Mass transport of organic contaminants through a self-sealing/self-healing mineral landfill liner

The self-sealing/self-healing (SS/SH) liner system is based on the fundamental principle that an impermeable seal is self-formed and self-healed by the pozzolanic reaction at the interface between two adjacent reactive layers. The objectives of this study were to evaluate the effect of contaminants on the performance of an SS/SH liner used as a hydraulic barrier, to understand mechanism of volatile organic compound (VOC) sorption on the SS/SH materials, and to estimate the mass transport parameters of contaminants through the SS/SH liner materials. The hydraulic conductivity of the liner material decreased continuously with time, and stabilized at less than 1 × 10^–7cm/s after approximately 15 days. It is known that the seal at the interface between two reactive layers is self-formed over time, and this contributes to the decrease in the hydraulic conductivity of such a liner system. The retardation of the seven target VOCs tested was greater in the SS/SH liner materials than in a clayey soil specimen owing to the higher sorption capacity. An analytical solution developed to test column equipment could reduce the time required to estimate the hydrodynamic dispersion coefficients of organic compounds by using the data on changes in concentration in the upper reservoir of the column.     

Planning STI/HIV prevention among refugees and mobile populations: situation assessment of Sudanese refugees

This article reflects an investigation of knowledge, attitudes and behaviours and HIV/STI prevalence of Sudanese refugees and Ethiopian sex workers in 1992. It represents one of the earliest such investigations within an African refugee population. The investigation took place in the Dimma refugee settlement in south-western Ethiopia and study participants included Sudanese refugee men and women and Ethiopian female sex workers. Methods used for this investigation included focus group discussions, behavioural surveys and serologic testing. The main outcome measures of the investigation were HIV/STI knowledge, attitudes and behaviours and biological markers for HIV, syphilis and herpes simplex 2. The study findings indicate that in the early 1990s, knowledge about AIDS and condom use was low among Sudanese refugee women and not one reported having ever used a condom. Furthermore, sexual contact between refugee men and sex workers was frequent during the time of this study and the prevalence of HIV and other STIs was high. The results confirm a widely held assumption that highly mobile and transient populations in Africa are susceptible to STIs and HIV, in large part due to their knowledge, attitudes and behaviours.     

Looking beyond food aid to livelihoods, protection and partnerships: strategies for WFP in the Darfur states

The humanitarian crisis in Darfur remains extremely serious. The optimism that followed the signing of the Abuja Peace Accord was followed by a rapid deterioration in security on the ground in part associated with increasing factionalism in various rebel movements. This paper briefly reviews the evolution of the crisis, its impact on lives and livelihoods and the response by the World Food Programme (WFP) to June 2006. The major challenges and issues facing the food aid programme in the previous 18 months included: dealing with insecurity while maintaining or even extending programme outreach; the need to link protection with assistance more explicitly; and determining the wider impact of food aid programming on the processes and institutions linked with the conflict. The paper discusses the main strategic issues facing WFP in the future such as: integrating security and protection with needs assessments and operational decisions, broadening response strategies beyond food aid and bringing livelihoods to the fore, the need to review cost-efficiency, promoting partnerships and strengthening national and regional capacities.     

Mantle protein excretion and calcification in the hardshell clam Mercenaria mercenaria. II. Protein synthesis and excretion by the isolated mantle

Sheets of mantle tissue from above the mantle line of Mercenaria mercenaria were incubated for 2, 6 and 20 h at 20°C in 50 Ci ³H-glycine in 50 ml artificial seawater. Incorporation of tritium into soluble proteins excreted by the mantle and into tissue proteins was followed. The excretion of soluble protein continued throughout the experiment; the proportion of incorporated label excreted reached 17% by 20 h. The initiation of excretion of labelled protein seemed to lag 60 to 70 min behind the initiation of protein synthesis. Protein synthesis by the mantle contributed to proteins of the extrapallium and mantle chambers and, thus, may be involved in synthesis and regulation of proteins involved in the shell-formation process.     

Effectiveness of China's National Forest Protection Program and nature reserves

There is profound interest in knowing the degree to which China's institutions are capable of protecting its natural forests and biodiversity in the face of economic and political change. China's 2 most important forest‐protection policies are its National Forest Protection Program (NFPP) and its national‐level nature reserves (NNRs). The NFPP was implemented in 2000 in response to deforestation‐caused flooding. We undertook the first national, quantitative assessment of the NFPP and NNRs to examine whether the NFPP achieved its deforestation‐reduction target and whether the NNRs deter deforestation altogether. We used MODIS data to estimate forest cover and loss across mainland China (2000–2010). We also assembled the first‐ever polygon dataset for China's forested NNRs (n = 237, 74,030 km² in 2000) and used both conventional and covariate‐matching approaches to compare deforestation rates inside and outside NNRs (2000–2010). In 2000, 1.765 million km² or 18.7% of mainland China was forested (12.3% with canopy cover of ≥70%)) or woodland (6.4% with canopy cover <70% and tree plus shrub cover ≥40%). By 2010, 480,203 km² of forest and woodland had been lost, an annual deforestation rate of 2.7%. Forest‐only loss was 127,473 km² (1.05% annually). In the NFPP provinces, the forest‐only loss rate was 0.62%, which was 3.3 times lower than in the non‐NFPP provinces. Moreover, the Landsat data suggest that these loss rates are overestimates due to large MODIS pixel size. Thus, China appears to have achieved, and even exceeded, its target of reducing deforestation to 1.1% annually in the NFPP provinces. About two‐thirds of China's NNRs were effective in protecting forest cover (prevented loss 4073 km² unmatched approach; 3148 km² matched approach), and within‐NNR deforestation rates were higher in provinces with higher overall deforestation. Our results indicate that China's existing institutions can protect domestic forest cover.     

Predicting collective climates: assessing the role of shared work values,needs, employee interaction and work group membership

Previous research has debated whether the collective climates, produced through cluster analysis of psychological climate perceptions, are representative of meaningful organizational collectives or simply statistical artifacts. In this study we examined the extent to which collective climates are comprised of individuals with similar interpretive schemata such as work values and need strength or consist of individuals who share work group or interaction group membership. Measures of psychological climate, work values, need strength, and employee interaction patterns were collected from the management and administrative staff of a manufacturing organization. Results supported the symbolic interactionist perspective to the formation of collective climates. We found clear evidence that collective climates are related to employee interaction groups. Employee interaction based on sensemaking and information seeking activities was most strongly related to shared climate perceptions. There was also some evidence that individuals with similar levels of need strength share collective climate membership. Implications of these results on the debate over the use of collective climates are discussed. Copyright © 1999 John Wiley & Sons, Ltd.     

Biomarker responses of <Emphasis Type="Italic">Peromyscus leucopus</Emphasis> exposed to lead and cadmium in the Southeast Missouri Lead Mining District

Biomarker responses and histopathological lesions have been documented in laboratory mammals exposed to elevated concentrations of lead and cadmium. The exposure of white-footed mice (Peromyscus leucopus) to these metals and the potential associated toxic effects were examined at three contaminated sites in the Southeast Missouri Lead Mining District and at a reference site in MO, USA. Mice from the contaminated sites showed evidence of oxidative stress and reduced activity of red blood cell δ-aminolevulinic acid dehydratase (ALAD). Histological examinations of the liver and kidney, cytologic examination of blood smears, and biomarkers of lipid peroxidation and DNA damage failed to show indications of toxic effects from lead. The biomagnification factor of cadmium (hepatic concentration/soil concentration) at a site with a strongly acid soil was 44 times the average of the biomagnification factors at two sites with slightly alkaline soils. The elevated concentrations of cadmium in the mice did not cause observable toxicity, but were associated with about a 50% decrease in expected tissue lead concentrations and greater ALAD activity compared to the activity at the reference site. Lead was associated with a decrease in concentrations of hepatic glutathione and thiols, whereas cadmium was associated with an increase. In addition, to support risk assessment efforts, we developed linear regression models relating both tissue lead dosages (based on a previously published a laboratory study) and tissue lead concentrations in Peromyscus to soil lead concentrations.