全文获取类型
收费全文 | 2211篇 |
免费 | 97篇 |
国内免费 | 792篇 |
专业分类
安全科学 | 169篇 |
废物处理 | 137篇 |
环保管理 | 160篇 |
综合类 | 1220篇 |
基础理论 | 385篇 |
污染及防治 | 734篇 |
评价与监测 | 78篇 |
社会与环境 | 59篇 |
灾害及防治 | 158篇 |
出版年
2024年 | 1篇 |
2023年 | 43篇 |
2022年 | 118篇 |
2021年 | 105篇 |
2020年 | 61篇 |
2019年 | 69篇 |
2018年 | 79篇 |
2017年 | 106篇 |
2016年 | 132篇 |
2015年 | 162篇 |
2014年 | 157篇 |
2013年 | 224篇 |
2012年 | 181篇 |
2011年 | 188篇 |
2010年 | 148篇 |
2009年 | 121篇 |
2008年 | 146篇 |
2007年 | 121篇 |
2006年 | 104篇 |
2005年 | 76篇 |
2004年 | 63篇 |
2003年 | 74篇 |
2002年 | 61篇 |
2001年 | 58篇 |
2000年 | 59篇 |
1999年 | 79篇 |
1998年 | 61篇 |
1997年 | 56篇 |
1996年 | 49篇 |
1995年 | 49篇 |
1994年 | 27篇 |
1993年 | 38篇 |
1992年 | 31篇 |
1991年 | 24篇 |
1990年 | 14篇 |
1989年 | 3篇 |
1988年 | 5篇 |
1987年 | 1篇 |
1984年 | 3篇 |
1981年 | 2篇 |
1958年 | 1篇 |
排序方式: 共有3100条查询结果,搜索用时 0 毫秒
141.
PCBs污染土壤的CaO诱导低温热处理脱氯研究 总被引:1,自引:0,他引:1
研究了低温热处理脱氯技术对废弃电容器封存点附近污染土壤中多氯联苯脱氯的效果,考察反应温度、反应时间及CaO添加比例对PCBs去除率、脱氯率的影响以及反应前后土壤中污染物的组分变化.实验土样中PCBs浓度为107.7 mg/g,属于罕见高浓度PCBs污染土壤.当反应温度为400℃、停留时间4h、CaO添加比例为10%,PCBs的去除率为87.7%,脱氯率为85.3%.土壤样品中五氯联苯和四氯联苯反应后含量降低或未检出,部分反应后样品检出一氯联苯和联苯,说明在CaO诱导PCBs低温热处理脱氯反应中存在逐步脱氯/加氢反应途径. 相似文献
142.
143.
144.
Zeyou Chen Hui Li Anping Peng Yanzheng Gao 《Environmental science and pollution research international》2014,21(18):10696-10705
Polycyclic aromatic hydrocarbons (PAHs) are environmental contaminants that are toxic, mutagenic, and carcinogenic. We investigated the horseradish peroxidase (HRP)-catalyzed oxidation of PAHs in water containing N,N-dimethylformamide. Four PAHs (anthracene, phenanthrene, pyrene, and fluoranthene) were investigated using single-PAH and mixed-PAH systems. The results provide useful information regarding the preferential oxidation of anthracene over other PAHs regardless of the reaction time, enzyme dosage, and hydrogen peroxide concentration. The removal of PAHs was found to be very strongly correlated with the ionization potential (IP), and much greater PAH oxidation was observed at a lower IP. The oxidation of anthracene was specifically pH- and temperature-dependent, with the optimal pH and temperature being 8.0 and 40 °C, respectively. The redox mediators 1-hydroxybenzotriazole and veratryl alcohol promoted the transformation of anthracene by HRP; 9,10-anthraquinone was the main product detected from the anthracene oxidation system. The results of this study not only provide a better understanding of the oxidation of PAHs by utilizing a plant biocatalyst, but also provide a theoretical basis for establishing the HRP-catalyzed treatment of PAH-contaminated wastewater. 相似文献
145.
The formation of disinfection by-products (DBPs), including both nitrogenous disinfection by-products (N-DBPs) and carbonaceous disinfection by-products (C-DBPs), was investigated upon chlorination of water samples following two treatment processes: (i) coagulation-inclined plate sedimentation (IPS)-filtration and (ii) coagulation-dissolved air flotation (DAF)-filtration. The removal of algae, dissolved organic nitrogen (DON), dissolved organic carbon (DOC) and UV254 by coagulation-DAF-filtration was superior to coagulation-IPS-filtration. On average, 53%, 53% and 31% of DOC, DON and UV254 were removed by coagulation-DAF-filtration process, which were higher than 47%, 31% and 27% of that by coagulation-IPS-filtration process. Additionally, coagulation-IPS-filtration performed less well at removing the low molecular weight organics than coagulation-DAF-filtration process. The concentrations of chloroform, dichloroacetamide (DCAcAm) and dichloroacetonitrile (DCAN) formed during chlorination after coagulation-DAF-filtration reached their maximum values of 13, 1.5 and 4.7 μg L−1, respectively, and were lower than those after coagulation-IPS-filtration with the maximum detected levels of 17, 2.9 and 6.3 μg L−1. However, the trichloronitromethane (TCNM) concentration after the two processes was similar, suggesting that DON may have less of a contribution to TCNM formation than DCAcAm and DCAN. 相似文献
146.
铁路安全预警系统的研究和实现 总被引:2,自引:2,他引:2
结合哈尔滨铁路局实际运营系统 ,基于事故树分析理论 ,探讨了铁路安全预警系统的实现。首先论述了事故树的建立方法和以事故树分析法为基础的铁路安全预警系统的核心算法 ,然后讨论了具体实现的数据结构和事故树编码方法 ,最后简要提出了铁路安全预警系统的系统设计思想 相似文献
147.
148.
149.
Linking landscape development intensity within watersheds to methyl-mercury accumulation in river sediments 总被引:1,自引:0,他引:1
An indicator of the disturbance of natural systems, the landscape development intensity (LDI) index, was used to assess the potential for land-use within watersheds to influence the production/accumulation of methyl-mercury (MeHg) in river sediments. Sediment samples were collected from locations impacted by well-identified land-use types within the Mobile-Alabama River Basin in Southeastern USA. The samples were analyzed for total-Hg (THg) and MeHg concentrations and the obtained values correlated to the calculated LDI indexes of the sampled watersheds to assess the impact of prevalent land use/land cover on MeHg accumulation in sediments. The results show that unlike THg, levels of MeHg found in sediments are impacted by the LDI indexes. Overall, certain combinations of land-use types within a given watershed appear to be more conducive to MeHg accumulation than others, therefore, pointing to the possibility of targeting land-use practices as potential means for reducing MeHg accumulation in sediments, and ultimately, fish contamination. 相似文献
150.
湖泊底泥磷释放及磷形态变化 总被引:2,自引:0,他引:2
为研究底泥中内源性磷释放对城市景观水体富营养化的影响,以西安市曲江南湖为对象,采用底泥磷形态标准测试方法(SMT)分析了磷的赋存形态,通过模拟实验探究了在不同环境条件(温度、pH和溶解氧)下磷形态变化的特征。结果表明:温度升高促进内源磷的释放,在夏季加剧水体富营养化程度;碱性条件有利于磷的释放,增大补给水源可减少底泥释磷量;厌氧环境下底泥释磷量是好氧时的3.96倍;Al-P 和Ca-P较稳定,在酸性条件下会加速其溶解;NH4+-P、 Fe-P 和OrgP受溶解氧、pH和温度影响较大,其吸附与释放能力有明显的差异。 相似文献