Mesoporous WO3-graphene photocatalyst for photocatalytic degradation of Methylene Blue dye under visible light illumination

Advanced oxidation technologies are a friendly environmental approach for the remediation of industrial wastewaters. Here, one pot synthesis of mesoporous WO_3 and WO_3-graphene oxide(GO) nanocomposites has been performed through the sol–gel method. Then, platinum(Pt) nanoparticles were deposited onto the WO_3 and WO_3-GO nanocomposite through photochemical reduction to produce mesoporous Pt/WO_3 and Pt/WO_3-GO nanocomposites. X-ray diffraction(XRD) findings exhibit a formation of monoclinic and triclinic WO_3 phases. Transmission Electron Microscope(TEM) images of Pt/WO_3-GO nanocomposites exhibited that WO_3 nanoparticles are obviously agglomerated and the particle sizes of Pt and WO_3 are ~ 10 nm and 20–50 nm, respectively. The mesoporous Pt/WO_3 and Pt/WO_3-GO nanocomposites were assessed for photocatalytic degradation of Methylene Blue(MB) as a probe molecule under visible light illumination.The findings showed that mesoporous Pt/WO_3, WO_3-GO and Pt/WO_3-GO nanocomposites exhibited much higher photocatalytic efficiencies than the pure WO_3. The photodegradation rates by mesoporous Pt/WO_3-GO nanocomposites are 3, 2 and 1.15 times greater than those by mesoporous WO_3, WO_3-GO, and Pt/WO_3, respectively. The key factors of the enhanced photocatalytic performance of Pt/WO_3-GO nanocomposites could be explained by the highly freedom electron transfer through the synergetic effect between WO_3 and GO sheets, in addition to the Pt nanoparticles that act as active sites for O2 reduction, which suppresses the electron hole pair recombination in the Pt/WO_3-GO nanocomposites.     

Long-term effects of sliver nanoparticles on the abundance and activity of soil microbiome

正Silver nanoparticles(Ag NPs)are among the most extensively used engineered nanomaterials because of their wellestablished antimicrobial and unique physicochemical properties(Yin et al.,2015).Applications of AgNPs have now been     

Seasonal variation and size distribution of biogenic secondary organic aerosols at urban and continental background sites of China

Size-resolved biogenic secondary organic aerosols(BSOA) derived from isoprene and monoterpene photooxidation in Qinghai Lake, Tibetan Plateau(a continental background site) and five cities of China were measured using gas chromatography/mass spectrometry(GC/MS). Concentrations of the determined BSOA are higher in the cities than in the background and are also higher in summer than in winter. Moreover, strong positive correlations(R2= 0.44–0.90) between BSOA and sulfate were found at the six sites,suggesting that anthropogenic pollution(i.e., sulfate) could enhance SOA formation,because sulfate provides a surface favorable for acid-catalyzed formation of BSOA. Size distribution measurements showed that most of the determined SOA tracers are enriched in the fine mode( 3.3 μm) except for cis-pinic and cis-pinonic acids, both presented a comparable mass in the fine and coarse( 3.3 μm) modes, respectively. Mass ratio of oxidation products derived from isoprene to those from monoterpene in the five urban regions during summer are much less than those in Qinghai Lake region. In addition, in the five urban regions relative abundances of monoterpene oxidation products to SOA are much higher than those of isoprene. Such phenomena suggest that BSOA derived from monoterpenes are more abundant than those from isoprene in Chinese urban areas.     

复合型道路抑尘剂在城市道路中的应用及经济分析研究

采用由多种可降解高分子材料组成的新型复合型道路抑尘剂喷洒酒泉市肃州区道路,研究喷洒前后城市道路扬尘中PM_(10)、PM_(2.5)和氮氧化物的变化及抑尘剂所带来的经济效益。结果表明,PM_(10)平均去除率为20%,喷洒后能迅速捕捉并吸附微粒粉尘,加速粉尘颗粒凝聚,最好去除效果高达40%;对PM_(2.5)和氮氧化物的去除效果约15%,没有PM_(10)显著;相对于传统洒水方式,喷洒道路抑尘剂可以节省30%经济用水,且对人体和环境无毒害。     

基层卫生医疗机构财务管理战略对环境污染的影响分析研究

基层卫生医疗机构财务的优化管理能降低环境污染,定量分析基层卫生医疗机构财务管理战略对环境污染的影响,优化基层医疗机构的财务管理水平,从而抑制环境污染,提出基于关联规则统计分析模型的基层卫生医疗机构财务管理模型。结合定量回归分析方法进行环境污染的影响因素分析,采用解释变量的相关性分析方法进行统计平均检验,构建检测统计量和判决统计量进行环境污染影响及医疗卫生结构财务管理的关联规则分析评估,提高基层医疗结构财务管理的智能化水平。     

大型电力企业污染治理型营销策略研究

大型电力企业是国家发展电力需要重要扶持的企业。在大型电力企业电源结构中,火力发电占据重要地位,消耗煤炭的同时,会产生固体污染和废气污染,影响生态环境。为此,在提高大型电力企业完成电能输出的同时,需实现对环境的保护,提出对大型电力企业污染治理型营销策略进行研究。通过分析大型电力企业发展的生态环境、经济环境和行业发展环境,总结大型电力企业营销外部环境现状。考虑火力发电在电源结构中的地位以及对环境造成的污染,提出设计火力发电以外的电源结构,实现大型发电企业污染治理型营销策略提出与研究。     

市场化主导下生态产业园区柔性规划实践研究

借助生态产业园区的地理资源和新兴科技资源,进行生态园区和工业园区的柔性组合设计,平衡工业发展与生态保护之间的价值关系,以环境生态保护为基础,以市场行为为主导,结合旅游资源和产业的整合,促进区域经济和生态环境协调发展,通过生态产业园区带动地方城镇化建设,促进生态产业园区的环境、经济、社会效益统筹发展,提高资源利用率和土地利用率,大力倡导生态保护,建立生态环境与工业发展的平衡机制,提升生态产业园区的环境效益和市场经济效益。     

基于PVAR模型的产业集聚与环境污染关系研究

通过建立面板向量自回归(PVAR)模型,实证研究发现:产业集聚对环境的影响具有门槛效应,但其对环境污染排放变化的贡献率较低,产业集聚并非环境污染的主因;长期内,环境污染冲击对产业集聚的解释力要大于产业集聚对环境污染的解释力;产业集聚对工业固体废物的产生和工业废水排放的影响持续时期较短,而对工业废气排放则具有持久影响。     

石化特种设备管理现状及风险控制对策

为加强特种设备管理,提高风险控制水平,对中国特种设备的管理法规标准体系、中国石化特种设备管理现状及存在的问题,进行了讨论和思考,并提出了石化特种设备风险控制对策。     

介质膜干涉滤光片标准物质研究

研制介质膜干涉滤光片标准物质,包含3片不同标称值波长的滤光片,厚度为(2~3)mm,根据光谱中性金属膜的材质不同其峰值波长称值大约450 nm、550 nm、670 nm,用以检测光谱光度计波长示值误差和重复性。滤光片采用分光光度计方法进行定值,溯源至自然基准低压石英汞灯。根据(JJF 1343-2012)《标准物质定值的通用原则及统计学原理》和(JJG 812-93)《干涉滤光片检定规程》通过对滤光片进行均匀性检验、稳定性考核和介质膜干涉滤光片波长测量的不确定度评定,完成介质膜干涉滤光片标准物质的研究工作。