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521.
W. S. Chow S. G. Tan Z. Ahmad K. H. Chia N. S. Lau K. Sudesh 《Journal of Polymers and the Environment》2014,22(1):140-147
In this study, bio-thermoset from epoxidized soybean oil (ESO) was prepared in the presence of methylhexahydrophthalic anhydride curing agent and 2-ethyl-4-methylimidazole catalyst. The crosslink densities of the synthesized ESO are ranged from 0.109 × 10?3 to 0.308 × 10?3 mol/cm3. The ESO bio-thermosets were exposed to the soil-burial test for 8 months. Weight change and morphology of the degraded ESO specimens were assessed. It was found that the weight loss of ESO was governed by the materials compositions, crosslink density and the soil-burial exposure time. The 3 mm thickness ESO bio-thermosets with crosslink density of 0.109 × 10?3 mol/cm3 had fully biodegraded after soil-burial for 6 months. In addition, 16S rDNA sequencing was carried out to identify the soil microorganisms. It was suggested that Comamonas sp., Bacillus sp., Streptomyces sp. and Acinetobacter sp. are the possible soil microbes that degrade the ESO bio-thermosets in the compost soil environment. 相似文献
522.
In this study, an interval-fuzzy two-stage chance-constrained integer programming (IFTCIP) method is developed for supporting
environmental management under uncertainty. The IFTCIP improves upon the existing interval, fuzzy, and two-stage programming
approaches by allowing uncertainties expressed as probability distributions, fuzzy sets, and discrete intervals to be directly
incorporated within a general mixed integer linear programming framework. It has advantages in uncertainty reflection, policy
investigation, risk assessment, and capacity-expansion analysis in comparison to the other optimization methods. Moreover,
it can help examine the risk of violating system constraints and the associated consequences. The developed method is applied
to the planning for facility expansion and waste-flow allocation within a municipal solid waste management system. Violations
of capacity constraints are allowed under a range of significance levels, which reflects tradeoffs between the system cost
and the constraint-violation risk. The results indicate that reasonable solutions for both binary and continuous variables
have been generated under different risk levels. They are useful for generating desired decision alternatives with minimized
system cost and constraint-violation risk under various environmental, economic, and system-reliability conditions. Generally,
willingness to take a higher risk of constraint violation will guarantee a lower system cost; a strong desire to acquire a
lower risk will run into a higher system cost. 相似文献
523.
C. L. Yang Z. F. Wu H. H. Zhang R. P. Guo Y. Q. Wu 《Environmental monitoring and assessment》2009,159(1-4):381-391
In this study, the spatial distributions of soil lead (Pb) concentration in three horizontal soils in Guangdong, China, were surveyed and analyzed using geostatistics and geography information systems (GIS). Findings indicated that the Pb geometric mean concentration of 23.3 mg/kg in surface soils was found to be higher than those in global soils, which ranged from 2.3–235 mg/kg. In addition, the Pb geometric mean concentrations from A- to C-horizon were found to be 23.3, 27.2, and 28.6 mg/kg, respectively. The classification of a soil Pb environmental risk in an area was likewise presented based on the different levels of environmental quality of Pb and was done by GIS technology. Accordingly, there is a higher local concentration of Pb in the surrounding areas of Guangzhou where there is higher population density and in the north of Guangdong, which is a historic mining area. The results obtained by the environmental risk assessment reveal that about 46% of total surveyed area was above the background value, that is, 2.7% of the total area was at risk of pollution. 相似文献
524.
Grant R. Sutherland Elizabeth Baker Stuart Purvis-Smith Athel Hockey Ed Krumins Sam Z. Eichenbaum 《黑龙江环境通报》1987,7(3):197-202
Eleven pregnancies in ten patients at risk for the fragile X were monitored by amniocentesis or chorion villus biopsy and induction of the fragile site using thymidine, methotrexate and FUdR. Three female fetuses and one male fetus were found to have the fragile X. The results obtained using thymidine induction were superior to those using methotrexate induction and probably better than those obtained using FUdR induction. 相似文献
525.
采用改性沸石分离富集-火焰原子吸收光谱法测定长江水中微量镉,优化了富集和洗脱条件,讨论了干扰离子的影响。方法在0μg~4.00μg范围内线性良好,检出限为0.214μg/L,长江水平行测定的RSD为1.8%,加标回收率为99.0%~104%。 相似文献
526.
Fourteen (14) characters from six (6) water samples collected from springs, ponds, and streams located in Lower Cretaceous sedimentary area of Afikpo Basin have been analyzed. These include pH, turbidity, conductivity, total dissolved solid, hardness, Fe2+, Ca2+, Mg2+, K+, NO3 ?, Cl?, SO4 2?, and Na+. These sediments, which are Turonian and Coniacian in age, are subdivided into two by a basic rock dyke. Results of the analyses show clearly that the Turonian sediments, intruded by dolerite, have net Fe2+, HCO3 ?, Ca2+, Mg2+, Mn2+, Cl?, and SO4 2? concentration while those from the younger Coniacian sediment have net higher amounts of K+, Na+, and Mn2+. The overriding mafic minerals in the basic intrusive rock possibly led to higher leaching into ground water system near it. On the other hand, the presence of feldsparthic to kaolinitic sands of the younger Coniacian units led to higher K+ and Na+ matter in the water from these zones. The formations dip away from the older sediments. Concentrations of these characters are within acceptable drinking water standards by World Health Organization but noticeable anomalous zones for Fe2+, Mg2+, and Ca2+ are zones of basic rock suites. Areas with greater Na+ and K+ are traceable to sandy units. It is thus concluded that more analysis of surface, subsurface, and pond water samples can be utilized for minerals search and geological mapping. At this stage, it forms a veritable reconnaissance tool. 相似文献
527.
Tsung-Hung Hsu Jen-Yang Lin Tsu-Chuan Lee Harry X. Zhang Shaw L. Yu 《Environmental monitoring and assessment》2010,163(1-4):81-94
It is vitally important to define the critical condition for a receiving water body in the total maximum daily load (TMDL) development process. One of the major disadvantages of using a continuous simulation approach is that there is no guarantee that the most critical condition will be covered within the subjectively selected representative hydrologic period, which is usually several years depending on the availability of data. Another limitation of the continuous simulation approach, compared to a design storm approach, is the lack of an estimate of the risk involved. Because of the above limitations, a storm event-based critical flow-storm (CFS) approach was previously developed to explicitly address the critical condition as a combination of a prescribed stream flow and a storm event of certain magnitude, both having a certain frequency of occurrence and when combined, would create a critical condition. The CFS approach was tested successfully in a TMDL study for Muddy Creek in Virginia. The present paper reports results of a comparative study on the applicability of the CFS approach in Taiwan. The Dy-yu creek watershed in northern Taiwan differs significantly from Muddy Creek in terms of climate, hydrology, terrain, and other characteristics. Results show that the critical condition for different watersheds might be also different, and that the CFS approach could clearly define that critical condition and should be considered as an alternative method for TMDL development to a continuous simulation approach. 相似文献
528.
Occurrence and distribution of polycyclic aromatic carbons in sludges from wastewater treatment plants in Guangdong, China 总被引:1,自引:0,他引:1
Xiangying Zeng Zheng Lin Hongyan Gui Wenlan Shao Guoying Sheng Jiamo Fu Zhiqiang Yu 《Environmental monitoring and assessment》2010,169(1-4):89-100
In this study, the occurrence and distribution of polycyclic aromatic hydrocarbons (PAHs) were investigated in six sludge samples collected from Guangdong Province, China. Concentrations of PAHs varying from 2,534.1 to 6,926.6 μg kg???1 (dry sludge) were observed in three municipal wastewater treatment plants with phenanthrene (Phe), fluoranthene, and pyrene being the main compounds. In addition, 682.6 μg kg???1 PAHs were detected in one sludge sample from a food processing plant, with fluorene, Phe, and chrysene being the main components. No PAHs were detected in sludge samples obtained from two cosmetic plants. The levels and distributional characteristics of PAHs, polychlorinated biphenyls (PCBs), and polycyclic musks (PMs) from the samples were also compared. The results of this comparison indicated that petrochemical refineries and road traffic played important roles in the PAH loads in sludge, while PMs primarily originated from domestic wastewater and industrial wastewater from cosmetic plants. Finally, the presence of 98.8 μg kg???1 PCBs in sludge suggested diffusional emission sources from electrical components containing PCBs. 相似文献
529.
530.
高速公路路面沉积物的污染特性 总被引:1,自引:0,他引:1
对湖南省长潭西高速公路不同采样点的路面沉积物进行取样分析,并检测了样品的颗粒级配、COD、重金属(Cu、Zn、Pb和Cd)和有机质。结果表明,路面沉积物主要以粒径<0.15 mm的颗粒为主;较小颗粒物中的COD含量高于较大颗粒中的COD含量;粒径在0.15 mm以下的颗粒物所含重金属Cu、Zn、Pb和Cd的浓度普遍高于所选的土壤标准值,降雨一旦形成径流将会产生严重的污染危害;沉积物中的有机质含量对重金属的吸附有一定的影响,有机质含量越高,沉积物中重金属含量相对也高。 相似文献