维生素和酮苷生产废水中难降解污染物的溯源研究

研究了维生素和酮苷生产过程中各生产工段排水的生物降解特性,评价了各生产工段对生产废水中难降解有机物的贡献率,追溯了可能的难降解特征污染物。结果表明,维生素生产废水中的难降解物质主要来自W1-1、W1-3、W1-5和W1-6生产工段,甲醛、丁烯酮、醛酮聚合物和吡啶可能是导致生产废水难降解的重要原因;酮苷生产废水中的难降解物质主要来自W2-1、W2-3和W2-7生产工段,氯代有机溶剂和苯环类物质可能是导致生产废水难降解的重要原因。建议根据具体生产工段排水的水质特征,有针对性地进行物化处理,提高废水可生化性。     

Cost-effectiveness of two operational models at industrial wastewater treatment plants in China: A case study in Shengze town,Suzhou City

The widespread illegal discharge of industrial wastewater in China has posed significant challenges to the effective management of industrial wastewater treatment plants (IWTPs) and caused or exacerbated critical social issues such as trans-boundary environmental pollution. This study examines two operational strategies, decentralized model and an innovative integrated model, that have been used in the industrial town of Shengze (located in Suzhou City) over the past two decades at IWTPs handling wastewater from the city’s dyeing industry. Our cost-effectiveness analysis shows that, although the operational cost of IWTPs under the integrated model is higher than under the original decentralized model, the integrated model has significantly improved IWTP performance and effectively reduced illegal discharge of industrial wastewater. As a result, the number of reported incidents of unacceptable pollution in local receiving water bodies had declined from 13 in 2000–1 in 2008. Key factors contributing to the success of the innovative integrated model are strong support from municipal and provincial leaders, mandatory ownership transfer of IWTPs to a centralized management body, strong financial incentives for proper plant management, and geographically-clustered IWTPs.     

植物监测在大气污染监测中的应用

近年来环境污染日益严重,成为举世瞩目的全球性问题。许多国家每年花费巨资对环境污染进行监测和治理。研究发现,植物在大气污染监测中起着不可忽视的作用,并以其价格低廉、方便灵活的特点成为一项具有发展前景的监测手段。简要概括了植物监测技术在大气污染监测中具有价格低廉、方便灵活、反应灵敏、美化环境等应用优点,分析了难以标准化、规范化等局限性。通过举例详细说明了地衣、苔藓等生物监测器在大气污染监测中的具体用途。     

Evaluation of airborne particulate matter and metals data in personal,indoor and outdoor environments using ED-XRF and ICP-MS and co-located duplicate samples

Factors and sources affecting measurement uncertainty associated with monitoring metals in airborne particulate matter (PM) were investigated as part of the Windsor, Ontario Exposure Assessment Study (WOEAS). The assessment was made using co-located duplicate samples and a comparison of two analytical approaches: ED-XRF and ICP-MS. Sampling variability was estimated using relative percent difference (RPD) of co-located duplicate samples. The comparison of ICP-MS and ED-XRF results yields very good correlations (R² ≥ 0.7) for elements present at concentrations that pass both ICP-MS and ED-XRF detection limits (e.g. Fe, Mn, Zn, Pb and Cu). PM concentration ranges (median, sample number) of 24-h indoor PM₁₀ and personal PM₁₀ filters, and outdoor PM_2.5 filters were determined to be 2.2–40.7 (11.0, n = 48) μg m^?3, 8.0–48.3 (11.9, n = 48) μg m^?3, and 17.1–42.3 (21.6, n = 18) μg m^?3, respectively. The gravimetric analytical results reveal that the variations in PM mass measurements for same-day sampling are insignificant compared to temporal or spatial variations: 92%, 100% and 96% of indoor, outdoor and personal duplicate samples, respectively, pass the quality criteria (RPD ≤ 20%). Uncertainties associated with ED-XRF elemental measurements of S, Ca, Mn, Fe and Zn for 24-h filter samples are low: 78%–100% of the duplicate samples passed the quality criteria. In the case of 24-h filter samples using ICP-MS, more elements passed the quality criteria due to the lower detection limits. These were: Li, Na, K, Ca, Si, Al, V, Fe, Mn, Co, Cu, Mo, Ag, Zn, Pb, As, Mg, Sb, Sn, Sr, Th, Ti, Tl, and U. Low air concentrations of metals (near or below instrumental detection limits) and/or inadvertent introduction of metal contamination are the main causes for excluding elements based on the pass/fail criteria. Uncertainty associated with elemental measurements must be assessed on an element-by-element basis.     

江苏省能源可持续发展模式初探

针对目前江苏省能源可持续发展面临的挑战,以保障江苏能源综合供需平衡和实现能源 经济 环境协调发展为目标,以调整能源结构、优化能源供给体系、提高能源转化效率和清洁性为立足点,以充分利用省内不同区位的能源发展优势为主线,因地制宜地提炼出江苏省能源可持续发展的基本模式,包括自有资源优化开发模式和外部资源导入开发模式两大类型。其中,自有资源优化开发模式又可分为徐州煤炭工业综合体、苏北石油工业基地和沿海滩涂型可再生能源基地3种子模式;外部资源导入开发模式可分为沿江电力生产基地、苏南电力负荷中心和沿海临港型能源基地3种子模式。各种模式协同发展,有利于增强江苏省的能源可持续发展能力.     

机械冲击振打扁袋和脉冲圆袋除尘器性能对比

对脉冲对反吹圆袋除尘器和机械冲击振打扁袋除尘器进行了数字计算和分析对比,显示前者落后,后者先进,并对空气净化除尘及可预计的节能降耗目标进行了粗估。     

污水处理厂一级A出水低温热能的回收与应用

阐述了国内外污水热能的应用现状,介绍了污水源热泵的工作原理、系统优越性、存在的问题。以工程实例证明污水源热泵是高效节能、经济可行、节能环保的新能源,对开发新的清洁能源、减少温室气体排放有重要价值。     

四川地震灾后生态低碳均衡的统筹重建模式

5.12汶川大地震破坏了四川的森林、草地、农田和湿地等生态要素,灾区的气候、山体、水体、森林等环境参量受地震影响发生了变化,生态系统表现出高碳不均衡特征。为了解决生态系统高碳化,本文采用系统均衡理论,从灾区生态实际状况出发,归纳出灾后生态系统整体特征——熵值增大化、结构高碳化、生态复杂化、系统巨量化;针对震后生态系统结构表现出的高碳化,通过对生态碳循环规律的深入研究,提出生态碳循环均衡概念,构建出灾后生态低碳均衡结构;运用统筹思想,兼顾自然生态系统和人工生态系统碳循环的不同特点,以自然生态的增汇和人工生态的减源作为实践方向,建立灾后生态重建的运行模式;从生态城市、生态工业、生态农业三个维度实施灾后低碳重建工程,并提出在灾区实施低碳政策、实现低碳生产、构建碳汇基地、建立碳汇市场等相关建议,保障灾后生态恢复与人类社会重建的可持续协调发展。     

臭氧氧化法处理焦化废水生化出水的反应动力学简

对臭氧氧化去除焦化废水生化出水COD的反应动力学及其影响因素进行了实验研究,结果表明,在臭氧投加量为8.50 mg/min,反应温度为20℃和初始pH为10.61条件下,对COD的降解符合表观一级反应动力学模型,其相关系数R²=0.9991,表观反应速率常数k_Abs=1.01×10^-3 s^-1。该条件下,臭氧氧化对COD的降解主要来源于高活性羟基自由基的强氧化作用。在不同的臭氧投加量（4.25~12.75 mg/min）、不同的反应温度（10~40℃）和不同的初始pH（3.76~12.53）下,COD的降解也同样遵循一级反应动力学规律。随着臭氧投加量的增大,COD降解的表观反应速率常数从（0.554×10^-3） s^-1增加到（1.06×10^-3） s^-1;随着反应温度的升高,表观反应速率常数从（0.427×10^-3） s^-1增加到（1.40×10^-3） s^-1,温度越高反应速率提高的幅度却越小;在初始pH3.76~10.61范围内,表观反应速率常数从（0.218×10^-3） s^-1增加到（1.01×10^-3） s^-1,在初始pH为12.53时表观反应速率常数下降到（0.857×10^-3） s^-1。     

突变灰盖鬼伞过氧化物酶降解刚果红的响应面法优化分析简

酶法降解偶氮染料刚果红是一个复杂的过程,受温度、pH、酶量、刚果红浓度和双氧水浓度显著影响。为研究各因素及因素间交互作用对刚果红降解影响,提高刚果红的降解率,分别使用单因素法和响应面分析法对刚果红降解条件进行了优化。单因素实验结果显示灰盖鬼伞过氧化物酶降解刚果红的最适条件为：pH 5.0、32℃、酶量4.98 U、双氧水0.1 mmol/L、刚果红20 mg/L,此时刚果红最高降解率为34.84%。然后选双氧水浓度、刚果红浓度和灰盖鬼伞过氧化物酶量作为3个因素,通过中心组合设计实验,用响应面法对刚果红降解进行优化分析,最后得到一个拟合度良好的二次多项方程模型（R²=0.9900）。方差分析结果显示,刚果红浓度和酶量是影响最显著的因素,双氧水与酶以及染料与酶之间的交互作用极显著。响应面分析优化后的反应体系为：双氧水浓度0.15 mmol/L,刚果红浓度为27.21 mg/L,酶为2.0 7 U,在此条件下,刚果红降解率达58.13%。