Preparation and evaluation of bis(diallyl alkyl tertiary ammonium salt) polymer as a promising adsorbent for phosphorus removal

Problems associated with water eutrophication due to high phosphorus concentrations and related environmentally safe solutions have attracted wide attention. A novel bis(diallyl alkyl tertiary ammonium salt) polymer, particularly poly(N~1,N~1,N~6,N~6-tetraallylhexane-1,6-diammonium dichloride)(PTAHDADC), was synthesized and characterized by Fourier transform infrared spectroscopy, nuclear magnetic resonance, scanning electron microscopy, mercury intrusion method, and thermogravimetric analysis. The adsorption characteristics in phosphorus were evaluated in dilute solution, and the recycling properties of PTAHDADC were investigated. Results showed that PTAHDADC possessed macropores with a size distribution ranging from 30 to 130 μm concentrating at 63 μm in diameter and had 46.52% of porosity, excellent thermal stability below 530 K, and insolubility. PTAHDADC could effectively remove phosphorus at p H = 7–11 and had a removal efficiency exceeding 98.4% at pH = 10–11. The adsorption equilibrium data of PTAHDADC for phosphorus accorded well with the Langmuir and pseudo-second-order kinetic models. Maximum adsorption capacity was 52.82 mg/g at 293 K. PTAHDADC adsorbed phosphorus rapidly and reached equilibrium within 90 min. Calculated activation energy Eawas 15.18 k J/mol. PTAHDADC presented an excellent recyclability with only 8.23% loss of removal efficiency after five adsorption–desorption cycles. The morphology and structure of PTAHDADC slightly changed as evidenced by the pre-and post-adsorption of phosphorus, but the process was accompanied by the partial deprotonation of the(–CH_2)_3-NH~+ group of PTAHDADC. The adsorption was a spontaneous exothermic process driven by entropy through physisorption, electrostatic attraction, and ion exchange. Survey results showed that PTAHDADC was a highly efficient and fast-adsorbing phosphorus-removal material prospective in treating wastewater.     

A reasoned approach towards administering COVID-19 vaccines to pregnant women

There are over 50 SARS-CoV-2 candidate vaccines undergoing Phase II and III clinical trials. Several vaccines have been approved by regulatory authorities and rolled out for use in different countries. Due to concerns of potential teratogenicity or adverse effect on maternal physiology, pregnancy has been a specific exclusion criterion for most vaccine trials with only two trials not excluding pregnant women. Thus, other than limited animal studies, gradually emerging development and reproductive toxicity data, and observational data from vaccine registries, there is a paucity of reliable information to guide recommendations for the safe vaccination of pregnant women. Pregnancy is a risk factor for severe COVID-19, especially in women with comorbidities, resulting in increased rates of preterm birth and maternal morbidity. We discuss the major SARS-CoV-2 vaccines, their mechanisms of action, efficacy, safety profile and possible benefits to the maternal-fetal dyad to create a rational approach towards maternal vaccination while anticipating and mitigating vaccine-related complications. Pregnant women with high exposure risks or co-morbidities predisposing to severe COVID-19 infection should be prioritised for vaccination. Those with risk factors for adverse effects should be counselled accordingly. It is essential to support patient autonomy by shared decision-making involving a risk-benefit discussion with the pregnant woman.     

Coordination Degree of Urban Population, Economy, Space, and Environment in Shenyang Since 1990

In the background of China's rapid urbanization, the conflicts between urban population, economy, space, and environment are intensified and complicated. This article aims to establish a coordinate assessment method for studying urban population, economy, space, and environment interactions in city scale by principal component analysis and regression analysis. On the basis of the case study on Shenyang city, the results indicated that the integrated development of urban population, economic, and space was in a poor situation from 1993 to 1999, whereas it turned better after 2000, and the urban environment improved steadily after 1998. The static coordination degree of urban integrated development and environment showed obvious periodical and fluctuant characteristics. Compared with the static coordination degree, the dynamic coordination degree appeared to be smooth and lag. The static coordination degree was elementary discoordinative in 1993, 1994, and 1999; whereas it turned to be elementary coordinative between 1995 and 2005. The dynamic coordination degree was elementary discoordinative from 1993 to 1996, whereas it became elementary coordinative overall after 1997.     

安徽沿江地带投资环境综合研究

改善投资环境吸引外资是经济发展的重要内容。安徽沿江地带是长江经济带重要的组成部分，对安徽沿江地带投资环境进行了分析与评价，并就进一步完善沿江地带宏观投资环境，推动经济联合发展提出了建议与措施。     

黄山贫困山区资源特点与治贫开发对策

黄山是我国十大风景名胜区之一，但全区经济发展水平十分落后，属安徽省贫困地区之一。本文对黄山贫困山区的资源特点与存在问题进行了综合分析，指出了本区贫困落后的主要原因，并就治贫开发提出了相应对策。     

Mechanisms and evidence of vertical transmission of infections in pregnancy including SARS-CoV-2s

There remain unanswered questions concerning mother-to-child-transmission of SARS-CoV-2. Despite reports of neonatal COVID-19, SARS-CoV-2 has not been consistently isolated in perinatal samples, thus definitive proof of transplacental infection is still lacking. To address these questions, we assessed investigative tools used to confirm maternal-fetal infection and known protective mechanisms of the placental barrier that prevent transplacental pathogen migration. Forty studies of COVID-19 pregnancies reviewed suggest a lack of consensus on diagnostic strategy for congenital infection. Although real-time polymerase chain reaction of neonatal swabs was universally performed, a wide range of clinical samples was screened including vaginal secretions (22.5%), amniotic fluid (35%), breast milk (22.5%) and umbilical cord blood. Neonatal COVID-19 was reported in eight studies, two of which were based on the detection of SARS-CoV-2 IgM in neonatal blood. Histological examination demonstrated sparse viral particles, vascular malperfusion and inflammation in the placenta from pregnant women with COVID-19. The paucity of placental co-expression of ACE-2 and TMPRSS2, two receptors involved in cytoplasmic entry of SARS-CoV-2, may explain its relative insensitivity to transplacental infection. Viral interactions may utilise membrane receptors other than ACE-2 thus, tissue susceptibility may be broader than currently known. Further spatial-temporal studies are needed to determine the true potential for transplacental migration.     

东方大港的探讨—利用GIS对宁波深水港的分析

根据孙中山先生提出的在我国北、东、南建立三方大港的思想，对我国东部沿海的宁波港进行了分析。在对其历史和现状分析的基础上，借助于现代的信息系统技术和遥感技术，对宁波港的水深状况和集疏运输情况进行了进一步分析，并与北、南二大深水港大连港、广州港、以及我国目前最大的上海港作了比较，提出了正在快速发展的宁波港有潜力成为我国的东方大港，为国家对港口的宏观布局提供了依据。