Effective removal of coordinated copper from wastewater using a new dithiocarbamate-type supramolecular heavy metal precipitant

A new dithiocarbamate-type heavy metal precipitant, sodium 1,3,5-hexahydrotriazinedithiocarbamate (HTDC), was prepared and used to remove coordinated copper from wastewater. In the reported dithiocarbamate-type precipitants, HTDC possesses the highest percentage of the effective functional groups. It could effectively precipitate copper to less than 0.5 mg l⁻¹ from both synthetic and actual industrial wastewater containing CuEDTA in the range of pH 3–9. UV–vis spectral investigation and elemental analysis suggested that the precipitate was a kind of coordination supramolecular compound, [Cu₃(HTDC)₂]_n. The toxicity characteristic leaching procedure (TCLP) and semi-dynamic leaching test (SDLT) indicated that the supramolecular precipitate was non-hazardous and stable in weak acid and alkaline conditions. Tests of an anion exchange resin D231 provided a clue to simultaneously remove excess HTDC and residual CuEDTA in practical process of wastewater treatment.     

天然气开采废水处理技术综述

针对天然气开采废水量大、矿化度高、杂质含量多、处理难度大的问题,从预处理技术、COD处理技术、氨氮处理技术、脱盐处理到深度处理技术等对各种处理技术进行分析和对比,说明了各种方法的特点和适用情况等。根据对各种方法的特点总结,结合不同废水的水质特点,提出适宜的组合处理方法,并探讨了综合处理技术在部分地区的工程化应用情况。     

Structure optimization and annual performance analysis of the lens-walled compound parabolic concentrator

The primary lens-walled compound parabolic concentrator (lens-walled CPC) has a significant advantage of a larger half acceptance angle as a static solar concentrator, but it also has a drawback of a low optical efficiency. In order to overcome this drawback, in this article, series of structure parameters were investigated and compared to further improve the optical efficiency within the half acceptance angle combined with the material properties. The average optical efficiencies of the improved lens-walled CPCs could achieve more than 82% within the half acceptance angle of 35?. Experiments were adopted to verify the credibility and validity of the simulation. Moreover, annual performance of the lens-walled CPCs comparison with that of the mirror CPC for Nottingham was analyzed. Results show that the improved lens-walled CPC has a higher optical performance for actual building application.     

EGSB出水回流对EGSB—SBR工艺处理果汁废水的影响

采用EGSB—SBR工艺处理实际果汁废水(COD 2 608~6 500 mg/L,p H 5.0~7.0)。在EGSB反应器成功启动及驯化完成的情况下,连续运行49 d。实验结果表明:第25天起,控制EGSB回流比为3.00∶1,EGSB反应器可在无须添加Na HCO3的条件下稳定运行,从而降低了废水处理成本;第25天起,平均进水COD,BOD5,SS分别为5 968,2 130,1 020 mg/L,平均出水COD,BOD5,SS分别降至131,11,50 mg/L,平均COD,BOD5,SS去除率分别为98%,99%,95%;组合工艺对该实际果汁废水具有良好的处理效果。     

环境影响后评价的最新进展与建议

结合《中华人民共和国环境影响评价法》的有关条款,探讨了环境影响后评价的概念、分类、适用对象、意义和内容,提出了环境影响后评价的管理和实施程序.结合多年的实践,分析了目前环境影响后评价工作在理论、方法和管理上存在的问题,提出了改进和完善的建议.案例实践表明,开展环境影响后评价有助于提高环境影响评价制度的有效性.     

腐殖酸、细颗粒泥沙对粉末活性炭吸附苯酚特性影响的研究

通过一系列实验,探讨了粉末活性炭吸附水中苯酚时,腐殖酸(HA)浓度和细颗粒泥沙用量对苯酚吸附量和去除率的影响.实验结果表明:在中性条件下,随着HA浓度的增加,粉末活性炭对苯酚的吸附量减少;在不同质量细颗粒泥沙的影响下,苯酚的去除率基本不变;在未加HA时,粉末活性炭对苯酚的吸附行为用Langmuir吸附等温式拟合效果最好,对苯酚的最大吸附量为150.60 mg/g,而在有HA存在时,粉末活性炭对苯酚的吸附行为用Freundlich吸附等温式拟合效果最好,对苯酚的最大吸附量为28.49 mg/g.     

Investigation of PM2.5 pollution during COVID-19 pandemic in Guangzhou, China

The COVID-19 pandemic has raised awareness about various environmental issues,including PM_2.5 pollution.Here,PM_2.5 pollution during the COVID-19 lockdown was traced and analyzed to clarify the sources and factors influencing PM_2.5 in Guangzhou,with an emphasis on heavy pollution.The lockdown led to large reductions in industrial and traffic emissions,which significantly reduced PM_2.5 concentrations in Guangzhou.Interestingly,the trend of PM_2.5     

UASB处理低浓度城市生活污水的中试试验

研究1·2m3厌氧反应器(UASB),在自然温度(水温32~5℃)下,处理CODCr浓度为200mg/L左右的低浓度生活污水。实验采用颗粒污泥接种二次启动法。水处理系统在水温32~5℃范围内运行6个月的时间,UASB反应器在上升流速为1·4~1·7m/h,水力停留时间(HRT)为3·0~2·5h,CODCr有机污泥负荷(SLR)为0·06~0·13kg/(kg·d)时,去除效率比较稳定,CODCr去除率达40%~80%。