成都市危险废物现状调查及污染控制对策研究

本文在对成都市危险废物产生及污染控制状况进行调查分析的基础上,结合国内外危险废物管理经验,提出了成都市危险废物控制的对策及建议。     

One-at-a-time sensitivity analysis of pollutant loadings to subsurface properties for the assessment of soil and groundwater pollution potential

Chemical leak was numerically simulated for four chemical substances: benzene (light non-aqueous phase liquid (NAPL)), tetrachloroethylene (dense NAPL), phenol (soluble in water), and pentachlorophenol (white crystalline solid) in a hypothetical subsurface leak situation using a multiphase compositional transport model. One metric ton of chemical substances was assumed to leak at a point 3.51 m above the water table in a homogeneous unconfined aquifer which had the depth to water table of 7.135 m, the hydraulic gradient of 0.00097, the recharge rate of 0.7 mm/day, and the permeability of 2.92?×?10^?10 m². For comparison, surface spill scenarios, which had a long pathway from source to the water table, were simulated. Using the model results, point-source pollutant loadings to soil and groundwater were calculated by multiplying mass, impact area, and duration above and below the water table respectively. Their sensitivity to subsurface properties (depth to water table, recharge rate, porosity, organic carbon content, decay rate, hydraulic gradient, capillary pressure, relative permeability, permeability) was analyzed, with changing each parameter within acceptable ranges. The study result showed that the pollutant loading to groundwater was more sensitive to the subsurface properties than the pollutant loading to soil. Decay rate, groundwater depth, hydraulic gradient and porosity were influential to pollutant loadings. The impact of influential parameters on pollutant loadings was nonlinear. The dominant subsurface properties of pollution loadings (e.g., decay rate, groundwater depth, hydraulic gradient, and porosity for groundwater) also affect the vulnerability, and the subsurface pollutant loadings defined in this study are dependent on chemical properties as well, which indicates that the influential hydrogeological and physicochemical parameters to pollutant loadings can be used for pollution potential assessment. The contribution of this work is the suggestion that the sensitivity of pollutant loadings can be used for pollution potential assessment. Soil and groundwater pollution potential of chemicals are discussed altogether for leak scenarios. A physics-based model is used to understand the impact of subsurface properties on the fate and transport of chemicals above and below the water table, and consequently their impact on the pollutant loading to soil and groundwater.

     

Integrating total oxidizable precursor assay data to evaluate fate and transport of PFASs

Fate and transport of per‐ and polyfluoroalkyl substances (PFASs) are complex and are not well understood. Among this class of emerging contaminants, perfluoroalkyl acids (PFAAs) comprising perfluoroalkyl carboxylates (PFCAs) and perfluoroalkyl sulfonates (PFSAs) are being studied more frequently than polyfluorinated compounds. PFAAs are persistent in the environment, recalcitrant to biological degradation, and, therefore, widespread. Previous studies have indicated that some PFASs bioaccumulate. The fate and transport of PFAAs can be complicated by the presence of PFAA precursors. The PFAA precursors are defined in this article as those fluorinated chemicals that can be potentially transformed abiotically or biotically into terminal PFCA or PFSA products. Due to potential biotransformation in the environment, PFAA precursors can influence the temporal and lateral distribution of PFAAs in the environment. Presently, only a very small number of PFAA precursors can be quantitatively analyzed by commercial laboratories. For instance, N‐ethyl perfluorooctanesulfonamidoacetic acid and N‐methyl perfluorooctanesulfonamidoacetic acid are the only two precursors included in the most commonly applied PFAS analytical method, U.S. Environmental Protection Agency Method 537. The current commercial laboratory methodologies primarily quantify between 14 and 31 PFASs. As an alternative, a total oxidizable precursor assay (TOPA) was developed to quantify the measurable PFSA and PFCA concentrations after aggressive oxidation converting PFAA precursors abiotically into PFCAs. The difference between PFAA concentrations before and after oxidation can be used to estimate the amount of oxidizable PFAA precursors in the sample. This is one of the first articles that utilized TOPA data to help interpret PFAS fate and transport in the environment.     

国内外环境噪声监测方法比较及启示

综合比较了中国、日本、欧盟、美国和澳大利亚等国家或地区的环境噪声监测与评价方法,分析了声环境质量监测法、噪声地图预测法和噪声源监测法3种环境噪声评估方法的优缺点,认为声环境质量监测法适合现阶段中国环境噪声监测与管理需求,但下一步应结合噪声产生与传播预测方法改进中国声环境监测评价方法,增强对监测过程的质控,增加重点噪声源监测,以期更全面地反映城市声环境质量状况。     

高效液相色谱法测定土壤中多环芳烃的条件优化

研究了加速溶剂萃取(ASE)、固相萃取柱净化(SPE)、高效液相色谱仪(HPLC)联合测定土壤中16种多环芳烃(PAHs)的分析方法,选择以正己烷/丙酮(1+1,V/V)作为ASE提取溶剂,提取液经SPE硅胶小柱净化,正己烷/二氯甲烷(1+1,V/V)进行洗脱,洗脱体积为10 m L,洗脱液经旋转蒸发浓缩至近干,过0.22μm有机滤膜,用乙腈定容至1 m L,最后用HPLC-紫外检测器对提取液中16种PAHs进行定量分析。土壤中16种PAHs的方法检出限为2.8~4.9μg/kg,加标回收率为81.9%~102%,相对标准偏差为2.5%~6.2%,完全满足土壤中PAHs分析的质量控制要求,该法稳定性好、准确度高、可操作性强,适合于土壤样品中16种PAHs的准确测定。     

基于隧道法的机动车对上海城市大气环境中氨的源排放贡献研究

以上海交通最为繁忙的隧道之一的邯郸路隧道为研究对象,设计了隧道内(进口、中段、出口)机动车NH_3排放因子测定实验和隧道外(垂直于隧道口310 m范围内)机动车NH_3排放环境扩散梯度实验。隧道内实验结果表明,隧道出口的ρ(NH_3)分别是隧道进口和外围环境质量浓度的5倍和11倍,机动车NH_3排放因子(平均值±标准差)为(28±5)mg/km。据此估算,2014年上海机动车的NH_3排放总量约为1 300 t,占该市NH_3排放量的12%。梯度实验表明,邯郸路隧道出口处的机动车NH_3排放一旦扩散到大气中,其对环境的影响强度在短短数十米内迅速降低,超过150 m的范围后影响基本趋同。证实了在交通路网密集的城市,机动车是大气环境NH_3的重要来源,进而对城市颗粒物污染有潜在贡献。     

石墨消解-电感耦合等离子体发射光谱法测定染整废水中总锑

建立了全自动石墨消解-电感耦合等离子体发射光谱法测定染整企业废水中总锑的测定方法。结果表明,锑的质量浓度在0~10 mg/L范围内线性关系良好,R值为0.999 5,方法检出限和测定下限分别为0.003和0.012 mg/L,相对标准偏差(RSD)为0.17%~2.6%,加标回收率为96.1%~103.8%。该方法操作简单、分析快速,符合技术规范要求。     

皖江城市带近20 a生态环境变化遥感指数分析

随着城市化进程的不断加快,环境保护问题越来越突出,加强生态文明建设也越来越成为城市发展的重心之一,因此快速监测城市生态环境变化显得尤为重要。选取1995年、2005年、2015年Landsat TM/OLI影像为主要数据源,分别提取绿度、湿度、干度、热度4个生态因子作为评估指标,结合主成分分析,生成遥感生态指数（RSEI）,客观、迅速、定量地对皖江城市带近20 a生态环境变化进行分析。结果表明：1995~2015年皖江城市带生态环境质量先降后升,总体呈上升趋势。其中RSEI从1995年的0.710下降至2005年的0.683再升至2015年的0.728,总共上升了2.54%;1995~2015年生态环境恶化区域面积比例由20.03%到14.56%,减少了26.86%;生态环境改善区域面积比例由21.87%到29.39%,增加了34.39%。生态环境恶化区域主要集中在长江沿岸经济发达的扩张型城市和地区;生态环境改善区域主要集中在植被覆盖、注重环境整治、绿化效果显著地区。总的来说,城市生态质量与植被覆盖情况（NDVI）和不透水建筑面积（NDBSI）关系最为密切,城市扩张发展的同时,应该加强生态文明建设,注重环境保护,增加绿化面积,实现城市的可持续发展。 关键词： 皖江城市带;RSEI指数;城市生态;变化检测;主成分分析     

长江经济带入境旅游经济时空格局动态性——基于ESDA&GWR法

以5 a为时间间隔,运用ESDA法采用旅游外汇收入平均增长量和平均增长率指标,研究长江经济带126个市域单元2000~2015年入境旅游经济的空间格局演化特征,运用GWR法分析入境旅游经济影响因素的空间异质性。结果表明：（1）长江经济带旅游外汇收入平均增长量莫兰指数经历了 0.164 6~0.164 1~0.057 2的变化趋势,增量相似市域由较强集聚向较弱集聚转化,市域旅游经济增长趋于均衡。一级热点区始终位于江浙沿海市域。一级冷点区由研究区中部向苏北转移,空间范围大大缩小。（2）长江经济带旅游外汇收入平均增长率莫兰指数表现为 0.098 6~0.293 1~0.198 9 的变化趋势,市域之间旅游经济增长关联程度增强,总体差异逐渐缩小。一级冷热点区大幅度转移,同时热点区范围大幅度扩大。后期热点市域数量大大超过冷点市域数量。（3）入境旅游发展较为落后的湖南省、云南省增长速度最快,长三角城市群所属市域始终是入境旅游经济增长最活跃的地区。     

甲醛暴露时间延长加剧小鼠哮喘模型肺氧化损伤并促进IL-17表达

为了探究不同暴露时间甲醛对小鼠哮喘模型肺氧化应激及IL-17表达的影响,用浓度为3.0 mg·m~(-3)的甲醛气体吸入染毒,同时将48只雄性Balb/c小鼠随机分为6组:(1)对照组(生理盐水组);(2)ovalbumin(OVA)致敏组;(3)0.5 h甲醛+OVA组;(4)1h甲醛+OVA组;(5)1.5 h甲醛+OVA组;(6)2 h甲醛+OVA组,以不同时间长度进行甲醛暴露,连续35 d。OVA致敏组、0.5 h甲醛+OVA组、1 h甲醛+OVA组、1.5 h甲醛+OVA组、2 h甲醛+OVA组均在第11、18及25天腹腔注射OVA致敏液(5 mg OVA+175 mg Al(OH)_3+30 mL生理盐水),第29~35天(共计1周)进行1%OVA雾化(30 min·d~(-1)),每日1次,诱发哮喘。第36天进行以下操作:取肺组织测定肺系数并制作肺匀浆,检测肺组织中活性氧自由基(ROS)、丙二醛(MDA)和还原型谷胱甘肽(GSH)的含量,并采用ELISA法检测肺组织中IL-17的水平。同时,采用HE染色法观察小鼠肺部气道的病理学变化。结果显示,在浓度为3.0 mg·m~(-3)的甲醛气体吸入染毒条件下,与对照组相比,1.5 h甲醛+OVA染毒组、2 h甲醛+OVA染毒组ROS、MDA、IL-17含量上升,具有统计学意义(P0.01)。同时,随着暴露时间长度的增加,小鼠肺部气道出现明显病理学变化。综上所述,每天2 h甲醛+OVA染毒能对小鼠肺造成损伤并恶化OVA对小鼠肺的损伤,产生炎症反应,并通过氧化应激反应介导。