种负担,而且还可能对周围环境产生景观上的不协调影响,因此环境影响评价中开展对烟囱高度合理性论证是非常必要的。以延安市某集中供热工程为实例,依照相关技术规范对烟囱高度的明确要求,并利用新版大气环境影响评价技术导则中推荐的SCREEN3模式,论证了该工程拟建设的120m高烟囱是合理可行的,同时得出了"高烟囱的设置可促成酸雨的形成"以及"过高的烟囱对环境质量的改善是并不明显的"这一结论。针对研究时存在的不足之处,最后提出了继续深入研究的方向。     

浅析重大危险源监控系统的建设

介绍了重大危险源监控系统建设中所涉及的硬件建设和软件建设两方面的内容。硬件建设即网络建设,主要介绍了设备和网络的建设;软件建设即系统开发,主要介绍了系统功能建设和GIS平台建设。     

四丰山水库富营养化状况

通过对四丰山水库2006至2010年监测数据的统计,分析水库水质富营养化状况,指出水质富营养化的危害,并提出避免水质恶化的建议.     

Historical trends of heavy metal contamination and their sources in lacustrine sediment from Xijiu Lake, Taihu Lake Catchment, China

Concentrations of Cd, Cr, Cu, Pb, Zn and Hg in Xijiu Lake sediment from the Taihu Lake catchment, China, were analyzed. Their contamination state was investigated based on the geoaccumulation index and enrichment factors. Statistical analysis was used to differentiate the anthropogenic versus natural sources of heavy metals (HMs), and the anthropogenic accumulation fluxes were calculated to quantify anthropogenic contribution to HMs. The results indicated that the lake sediment had been heavily contaminated by Cd, enrichment of Zn and Hg was at a relatively high level, while that of Cu and Pb was in the lower-to-moderate level and Cr was in the low enrichment level. Sources of Cr in the sediment were mainly from natural inputs, while other metals, especially Cd, were predominantly derived from anthropogenic sources. In the past century, anthropogenic accumulation fluxes of Pb, Zn and Hg increased by 0.1-47.3 mg/(cm².yr), 2.4-398.1 mg/(cm².yr), and 3.7-110.3 ng/(m².yr), respectively, accounting for most inputs of HMs entering the sediment. The contamination state of HMs varied with industrial development of the catchment, which demonstrated that contamination started in the early 20th century, reached the maximal level between the mid-1970s and mid-1990s, and decreased a little after the implementation of constraints on high contamination industries, although the contamination of some HMs, such as Cd, Zn and Hg, is still at high levels.     

新疆D矿田金矿资源定量评价

本文在建立D矿田找矿信息层次模型基础上,确定矿田统计单元划分和地质变量提取的赋值原则,将该矿田划分出466个统计单元,提取25个地质变量并进行二态赋值,而后应用数量化理论Ⅲ。特征分析法及勃尔法等方法,建立了矿田金矿资源定量评价模型,定位预测了45个勘探靶区。     

Carbonaceous particles in the atmosphere and precipitation of the Nam Co region, central Tibet

A continuous air and precipitation sampling for carbonaceous particles was conducted in a field observatory beside Nam Co, Central Tibetan Plateau during July of 2006 through January of 2007. Organic carbon (OC) was the dominant composition of the carbonaceous particles both in the atmosphere (1660 ng/m³) and precipitation (476 ng/g) in this area, while the average elemental carbon (BC) concentrations in the atmosphere and precipitation were only 82 ng/m³ and 8 ng/g, respectively. Very high OC/BC ratio suggested local secondary organic carbon could be a dominant contribution to OC over the Nam Co region, while BC could be mainly originated from Southern Asia, as indicated by trajectory analysis and aerosol optical depth. Comparison between the BC concentrations measured in Lhasa, those at “Nepal Climate Observatory at Pyramid (NCO-P)” site on the southern slope of the Himalayas, and Nam Co suggested BC in the Nam Co region reflected a background with weak anthropogenic disturbances and the emissions from Lhasa might have little impact on the atmospheric environment here, while the pollutants from the Indo-Gangetic Basin of Southern Asia could be transported to the Nam Co region by both the summer monsoon and the westerly.     

山体对烟羽弥散影响的一种数值模拟方法

本文对山地和丘陵地区中烟羽浓度扩散分布的计算提出一种方法,该方法引用浓度方程的分析解,通过对山地绕流数值计算速度势和流函数,可较简易地求得烟羽浓度分布。作为算例,文中对中条山某工厂烟囟排放的SO2,预测了它在各种风速时被输运扩敢的浓度分布。      

气相色谱质谱法分析挥发性有机污染物质量控制研究

根据美国环保局合同实验室计划(US EPA CLP),分析5个样品,系统地研究了色谱质谱法分析挥发性有机污染物全过程中每个环节上的质量控制问题。此法可用来定量大部分沸点在200℃以下,不溶于水的挥发性有机物。实际上对于水样的定量检测限大约是5μg/L,土壤和底泥是5μg/kg。     

毛细管柱气相色谱质谱法分析优先监测物的质量控制研究——Ⅰ.半挥发性有机物

报道了毛细管柱气相色谱质谱联用(GC-MS)方法分析半挥发性有机物的质量控制研究结果.对分析的全过程提出了质量控制标准.应用同位素标记内标物(IS),替代掺样物(SS)和基质掺样/重复基质掺样(MS/MSD)的回收率来判断样品处理与分析结果的可靠性.根据77种目标化合物,特别是标定检验化合物(CCC)和系统检验化合物(SPCC)的响应系数范围,确定GC-MS系统的工作状态和最终结果的正确性.给出了满足质量控制标准的12个土壤样品的结果.