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181.
Jernbro S Rocha PS Keiter S Skutlarek D Färber H Jones PD Giesy JP Hollert H Engwall M 《Environmental science and pollution research international》2007,14(2):85-87
Background, Aim and Scope
Perfluorooctane sulfonate (PFOS; C8F17SO3-) is a fully fluorinated organic compound which has been manufactured for decades
and was used widely in industrial and commercial products. The recent toxicological knowledge of PFOS mainly concerns mono-substance
exposures of PFOS to biological systems, leaving the potential interactive effects of PFOS with other compounds as an area
where understanding is significantly lacking. However, a recent study, reported the potential of PFOS to enhance the toxicity
of two compounds by increasing cell membrane permeability. This is of particular concern since PFOS has been reported to be
widely distributed in the environment where contaminants are known to occur in complex mixtures. In this study, PFOS was evaluated
alone and in combination with cyclophosphamide (CPP) to investigate whether a presence of PFOS leads to an increased genotoxic
potential of CPP towards hamster lung V79 cells. Genotoxicity was investigated using the micronucleus (MN) assay according
to the recent draft ISO/DIS 21427-2 method. PFOS alone demonstrated no genotoxicity up to a concentration of 12.5 mg/L. However,
PFOS combined with two different concentrations of CPP, with metabolic activation, caused a significant increase in the number
of micronucleated cells compared to treatments with CPP only. These results provide a first indication that PFOS has the potential
to enhance the genotoxic action of CPP towards V79 cells, suggesting that together with the alterations in cell membrane properties
shown previously, that genotoxicity of complex mixtures may be increased significantly by changes in chemical uptake. Together
with an earlier study performed by the own working group it can be concluded that PFOS alone is not genotoxic in this bioassay
using V79 cells up to 12.5 mg/L, but that further investigations are needed to assess the potential interaction between PFOS
and other substances, in particular regarding the impact of membrane alterations on the uptake of toxic substances.
Materials and Methods:
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Results:
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Discussion:
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Conclusions:
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Recommendations and Perspectives:
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182.
183.
In the period between 1999 and 2000 epiphytic bryophytes were taken as bioindicators for air pollution by use of the IAP method
(Index of Atmospheric Purity) and the VDI method within the Association of Engineers standards list (adapted from guideline
3799, 1995) in the heavy industrialized town of Linz, Austria. 52 study sites (265 trees) were analysed regarding species
richness, coverage, and vitality. Q-values (sensitivity factors), calculated for each species showed significant differences
for the various host tree species. The results gained by the IAP and the VDI methods were diverse, regarding the various sites
where only 25% were classified identical. These differences can mainly be attributed to the differing host tree species and
the size of the recording area on the various trees. Clusters of similar pollution levels were calculated and drawn as maps
for both methods tested. Comparing the results of the IAP and the VDI methods with data derived from technical measurements
(SO2, NO, NO2, and dust) a correlation between IAP-indices and SO2 concentrations could be observed. No correlation was detected between the results derived from VDI recording and for NO,
NO2, and dust. 相似文献
184.
Azhar Abbas T.S. Amjath-Babu Harald Kächele Muhammad Usman Klaus Müller 《国际发展与全球生态学杂志》2016,23(1):98-111
South Asia faces increasing flooding risks due to climatic and socio-economic changes. Various measures have been adopted by the governments of the countries in this region. However, these measures are not adequate to protect the vulnerable communities from ever-increasing flood losses. This study assesses the policy and planning processes and flood-related scientific research in India, Pakistan and Bangladesh. Based on a systematic review, a comparison of the existing flood management systems of the three countries is undertaken, and a framework for sustainable flood management in the region is suggested. Insights from the literature show that Bangladesh has been able to develop an effective governance structure to address flood hazards, while Pakistan’s approach to flood management planning is found to be largely inadequate. This inadequacy is mainly attributed to missing links in policy formulation and planning processes, along with a lack of institutional coordination. The results of the literature analysis reveal poor support from scientific research focusing on flooding issues in the case of Pakistan, while Bangladesh and India seem to have benefited from research support in formulating their flood management strategies. Based on these findings, an alternative framework is suggested, emphasizing the need to enhance institutional linkages, community participation and evidence-based research. 相似文献
185.
瑞典西海岸北部沿岸水域中的富营养化正在造成沿岸生态系统结构和功能的变化.为了在10~20年的过渡期内降低沿岸水域中营养物质,改善水质,按照欧洲水框架指令的要求,在措施计划中建议开展大规模的贻贝养殖.所有权、土地划拨、利益冲突及沿岸水体的保护正在阻挠着人们进入建立贻贝养殖场的合适水域.本文研究了关乎进入大规模贻贝养殖的沿岸水域这一领域的相关法律和法规中的障碍和可能性.在规划与建筑法、环境指令及与土地划拨和财产有关的法律框架中,给出了解决这个问题的一些可选择的方法并进行了讨论.适当地运用规划与建筑法,可以为进入沿岸水域进行以改善水的生态状况为目的的贻贝养殖提供有益的手段. 相似文献
186.
Investigations concerning the measurement and evaluation of mineral oil hydrocarbons using Fourier-transform-infrared (FT/IR-)-spectroscopy,1H-Nuclear magnetic resonance (1H-NMR)-spectroscopy and Capillary gas chromatography — Flame ionisation detection (GC-FID) are presented. By means of various mineral oils and three certified reference materials (CRM) all tested methods were within a ±7%-range to the mineral oil nominal value and the 95% confidence intervals of the CRM’s, respectively. The GC-FID evaluation could be done without calibration using an relative response ratio of mineral oil to an internal standard (n-tetracontane). A1H-NMR-method was developed for the quantitative determination of mineral oil hydrocarbons, successfully applied down to 0.2 mg/ml. Due to the determination limit achieved, the1H-NMR-spectroscopy gain in importance as a reference method for the analysis of mineral oils. 相似文献
187.
188.
Permeable reactive barriers (PRBs) are widely applied for in-situ remediation of contaminant plumes transported by groundwater. Besides the goal of a sufficient contaminant remediation inside the reactive cell (residence time) the width of plume intercepted by a PRB is of critical concern. A 2-dimensional analytical approach is applied to determine the flow fields towards rectangular PRBs of the continuous wall (CW) configuration with and without impermeable side walls (but yet no funnel). The approach is based on the conformal mapping technique and assumes a homogeneous aquifer with a uniform ambient flow field. The hydraulic conductivity of the reactive material is furthermore assumed to exceed the conductivity of the aquifer by at least one order of magnitude as to neglect the hydraulic gradient across the reactor. The flow fields are analyzed regarding the widths and shapes of the respective capture zones as functions of the dimensions (aspect ratio) of the reactive cell and the ambient groundwater flow direction. Presented are an improved characterization of the advantages of impermeable side walls, a convenient approach to improved hydraulic design (including basic cost-optimization) and new concepts for monitoring CW PRBs. Water level data from a CW PRB at the Seneca Army Depot site, NY, are used for field demonstration. 相似文献
189.
Špela Bavec Mateja Gosar Miloš Miler Harald Biester 《Environmental geochemistry and health》2017,39(3):443-465
A comprehensive geochemical investigation of potentially harmful elements (PHEs) in household dust from the town of Idrija (Slovenia), once a world-famous Hg mining town that is now seriously polluted, was performed for the first time. After aqua regia digestion, the content of mercury (Hg), arsenic (As), cadmium (Cd), cobalt (Co), chromium (Cr), copper (Cu), molybdenum (Mo), nickel (Ni), lead (Pb) and zinc (Zn) was measured. PHE-bearing particles were recognised and observed by scanning electron microscopy and energy-dispersive spectrometry before and after exposure to simulated stomach acid (SSA). Mercury binding forms were identified by Hg thermal desorption technique and gastric bioaccessible Hg was estimated after SSA extraction by ICP-MS. With regard to rural and urban background values for Slovenia, high Hg content (6–120 mg/kg) and slightly elevated As content (1–13 mg/kg) were found. Mercury pollution is a result of past mining and ore processing activities. Arsenic content is potentially associated with As enrichment in local soils. Four Hg binding forms were identified: all samples contained Hg bound to the dust matrix, 14 samples contained cinnabar, two samples contained metallic Hg (Hg0), and one sample assumingly contained mercury oxide. After exposure to SSA, Hg-bearing phases showed no signs of dissolution, while other PHE-bearing phases were significantly morphologically and/or chemically altered. Estimated gastric Hg bioaccessibility was low (<0.006–0.09 %), which is in accordance with identified Hg binding forms and high organic carbon content (15.9–31.5 %) in the dust samples. 相似文献
190.
Harald Geiger Karl H. Becker 《Journal of the Air & Waste Management Association (1995)》2013,63(4):425-433
Abstract Based on exhaust gas analyses from the combustion of five different types of gasoline in a passenger car operated on a chassis dynamometer, box model simulations of the irradiation of exhaust/NOx /air mixtures using an established chemical mechanism for a standardized photo-smog scenario were performed. The fuel matrix used covered wide fractional ranges for paraffinic, olefinic, and aromatic hydrocarbons. Two fuels also contained methyl tertiary butyl ether (MTBE). The different O3 profiles calculated for each run were compared and interpreted. The O3 levels obtained were strongly influenced by the exhaust gas concentrations of aromatic and olefinic hydro-carbons. The higher exhaust content of these compounds caused higher O3 production in the smog system investigated. The conclusion of the present study is that the composition of gasoline cannot be taken directly for the estimation of the emissions’ O3 creation potential from its combustion. Variation of the dilution in the different calculations showed evidence for an additional influence of transport effects. Accordingly, further detailed exhaust gas analyses followed by more complex modeling studies are necessary for a proper characterization of the relationship between fuel blend and gasoline combustion products. 相似文献