全文获取类型
收费全文 | 11161篇 |
免费 | 1017篇 |
国内免费 | 3968篇 |
专业分类
安全科学 | 954篇 |
废物处理 | 523篇 |
环保管理 | 875篇 |
综合类 | 7377篇 |
基础理论 | 1728篇 |
环境理论 | 2篇 |
污染及防治 | 2823篇 |
评价与监测 | 690篇 |
社会与环境 | 768篇 |
灾害及防治 | 406篇 |
出版年
2024年 | 65篇 |
2023年 | 266篇 |
2022年 | 678篇 |
2021年 | 653篇 |
2020年 | 664篇 |
2019年 | 522篇 |
2018年 | 501篇 |
2017年 | 663篇 |
2016年 | 691篇 |
2015年 | 785篇 |
2014年 | 907篇 |
2013年 | 1051篇 |
2012年 | 1016篇 |
2011年 | 993篇 |
2010年 | 801篇 |
2009年 | 743篇 |
2008年 | 815篇 |
2007年 | 652篇 |
2006年 | 605篇 |
2005年 | 421篇 |
2004年 | 331篇 |
2003年 | 351篇 |
2002年 | 345篇 |
2001年 | 269篇 |
2000年 | 293篇 |
1999年 | 189篇 |
1998年 | 178篇 |
1997年 | 138篇 |
1996年 | 120篇 |
1995年 | 83篇 |
1994年 | 83篇 |
1993年 | 68篇 |
1992年 | 54篇 |
1991年 | 28篇 |
1990年 | 30篇 |
1989年 | 21篇 |
1988年 | 19篇 |
1987年 | 3篇 |
1986年 | 11篇 |
1984年 | 5篇 |
1983年 | 3篇 |
1982年 | 9篇 |
1981年 | 3篇 |
1979年 | 2篇 |
1978年 | 6篇 |
1975年 | 2篇 |
1973年 | 1篇 |
1972年 | 3篇 |
1971年 | 2篇 |
1970年 | 1篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
981.
982.
Xian-De Xie Xiao-Bo Min Li-Yuan Chai Chong-Jian Tang Yan-Jie Liang Mi Li Yong Ke Jie Chen Yan Wang 《Environmental science and pollution research international》2013,20(9):6050-6058
Floatation tailings (FT) are the main by-products of the hydrothermal sulfidation–flotation process. FT (FT1 and FT2) were obtained by treating two different neutralization sludges (NS) (NS1 and NS2). This paper quantitatively evaluated the environmental risks of heavy metals (Zn, Cd, Cu, Pb, and As) in FT versus NS. The total concentration and leaching rates (R 2) of heavy metals in FT were much lower than those in NS, demonstrating that the hydrothermal sulfidation–flotation process was able to effectively suppress the mobility and leachability of heavy metals. The BCR-three sequence leaching procedure of FT confirmed that all metals were transformed into more stable forms (residue and oxidizable forms) than were found that in NS. The potential ecological risk index indicated that the overall risks caused by heavy metals decreased significantly from 6627.59 and 7229.67 (very serious risk) in NS1 and NS2, respectively, to 80.26 and 76.27 (low risk) in FT1 and FT2, respectively. According to the risk assessment code, none of the heavy metals in FT posed significant risk to the natural environment except Zn (with low risk). In general, the risk of heavy metals in FT had been well controlled. 相似文献
983.
Panax notoginseng (Burk.) F.H. Chen, a rare traditional Chinese medicinal herb, is a widely used phytomedicine used all over the world. In recent years, the arsenic contamination of the herb and its relative products becomes a serious problem due to elevated soil As concentration. This study aimed to evaluate the effects of different types and dosages of amendments on As stabilization in soil and its uptake by P. notoginseng. Results showed that comparing to control treatment, the As concentrations of P. notoginseng declined by 49–63%, 43–61% and 52–66% in 0.25% zero-valent iron (Fe(0)), 0.5% bauxite residue, and 1% zeolite treatment, respectively; whereas the biomasses were elevated by 62–116%, 45–152% and 114–265%, respectively. The As(III) proportions of P. notoginseng increased by 8%, 9%, and 8%, and the transfer factors of As from root to shoot increased by 37%, 42% and 84% in the optimal treatments of Fe(0), bauxite residue, and zeolite. For soil As, all the three amendments could transform the non-specifically adsorbed As fraction to hydrous oxides Fe/Al fractions (by Fe(0) and red mud) or specifically adsorbed As fraction (by zeolite), therefore reduced the bioavailability of soil As. With a comprehensive consideration of stabilization efficiency, plant growth, environmental influence, and cost, Fe(0) appeared to be the best amendment, and zeolite could also be a good choice. In conclusion, this study was of significance in developing As contamination control in P. notoginseng planting areas, and even other areas for medicinal herb growing. 相似文献
984.
985.
986.
The interactions between metals (Ca2+ and Hg2+) and extracellular polymeric substances (EPS) extracted from the aerobic and anaerobic sludge in wastewater treatment reactors were investigated using a combination of zeta potential measurement and 3-dimensional excitation–emission matrix (EEM) fluorescence spectroscopy with parallel factor (PARAFAC) analysis. Results show that Ca2+ had no substantial effects on the EEM fluorescence spectra of the EPS, but their zeta potentials increased with the increasing Ca2+ dosage. However, Hg2+ had a significant effect on the EEM fluorescence spectra of the EPS, while their zeta potentials seemed not to be affected by the dose of Hg2+. The interactions between Hg2+ and EPS were elucidated using the fluorescence quenching with PARAFAC analysis, while the interactions between Ca2+ and EPS were evaluated by the zeta potential technique. The binding constants for Hg2+ and EPS were two orders of magnitude higher than those for Ca2+ and EPS, suggesting that the binding mechanisms between Ca2+ and EPS were different from those between Hg2+ and EPS. The results might be useful for understanding the roles of EPS in bacterial self-protection against heavy metals and the aggregate formation mechanisms through ionic bridging interactions. 相似文献
987.
Size-specific concentrations and bioaccessibility of polybrominated diphenyl ethers (PBDEs) in dust from air conditioner filters were measured, and the factors influencing the PBDE bioaccessibility were determined. Generally, the PBDE concentrations increased with decreasing dust particle size, and BDE209 (deca-BDE) was generally the predominant congener. The bioaccessibility ranged from 20.3% to 50.8% for tri- to hepta-BDEs, and from 5.1% to 13.9% for BDE209 in dust fractions of varied particle size. The bioaccessibility of most PBDE congeners decreased with increasing dust particle size. The way of being of PBDE (adsorbed to dust surface or incorporated into polymers) in dust significantly influenced the bioaccessibility. There was a significant negative correlation between the tri- to hepta-BDE bioaccessibility and organic matter (OM) contents in dust. Furthermore, tri- to hepta-BDE bioaccessibility increased with increasing polarity of OMs, while with decreasing aromaticity of OMs. The tri- to hepta-BDE bioaccessibility significantly positively correlated with the surface areas and pore volumes of dust. Using multiple linear regression analysis, it was found that the OM contents and pore volumes of dust were the most important factors to influence the tri- to hepta-BDE bioaccessibility and they could be used to estimate the bioaccessibility of tri- to hepta-BDEs according to the following equation: bioaccessibility (%) = 45.05 − 0.49 × OM% + 1.79 × pore volume. However, BDE209 bioaccessibility did not correlate to any of these factors. 相似文献
988.
采用溶胶-凝胶法制备了活性炭纤维负载TiO2催化剂(TiO2/ACF),并通过SEM和XRD等手段对TiO2/ACF进行了表征。以邻苯二甲酸二甲酯(DMP)为目标降解物,考察了催化材料的电催化活性。实验结果表明:在反应温度为25 ℃、初始DMP质量浓度为100.0 mg/L、电解质Na2SO4质量浓度为100 mg/L、电流密度为62.5 mA/cm2、电极板间距为4 cm的条件下,经过40 min的降解,DMP质量浓度为1.8 mg/L,DMP去除率为98.2%;TiO2/ACF在反应过程中可以原位再生,经6次重复使用后仍保持很高的催化活性,对DMP的去除率仍达90%以上。 相似文献
989.
Xinying Li Quanyuan Chen Yasu Zhou Mark Tyrer Yang Yu 《Waste management (New York, N.Y.)》2014,34(12):2494-2504
The objective of this work was to investigate the feasibility and effectiveness of silica fume on stabilizing heavy metals in municipal solid waste incineration (MSWI) fly ash. In addition to compressive strength measurements, hydrated pastes were characterized by X-ray diffraction (XRD), thermal-analyses (DTA/TG), and MAS NMR (27Al and 29Si) techniques. It was found that silica fume additions could effectively reduce the leaching of toxic heavy metals. At the addition of 20% silica fume, leaching concentrations for Cu, Pb and Zn of the hydrated paste cured for 7 days decreased from 0.32 mg/L to 0.05 mg/L, 40.99 mg/L to 4.40 mg/L, and 6.96 mg/L to 0.21 mg/L compared with the MSWI fly ash. After curing for 135 days, Cd and Pb in the leachates were not detected, while Cu and Zn concentrations decreased to 0.02 mg/L and 0.03 mg/L. The speciation of Pb and Cd by the modified version of the European Community Bureau of Reference (BCR) extractions showed that these metals converted into more stable state in hydrated pastes of MSWI fly ash in the presence of silica fume. Although exchangeable and weak-acid soluble fractions of Cu and Zn increased with hydration time, silica fume addition of 10% can satisfy the requirement of detoxification for heavy metals investigated in terms of the identification standard of hazardous waste of China. 相似文献
990.
海水异养硝化-好氧反硝化芽孢杆菌SLWX2的筛选及脱氮特性 总被引:1,自引:3,他引:1
从分离自刺参养殖环境的7株候选菌株中筛选出1株具有较强异养硝化和好氧反硝化能力的菌株SLWX_2,通过形态学特征、生理生化特性和16S rRNA基因测序分析鉴定其为花津滩芽孢杆菌(Bacillus hwajinpoensis).该菌株脱氮特性研究结果表明,SLWX_224 h对氨氮、亚硝酸氮和硝酸氮的去除率分别达到100%、99.5%和85.6%;当3种无机氮源同时存在时,菌株优先利用氨氮,再利用NO_2~--N和NO_3~--N,72 h 3种无机氮的质量浓度均降至0.013 mg·L~(-1)以下,表明该菌株能同时进行异养硝化和好氧反硝化完成脱氮;在氨氮负荷500 mg·L~(-1)、亚硝酸氮负荷100 mg·L·~(-1)和硝酸氮负荷200 mg·L~(-1)范围内,该菌的脱氮能力不受明显抑制,对3种形态的氮均有良好去除效果,96 h最多可去除180 mg NH_4~+-N、30 mg NO_2~--N和120 mg NO_3~--N,并且在硝化过程中没有亚硝酸氮积累.该菌株在海水养殖和高盐高氮工业废水的脱氮处理方面具有更大潜力. 相似文献