An insight into the removal of fluoroquinolones in activated sludge process: Sorption and biodegradation characteristics

The detailed sorption steps and biodegradation characteristics of fluoroquinolones(FQs)including ciprofloxacin, enrofloxacin, lomefloxacin, norfloxacin, and ofloxacin were investigated through batch experiments. The results indicate that FQs at a total concentration of 500 μg/L caused little inhibition of sludge bioactivity. Sorption was the primary removal pathway of FQs in the activated sludge process, followed by biodegradation, while hydrolysis and volatilization were negligible. FQ sorption on activated sludge was a reversible process governed by surface reaction. Henry and Freundlich models could describe the FQ sorption isotherms well in the concentration range of 100–300 μg/L. Thermodynamic parameters revealed that FQ sorption on activated sludge is spontaneous, exothermic, and enthalpy-driven. Hydrophobicity-independent mechanisms determined the FQ sorption affinity with activated sludge. The zwitterion of FQs had the strongest sorption affinity, followed by cation and anion, and aerobic condition facilitated FQ sorption. FQs were slowly biodegradable, with long half-lives( 100 hr). FQ biodegradation was enhanced with increasing temperature and under aerobic condition,and thus was possibly achieved through co-metabolism during nitrification. This study provides an insight into the removal kinetics and mechanism of FQs in the activated sludge process, but also helps assess the environmental risks of FQs resulting from sludge disposal.     

Measuring the economic effects of sea level rise on shore fishing

In this paper we develop estimates of the economic effects of sea level rise on marine recreational shore fishing in North Carolina, USA. The relationship between angler behavior and spatial differences in beach width is estimated using the Marine Recreational Fishing Statistics Survey and geospatial data. We exploit the empirical relationship between beach width and fishing site choice by simulating the effects of sea level rise on angler site choice. We find that reductions in beach width negatively affect the quality and number of fishing trips even as anglers adapt by using piers and bridges. Welfare losses are potentially substantial, ranging up 39% of the total value of marine shore fishing in North Carolina.     

Conception of an environmental friendly O/W cosmetic emulsion from microalgae

The development of eco-friendly cosmetic such as those from microalgae for skin regeneration and collagen synthesis has gained a great interest worldwide. Accordingly, the potential of microalgae biomass as source of anti-aging cosmetic cream with high antioxidant activity has been investigated. Stabilities and sensory characteristics of cosmetic creams supplemented with Spirulina, Tetraselmis sp. and Dunaliella sp. at 0.5, 1.5 and 2.5%, respectively, revealed a conservation of physico-chemical and preliminary stability properties of formulations. To analyze physico-chemical and textural parameters, accelerated stability study was evaluated under two thermal conditions (25 and 40 °C) during 90 days. Results showed that pH values of all formulations were within the limits of normal skin pH range under storage time at 25 and 40 °C. During this period, the colored creams showed a significant changes of a* and b* indices, reflecting the instability of microalgae colors. Microalgae modified the textural characteristics of emulsions. The Tetraselmis sp. containing-cream had the lowest (P < 0.05)?values of hardness, springiness, and cohesiveness. The 0.5% Spirulina containing-cream had the best stable consistency and adhesiveness under time and temperature variations. It exhibited the best properties to be used for skin care products. Thanks to their high content in bioactive macromolecules, microalgae considerably improved the antioxidant activity of the new formulated skin creams.

     

Methodological approaches for delimitating mixing zones in rivers: establishing admissibility criteria and flow regime representation

The present paper addresses defining the extent of the mixing zones of effluents discharged into rivers, which is a problem that should be analyzed based on probabilistic terms, as it is governed by several random processes. A river’s flow regime is one of the main variables, and it has a high dependence on hydrological processes. Additionally, after calculating the extent of the mixing zone, it is necessary to determine if the resulting dimensions are admissible or not. Common practice includes the admissibility criteria associated with the geometry of the river. However, this practice does not consider the environmental characteristics of the river that make it capable of absorbing the impact of the effluent (the biological and hydromorphological status of the river and the presence of structures that can change the river flow conditions, ecologically sensitive area or threatened species). This paper presents work on two important topics: on the one hand, the development of a methodology to establish the admissible extent of the mixing zone as a function of the environmental vulnerability of the river to the discharged effluent and, on the other hand, the proposal of a procedure to perform the calculations of the effluent mixing considering the variability of the river’s flow regime. The proposed methodological approaches are illustrated with an application to a real case, including a numerical simulation of the hydrodynamic and effluent evolution of the river during a year, to test the proposed methodology’s suitability and demonstrate the important savings in computational effort that can be achieved.     

中国生态保护政策的县域经济效应——来自国家重点生态功能区的证据

为保障生态产品供给，中国设立了限制开发的国家重点生态功能区，建立了生态保护转移支付制度.本文首次在县域层面构建2002~2017年县级面板数据，运用倾向得分匹配法构造政策组的“反事实”情形，基于双重差分法评估重点生态功能区政策的县域经济效应.结果表明，该政策提高了县域财力、长期来看一定程度改善了产业结构；以标准财政缺口为主的资金分配机制弱化了县域经济发展激励，资金补助不能完全抵消限制开发对县域经济带来的负向影响；固定资产投资和内资企业受影响较大.随着投入资金累积、生态产品价值的转化，该负向效应随时间而减弱、经济促增效应逐渐显现.政策效应在不同生态功能和经济区位间表现出明显的异质性.建议持续增加生态转移支付资金、将生态产品供给数量和质量作为资金分配依据，考虑按生态功能类型设计差异化政策，更好激励县域生态产品高水平供给与经济价值实现的双赢，促进区域均衡发展.     

Estimating uncertainties in the life cycle assessment of composting household biowaste and urban green waste in Germany

Life cycle assessment (LCA) of waste treatment processes is often associated with considerable uncertainties. The aim of this study is to estimate the total uncertainty in the modelled composting system and the influence of material and process parameters on the uncertainty. Four composting combinations with fresh (FC) and mature substrate compost (MSC) from partially enclosed (PEC) and open composting (OC) were investigated. Perturbation analysis was used to determine the effect of parameters on the result and Monte Carlo simulation was used to estimate the total uncertainty. This study showed that the production of MSC using PEC had the lowest overall impacts across all impact categories except ozone depletion. Results of the Monte Carlo simulation showed that comparing composting options was challenging. The sensitivity ratios obtained from the perturbation analysis showed that the process parameter percentage of carbon fraction degraded was the most influential for FC. In MSC, the moisture content in the input material and the substitution factor used for peat were the most influential. Monte Carlo simulations demonstrated the overall uncertainty of the model and its relevance when comparing results between combinations. The perturbation analysis identified the parameters that required more accurate data to reduce the uncertainty in the model.

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Pyrolysis of lemon peel waste in a fixed-bed reactor and characterization of innovative pyrolytic products

Journal of Material Cycles and Waste Management - Lemon peel waste (LPW) were pyrolysed in a laboratory fixed-bed reactor at final temperature of 300&nbsp;°C, 400&nbsp;°C and...     

Extraction and characterization of chitin,chitosan, and protein hydrolysate from the invasive Pacific blue crab,Portunus segnis (Forskål, 1775) having potential biological activities

Environmental Science and Pollution Research - The diversity of marine biomasses is a set of exploitable and renewable resources with application in several sectors. In this context, a co-culture...     

履约对我国典型城市和偏远背景地区气态单质汞浓度和源区的影响研究

为了解我国城市和背景地区最新的气态单质汞（gaseous elemental mercury，GEM）水平，比较《关于汞的水俣公约》履约前后这些地区GEM来源和迁移规律的差异，本研究选择了1个城市监测站（淀山湖站）和1个背景监测站（哀牢山站），于2021年分别进行了为期1个月的GEM监测，同时使用潜在源贡献因子计算分析两地GEM的来源，并与履约前的结果进行比对。位于长三角地区的淀山湖站GEM浓度降幅大于位于我国西南的哀牢山站GEM浓度降幅，表明针对我国工业排放源超低排放的改造，获得了显著的履约成效。相对履约前，两地GEM的可能源区和传输形式没有显著改变，人为源排放仍然是影响两地GEM浓度的主要因素。本研究结果表明随着履约工作的逐步推进，我国城市和背景地区的GEM仍有下降的可能，长期在这些站点开展大气汞监测，可以为汞履约成效评估提供有效的数据支撑。