利用铬渣制造微晶玻璃建筑装饰板

铬盐在生产过程中排出大量有毒废渣,对环境造成严重污染,以铬渣为主要原料,经熔制、成型、热处理和磨光等工序制成微晶玻璃建筑装饰板。铬渣掺量达５０％,产品可溶性铬残留量小于０．２５ｍｇ／ｋｇ,物理化学性能指标优于天然花岗石和天然大理石,本法除毒彻底,吃渣量大,拟建成的生产线每年可处理８０００ｔ铬渣,经济效益好,是铬渣治理的一条有效新途径。     

压缩空气下FRPC能源桩承载特性分析

可再生能源储存系统是利用钢筋混凝土桩基础来储存由太阳能板产生的可再生能源,可再生能源以压缩空气的形式储存在空心截面的桩基内,桩基础作为上部结构的承载结构,不仅要承受上部结构荷载,还要承受土体的反作用力和压缩空气的压力。然而,混凝土在拉应力作用下易产生裂缝,导致钢筋混凝土桩储存能源的使用性能和耐久性受限。为了克服传统钢筋混凝土能量桩的这些缺陷,针对各种FRP(Fiber Reinforced Polymer)-混凝土复合桩基础储能和承载的双功能进行研究。综合考虑结构荷载、土体的反作用和压缩空气热动力循环引起的内部空气压力的共同作用,对多种形式的复合能量桩基础体系的适用性进行了综合有限元分析。研究表明,内侧和外侧的FRP管可以有效提高使用性能和耐久性,相对于钢筋混凝土桩,FRPC管桩的使用可靠性和耐久性性能更高。     

Sugarcane bagasse amendment improves the quality of green waste vermicompost and the growth of Eisenia fetida

•Earthworms were able to convert green waste into more plant-available nutrients. •The part of heavy metals content increased in the compost added by earthworm. •The addition of SCB to GW did enhance earthworm biomass and humic acid content. •The resulting vermicomposts were characterized by neutral pH and lower EC value. Vermicomposting is a feasible method for disposing of lignocellulosic waste while generating a useful product. The current study assessed the potential of vermicomposting green waste mixed with sugarcane bagasse in proportions of 25%, 50%, and 75% (v:v, based on dry weight). The suitability was evaluated based on the agrochemical properties, earthworm biomass, and phytotoxicity. The final vermicomposts exhibited near-neutral pH values (7.1–7.6), and lower EC values (0.43–0.72 mS/cm) and C:N ratios (14.1–19.9).The content of available nutrients and CEC for all the vermicomposts exceeded those of the control compost (without earthworms). For vermicomposts, the average values of NO₃^–-N, AP, AK, and CEC were 53, 517, 1362 mg/kg, and 158 cmol/kg, respectively. The total contents of heavy metals increased in all vermicompost treatments compared to control composts with the following average final percentages: Zn (2.0%), Cr (15.5%), Pb (23.4%), and Cu (44.3%), but these amounts were safe for application in agroforestry. The addition of sugarcane bagasse to green waste significantly increased the content of total humic substance, humic acid and urease activity, acid and alkaline phosphatase activity, and Eiseniafetida reproduction. The addition of 25% sugarcane bagasse to green waste decreased the toxicity to germinating seeds. These results revealed that vermicomposting is a feasible way to degrade green waste into a value-added chemical product.     

多次冻融循环人工盐渍土路基模型试验研究∗

青藏铁路西宁至格尔木段为典型的季节性冻土区铁路,冻害频发,严重影响铁路的正常使用和安全运营,为了整治路基体发生冻害,结合成熟的注浆技术和传统撒盐法,提出注盐法整治路基冻害。在室内模型箱中填筑实体模型,进行封闭系统中多次冻融循环条件下人工盐渍土路基模型试验,探究人工盐渍土路基中温度、水分、盐分以及变形规律,验证注盐法整治路基冻害的可行性。试验结果表明：路基土体内温度变化趋势符合环境温度变化趋势的余弦函数变化波动规律,土体内温度变化较环境温度变化推迟36 h左右;温度梯度是引起水分迁移的主要因素,越接近冷端,迁移量越大,在冻结锋面处达到最大;在封闭系统中,盐分随着水分向冷端运移,但是盐分运移量较低,随着周期的推进,盐分呈逐渐降低的趋势;随着温度的周期性变化路基顶面的变形呈现出有规律的冻胀和融沉现象,但是最大冻胀量为0.08 mm,可见路基盐化之后路基土体基本不产生冻胀变形。     

高职高专《动态网页设计》教学改革探索

动态网页是目前网站发展的趋势,也是网站设计的主流.动态网页设计的教学既是新型思维的训练又是综合技能的练习.本文结合现代高职教育的需求,针对动态网页设计教学课程的特点,从教学內容、教学方式、考核方式这三方面阐述了如何改进该课程的教学效果.     

Promotion of pyrene degradation in rhizosphere of alfalfa (Medicago sativa L.)

Pot experiment was conducted to evaluate the phytoremediation of pyrene-contaminated soil using alfalfa (Medicago sativa L.). Alfalfa biomasses, microbial viable counts, dehydrogenase activity, residual pyrene concentration and pyrene removal percentage were determined after 60 days of alfalfa growth. The results indicated that pyrene had an inhibitive effect on alfalfa growth, and higher pyrene concentration seriously affected alfalfa growth. In addition, the inhibitive effect on the root was more severe than that on the shoot. When pyrene concentration reached 492 mg kg(-1) in soil, the shoot and root biomasses were only 34% and 22% of those of alfalfa growing in non-spiked soil, respectively. The rhizospheric bacterial and fungi counts were 5.0-7.5 and 1.8-2.3 times higher than those in non-rhizosphere soil, respectively. The residual concentrations of pyrene in the rhizosphere soil were lower than those in the non-rhizosphere soil. After 60 days, 69-85% and 59-80% of spiked pyrene disappeared from the rhizosphere and non-rhizosphere soils, respectively. The removal percentage decreased with increasing pyrene concentration. However, the average removal of pyrene in the rhizosphere soil was 6% higher than that in the non-rhizosphere soil. Therefore, the presence of alfalfa roots was effective in promoting the phytoremediation of freshly added pyrene into the soil.     

丙烯酸废水超临界水氧化动力学研究

用H2O2作为氧化剂,对丙烯酸生产废水进行超临界水氧化研究.得到了反应速率方程表达式.COD、H2O2和水的反应级数分别为1、0和0,指前因子A为4.97 s-1,反应活化能Ea为20.64 kJ/mol,诱导时间为8 s左右.     

蒸发壁式超临界水氧化反应器处理分散红和活性红染料废水的比较

采用蒸发壁式超临界水氧化反应器对染料分散红C.I.60和活性艳红M-2B配制的模拟废水进行降解实验.实验结果表明,2种染料的COD和TN去除率随着反应温度、氧化剂过量比(r)的升高而上升.COD去除率活性红要高于分散红,而TN去除率则相反.根据GC-MS分析和陶瓷膜SEM图像,分析测得2种染料主要反应中间产物均含有苯酚和苯甲酸,2种染料的反应对陶瓷膜均有轻微的腐蚀.     

从聚醚残渣中回收聚醚和磷酸二氢钾

采用热水萃取分离技术回收聚醚残渣中J的聚醚和膦酸二氰钾,考察了萃取温度、结晶温度、水洗条件等因素对产品回收情况的影响。工业试验结果表明：聚醚回收率大于75%,磷酸二氢钾的平均回收率为70%.工业化试生产得到磷酸二氢钾和聚醚的产品质量分别达到HG2321-92工业品一级标准和该厂制定的GEP560S企业标准。该技术具有聚醚和磷酸二氢钾回收率高、工艺简单等特点,且经济效益、环境效益和社会效益显著。     

三效催化转化器老化过程预测及数值仿真

基于三效催化转化器的老化机理,提出了老化过程的预测方法。然后将老化机理与化学反应机理相结合,建立包含老化过程的三效催化转化器反应模型,并进行数值仿真,得到三效催化转化器载体温度及氧浓度沿载体轴向的分布特性,最后计算得出预测三效催化转化器老化过程的主要参数以及老化前后转化效率的变化,并与实验值进行比较。