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81.
Preparation and Characterization of Hydrogel Based on Poly(vinyl alcohol) Cross-Linked by Different Cross-Linkers Used to Dry Organic Solvents 总被引:1,自引:0,他引:1
Poly(vinyl alcohol) (PVA) hydrogels were chemically cross-linked with/without different cross-linkers such as glutaraldehyde
and epichlorohydrin, in the presence of a catalyst, or activator (potassium hydroxide) to produce three types of hydrogels.
The structures of PVA and the prepared gel types were determined by FTIR spectroscopy, the mechanical and thermal properties,
of these hydrogels were examined. The effects of different pH values and temperatures on the swelling properties of the prepared
gels were examined. From the obtained results, it was found that, the low concentration of the cross-linker produced hydrogel
with moderate properties, but in absence of the cross-linker, the obtained hydrogel exhibited good properties and can be used
as friendly environmentally moisture absorbents from the organic solvents. The insolubility and swelling properties of gels
were tested in these solvents. The results indicated that these hydrogels can be used as moisture absorbents and solvent dryers. 相似文献
82.
G. Shi Z. Chen C. Bi J. Teng S. Xu 《Environmental pollution (Barking, Essex : 1987)》2010,158(3):694-703
A set of toxic metals, i.e. As, Hg, Pb, Cd, Cu, Zn, Ni and Cr, in urban and suburban SDSs were investigated comparatively in the biggest metropolitan area of China, Shanghai. Results showed that all of the metals except As were accumulated greatly, much higher than background values. Geo-accumulation index indicated that metal contamination in urban SDSs was generally heavier than that in suburban SDSs. Potential ecological risk index demonstrated that overall risks caused by metals were considerable. Cd contributed 52% to the overall risk. Multivariate statistical analysis revealed that in urban SDSs, Zn, Ni, Cd, Pb, Cu and Cr were related to traffic and industry; coal combustion led to elevated levels of Hg; soil parent materials controlled As contents. In suburban SDSs, Pb, Cu, As and Cd largely originated from traffic pollution; Zn, Ni and Cr were associated with industrial contaminants; Hg was mainly from domestic solid waste. 相似文献
83.
Grahovac ZM Mitić SS Pecev ET Pavlović AN 《Journal of environmental science and health. Part. B》2010,45(8):783-789
In the present study, a new sensitive and simple kinetic-spectrophotometric method for the determination of the insecticide diflubenzuron [1-(4-chlorophenyl)-3-(2,6-diflubenzoil)urea] is proposed. The method is based on the inhibited effect of diflubenzuron on the oxidation of sulphanilic acid (SA) by hydrogen peroxide in phosphate buffer in presence Cu(II) ion. Diflubenzuron was determined with linear calibration graph in the interval from 0.31 to 3.1 μg mL?1 and from 3.1 to 31.0 μg mL?1. The optimized conditions yielded a theoretical detection limit of 0.18 μg mL?1 corresponding to 0.036 mg kg(-1)mushroom sample based on the 3S(b) criterion. The RSD is 5.03-1.83 % and 2.81-0.71 % for the concentration interval of diflubenzuron 0.31-3.1 μg mL?1 and 3.1-31.0 μg mL?1, respectively. The reaction was followed spectrophotometrically at 370 nm. The kinetic parameters of the reaction are reported, and the rate equations are suggested. The developed procedure was successfully applied to the rapid determination of diflubenzuron in spiked mushroom samples of different mushroom species. The HPLC method was used like a comparative method to verify results. 相似文献
84.
T.M. McIntire O.S. Ryder P.L. Gassman Z. Zhu S. Ghosal B.J. Finlayson-Pitts 《Atmospheric environment (Oxford, England : 1994)》2010,44(7):939-944
It is commonly assumed that atmospheric oxidation of hydrocarbon particles or hydrocarbon coatings on particles leads to polar products and increased water uptake, altering atmospheric visibility and increasing the likelihood they will act as cloud condensation nuclei (CCN). We show here through laboratory experiments that increased water uptake depends on the 3-dimensional structure of the particles. Laboratory studies of particles formed during ozonolysis of surface-bound alkenes, present as terminally unsaturated self-assembled monolayers (C8= SAM) on a silica substrate, were carried out at room temperature and 1 atm pressure. SAMs were exposed to ~1013 O3 molecules cm?3 for 40 min and resultant particles were analyzed using single particle Fourier transform infrared micro-spectroscopy (micro-FTIR) and secondary ion mass spectroscopy (SIMS). Spectroscopy results show that –COOH and other polar groups are formed but are buried inside a hydrophobic shell, consistent with earlier observations (McIntire et al., 2005, Moussa et al., 2009) that water uptake does not increase after reaction of the terminal alkene with O3. These insights into the 3-D structure of particles formed on oxidation have important implications for the ability of secondary organic aerosols to act as CCN. In addition, the nature of the surface of the particles is expected to determine their uptake into biological systems such as the surface of the lungs. 相似文献
85.
Gary Z. Whitten Gookyoung Heo Yosuke Kimura Elena McDonald-Buller David T. Allen William P.L. Carter Greg Yarwood 《Atmospheric environment (Oxford, England : 1994)》2010,44(40):5346-5355
Toluene is ubiquitous in urban atmospheres and is a precursor to tropospheric ozone and aerosol (smog). An important characteristic of toluene chemistry is the tendency of some degradation products (e.g., cresols and methyl-catechols) to form organic nitro and nitrate compounds that sequester NOx (NO and NO2) from active participation in smog formation. Explaining the NOx sinks in toluene degradation has made mechanism development more difficult for toluene than for many other organic compounds. Another challenge for toluene is explaining sources of radicals early in the degradation process. This paper describes the development of a new condensed toluene mechanism consisting of 26 reactions, and evaluates the performance of CB05 with this new toluene scheme (Toluene Update, TU) against 38 chamber experiments at 7 different environmental chambers, and provides recommendations for future developments. CB05 with the current toluene mechanism (CB05-Base) under-predicted the maximum O3 and O3 production rate for many of these toluene–NOx chamber experiments, especially under low-NOx conditions ([NOx]t=0 < 100 ppb). CB05 with the new toluene mechanism (CB05-TU) includes changes to the yields and reactions of cresols and ring-opening products, and showed better performance than CB05-Base in predicting the maximum O3, O3 formation rate, NOx removal rate and cresol concentration. Additional environmental chamber simulations with xylene–NOx experiments showed that the TU mechanism updates tended to improve mechanism performance for xylene. 相似文献
86.
X.X. Zhang P.J. Shi L.Y. Liu Y. Tang H.W. Cao X.N. Zhang X. Hu L.L. Guo Y.L. Lue Z.Q. Qu Z.J. Jia Y.Y. Yang 《Atmospheric environment (Oxford, England : 1994)》2010,44(13):1641-1648
Based on environmental monitoring data in 93 major cities and meteorological records at 398 weather stations in China from 1981 to 2007, total suspended particle (TSP) concentration, the intensity of dustfall, and sand and dust storm frequency (Fd) were analysed. During the past 27 years, the annual average TSP concentration (CTSP) in 93 cities was 402 μg m?3. Annual average CTSP decreased from the north to the south and from inland to the coast areas with a peak value of 628.8 μg m?3 in Lanzhou. In the 1980s, 1990s and 2000s, annual average CTSP was 628.7, 319.2, and 250.1 μg m?3, respectively. Annual average intensity of dustfall (Id) was 240.5 t km?2 a?1, decreased from northern to southern China and from inland to the coast areas with the maximum value of 717.2 t km?2 a?1 in Baotou. In the 1980s, 1990s and 2000s, annual average Id was 334.8, 220.9, 146 t km?2 a?1 respectively. Annual average Id in the Loess Plateau region was commonly higher than 200 t km?2 a?1. The annual average Fd decreased from arid regions in northwestern China to humid areas in southeastern China with two sand and sand storm centers existing in Xinjiang Taklamakan Desert and western Inner Mongolia. The annual average Fd in the 1980s, 1990s, 2000s was 16, 8, 6 days respectively, decreased steadily from 18 days in 1981–5 days in 2007. Annual average Id had a positive linear relation to annual average CTSP (R2 = 0.96). Annual average Fd had a positive relation with annual average CTSP (R2 = 0.97) as well as annual average Id (R2 = 0.94). TSP was the chief pollutant influencing Air Pollution Index (API) in northern China in spring and winter seasons. Sand and dust storm might be a major factor affecting the temporal variability and spatial distribution of TSP and dustfall in China. 相似文献
87.
B. Miljevic K.E. Fairfull-Smith S.E. Bottle Z.D. Ristovski 《Atmospheric environment (Oxford, England : 1994)》2010,44(18):2224-2230
Reactive oxygen species (ROS) and related free radicals are considered to be key factors underpinning the various adverse health effects associated with exposure to ambient particulate matter. Therefore, measurement of ROS is a crucial factor for assessing the potential toxicity of particles. In this work, a novel profluorescent nitroxide, BPEAnit, was investigated as a probe for detecting particle-derived ROS. BPEAnit has a very low fluorescence emission due to inherent quenching by the nitroxide group, but upon radical trapping or redox activity, a strong fluorescence is observed. BPEAnit was tested for detection of ROS present in mainstream and sidestream cigarette smoke. In the case of mainstream cigarette smoke, there was a linear increase in fluorescence intensity with an increasing number of cigarette puffs, equivalent to an average of 101 nmol ROS per cigarette based on the number of moles of the probe reacted. Sidestream cigarette smoke sampled from an environmental chamber exposed BPEAnit to much lower concentrations of particles, but still resulted in a clearly detectible increase in fluorescence intensity with sampling time. It was calculated that the amount of ROS was equivalent to 50 ± 2 nmol per mg of particulate matter; however, this value decreased with ageing of the particles in the chamber. Overall, BPEAnit was shown to provide a sensitive response related to the oxidative capacity of the particulate matter. These findings present a good basis for employing the new BPEAnit probe for the investigation of particle-related ROS generated from cigarette smoke as well as from other combustion sources. 相似文献
88.
Z. G. Prishutova 《Russian Journal of Ecology》2010,41(1):55-59
Vegetation was considerably trampled throughout Vodnyi Island in the Rostovskii Nature Reserve in 2007 because of a high pasture
load due to feral horses (0.15 horses/ha). Calculation of the food resources on the island, with its protection as part of
a nature reserve taken into account, has shown that the herd size is 3.5 times larger than the maximum allowable value. 相似文献
89.
Nilesh S. Gangurde Riyaz Z. Sayyed Shashi Kiran Arvind Gulati 《Environmental science and pollution research international》2013,20(1):488-497
During screening for poly-β-hydroxybutyrate (PHB) producing bacteria from distillery effluent sample, six out of 30 isolates comprising of three strains of Alcaligenes sp., two strains of Bacillus sp., and one strain of Pseudomonas sp. were found to accumulate varying levels of intracellular PHB. Amongst the various isolates, Alcaligenes sp. RZS4 was found as the potent PHB-producing organism, accumulating higher amounts of PHB. PHB productivity was further enhanced in the presence of oxygen, nitrogen-limiting conditions, and cloning of PHB synthesizing genes of Alcaligenes sp. RZS 4 into Escherichia coli. A twofold increase in PHB yield was obtained from recombinant E. coli vis-à-vis Alcaligenes sp.; the recombinant E. coli accumulated more PHB in NDMM, produced good amount of PHB in a single-stage cultivation process under both nutrient-rich and nutrient-deficient conditions. Extraction of PHB with acetone–alcohol (1:1) was found as suitable method for optimum extraction of PHB as this mixture selectively extracted PHB without affecting the non-PHB cell mass. PHB extract from recombinant E. coli showed the presence of C–H, =O stretching, =C–H deformation, =C–H, =CH, and =C–O functional groups characteristic of PHB. 相似文献
90.
X. Q. Liang Z. Y. Nie M. M. He R. Guo C. Y. Zhu Y. X. Chen Küppers Stephan 《Environmental science and pollution research international》2013,20(10):6972-6979
One strategy to combat nitrate (NO3-N) contamination in rivers is to understand its sources. NO3-N sources in the East Tiaoxi River of the Yangtze Delta Region were investigated by applying a 15N–18O dual isotope approach. Water samples were collected from the main channel and from the tributaries. Results show that high total N and NO3-N are present in both the main channel and the major tributaries, and NO3-N was one of the most important N forms in water. Analysis of isotopic compositions (δ 18O, δD) of water suggests that the river water mainly originated from three tributaries during the sampling period. There was a wide range of δ 15N-NO3 (?1.4 to 12.4 ‰) and a narrow range of δ 18O-NO3 (3.7 to 9.0 ‰) in the main channel waters. The δ 15N and δ 18O-NO3 values in the upper, middle, and lower channels along the river were shifted as 8.2, 3.5, and 9.5 ‰, and 9.0, 4.2, and 6.0 ‰, respectively. In the tributary South Tiao, the δ 15N and δ 18O-NO3 values were as high as 9.5 and 7.0 ‰, while in the tributaries Mid Tiao and North Tiao, NO3-N in most of the samples had relatively low δ 15N and δ 18O-NO3 values from 2.3 to 7.5 ‰ and 4.7 to 7.0 ‰, separately. Our results also suggest that the dual isotope approach can help us develop the best management practice for relieving NO3-N pollution in the rivers at the tributary scale. 相似文献