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131.
阴/非离子表面活性剂强化微米Cu/Fe对水及土壤泥浆中有机氯农药的降解 总被引:1,自引:0,他引:1
选择氯丹、硫丹和灭蚁灵为目标污染物,以实际污染场地土壤为对象,研究了表面活性剂强化微米Cu/Fe双金属对水和土壤泥浆中有机氯农药的降解效果。结果表明,非离子表面活性剂Triton X-100(TX-100)强化效果优于阴离子的十二烷基磺酸钠(SDS)。TX-100强化微米Cu/Fe体系能实现水中有机氯农药的快速高效降解,最佳TX-100浓度为0.1 mmol·L-1。处理12 h后,γ-氯丹、硫丹和α-氯丹的降解率接近100%,灭蚁灵的降解率达到85.2%。对于土壤泥浆体系,偏酸性p H值对微米Cu/Fe的还原活性有重要作用。加入TX-100显著促进了微米Cu/Fe双金属对土壤中有机氯农药的还原降解(P0.05)。Cu负载量的提高增强了污染物的降解去除效果。当m(土)∶V(水)为1∶5、土中Fe投加量w为10%、Cu负载量为5.0%、TX-100浓度为5.0 mmol·L-1、p H值为4~5时,处理72 h后,γ-氯丹、硫丹、α-氯丹和灭蚁灵的降解率分别为83.5%、68.1%、86.8%和70.1%。TX-100强化微米Cu/Fe双金属还原降解是一种有效的有机氯农药污染土壤修复技术。 相似文献
132.
Qing Xia Deyang Kong Guoqiang Liu Qingguo Huang Aamr Alalewi Junhe Lu 《Frontiers of Environmental Science & Engineering》2014,8(3):372-378
The removal of 17β-estradiol (E2) in laccase catalyzed oxidative coupling processes was systematically studied in this work. We focused on the influence of pH and natural organic matter (NOM) on the performance of the enzymatic treatment processes. It was found that the optimal pH for E2 removal was between 4 and 6. The removal of E2 was slightly inhibited in the presence of NOM. Enzymatic transformation of E2 was second-order in kinetics with first-order to both the concentrations of the enzyme and contaminant. Mass spectrum (MS) analysis suggested that coupling products were formed through radical-radical coupling mechanism. The results of this study demonstrated that laccase catalyzed oxidative coupling process could potentially serve as a treatment strategy to control steroid estrogens. 相似文献
133.
Chee Kong Yap Ahmad Ismail Franklin Berandah Edward Soon Guan Tan Siti Shapor Siraj 《毒物与环境化学》2013,95(4):683-695
Green-lipped mussels, Perna viridis, were collected from the eastern and western parts of the Johore Straits in September 2004 and January 2005. Based on the heavy metal concentrations in the different soft tissues (gonad, foot, mantle, gills, muscle, and remaining soft tissues) of these mussel samples, the eastern part of the Johore Straits (which is divided into two portions by a causeway), recorded higher levels of bioavailability and contamination by Cd, Cu, Fe, Ni, and Zn when compared to the western part, while Kg. Pasir Puteh in the eastern part was found to record the highest bioavailability and contamination by heavy metals. The use of different soft tissues of P. viridis as biomonitors of bioavailability and contamination by Cd, Cu, Fe, Pb, Ni, and Zn in the semi-enclosed Johore Straits is proposed, since erroneous results due to spawning and the problem of defecation before dissection could be overcome. Hence, a more accurate interpretation of the bioavailability and contamination by heavy metals in coastal waters could be obtained. To our knowledge, this is the most detailed study on the bioavailability and contamination of heavy metals in the Johore Straits on the Malaysian side of the waterway carried out by using the different soft tissues and metal distribution based on the Mussel Watch approach. 相似文献
134.
Isolated Trichoderma atroviride from Cu-polluted river sediment at the Serdang Industrial Area was studied under in vitro conditions to understand the mechanisms that allowed the fungi to thrive in the Cu-polluted freshwater ecosystem. From this study, adsorption was recognized as the main mechanism of Cu tolerance with 50–85% adsorption during the in vitro experiment. The uptake capacity of the isolate in liquid medium ranged from 0.8 to 11.2 mg g?1 in the potato dextrose broth medium with increasing Cu concentrations from 25 to 300 mg L?1. It was found that 2.7–5.0% of Cu was lost due to washing. The high percentage of Cu adsorption and the high uptake capacity of Cu by T. atroviride suggest that it is a potential bioremediator of Cu. However, further studies are needed to confirm its practical use as a bioremediating agent for Cu under field conditions. 相似文献
135.
Bioavailabilities of metals in sediment to aquatic organisms depend on the strength of metal bonding to particulates. The accumulation tests of Cu and Cd in carp and in snails have been studied in vitro with the solution containing semisynthetic sediment samples in which the contents of various speciation of metal in sediment have been extended. For carp, the accumulation of Cu and Cd is related to the concentration of dissolved metal which in turn is affected by the distributions of speciations in sediment under given environmental conditions. It is another pattern for snails, various speciations of metal in sediment can contribute indirectly to metal accumulation. The contribution ratio, or relative importance of various speciations of metal in sediment can be expressed by multiple linear regression formulas. The contribution of ion‐exchangable speciation and coprecipition with carbonate speciation is 105 times larger than that of residue speciation in sediment. 相似文献
136.
运用Fluent软件对重庆市嘉陵江化龙桥段瑞安新天地江水水源热泵系统尾水排入受纳水域的过程进行二维数值模拟,选取Fluent中非耦合、隐式求解器对模型内的定常流动进行求解,得出受纳水域受水源热泵系统温排水影响后的温升面积和温度梯度。结果表明:在温排水流量为2.0×103 m3/h、温差为4℃的条件下,计算该水域沿水流方向温升超过1℃的最大影响距离为150.4 m,温升超过1℃的水域面积约为1 525 m2,为模拟江水面积的8.59%。选取1℃温升值作为温升带的边界控制值,并在热泵系统最大负荷工况下,根据W=Q×ΔT计算研究水域热环境容量为19.402 m3.℃/s,剩余热环境容量为17.736 m3.℃/s。根据地表水环境质量标准,该工程温排水量小于受纳水域的热承载力,不会对受纳水域生态环境造成热污染。 相似文献
137.
秸秆还田配施化肥及微生物菌剂对水田土壤酶活性和微生物数量的影响 总被引:8,自引:0,他引:8
土壤微生物学特性是表征土壤质量的重要生物学指标。通过田间试验研究了秸秆还田配施不同配比化肥及微生物菌剂对水田土壤酶活性和微生物数量的影响。结果表明,与单施秸秆相比,秸秆还田配施N、P、K及微生物菌剂后,土壤过氧化氢酶、转化酶和尿酶活性分别提高了37.5%~68.8%、32.3%~61.5%和48.8%~102%,细菌和真菌数量分别提高了95.3%~174%、286%~351%,放线菌数量减少了34.5%~39.4%,差异显著。统计分析显示,土壤过氧化氢酶与尿酶活性之间及其酶活性与微生物数量之间关系密切。氨化细菌和硝化细菌数量主要控制土壤过氧化氢酶活性,真菌数量是转化酶活性的主要影响因素,而尿酶活性主要受细菌数量影响。秸秆还田配施微生物菌剂及平衡施肥可以促进酶活性的增强,使土壤微生物群落物种个体数增加更多,分布更为均匀。过量施用氮肥会抑制土壤酶活性和微生物的生长和繁殖。 相似文献
138.
Aquatic plants along the North Canal in Beijing were studied to identify the community structure of aquatic plants and vegetation index of biotic integrity (VIBI), and to provide scientific basis for the management and protection of urban rivers. Aquatic plants from 49 sampling sites along the North Canal were investigated during June 2015. Based on the field data, distributing range analysis, discriminatory power analysis, and correlation analysis were used stepwise to select core metrics from candidate metrics to establish the VIBI assessment system. The VIBI value of each sampling site was calculated as the average of the scaled values of all core metrics. Thirty-six aquatic plant species, including 14 hygrophytes, 13 emergent species, 6 submergent species, 2 floating-leaved species, and 1 floating species were collected. Species diversity was low in the North Canal, and no aquatic plants were recorded in 28 sampling sites, of which 9 sampling sites were dried up. Five sites were in excellent condition (VIBI > 0.60), 5 were good (0.60 > VIBI > 0.38), 7 were fair (0.38 > VIBI > 0.23), and 4 were poor (VIBI < 0.23). Based on the distribution of VIBI, Shahe River and Wenyu River upstream, and Fenghe River located in suburbs had a higher VIBI. Downstream tributaries, such as Qinghe River, Bahe River, and Liangshui River, had a lower VIBI. Correlation analysis showed that habitat quality, habitat complexity, and vegetation diversity along riparian zones were the important factors affecting VIBI along the North Canal, Beijing. Aquatic plants along the North Canal showed low species diversity owing to human disturbance. VIBI along tributaries with limited disturbance from human activities was higher; however, VIBI along tributaries disturbed by frequent human activities was lower. © 2018 Science Press. All rights reserved. 相似文献
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