Simultaneous determination of estrogenic odorant alkylphenols,chlorophenols, and their derivatives in water using online headspace solid phase microextraction coupled with gas chromatography-mass spectrometry

A simple online headspace solid-phase microextraction (HS-SPME) coupled with the gas chromatography-mass spectrometry (GC-MS) method was developed for simultaneous determination of trace amounts of nine estrogenic odorant alkylphenols and chlorophenols and their derivatives in water samples. The extraction conditions of HS-SPME were optimized including fiber selection, extraction temperature, extraction time, and salt concentration. Results showed that divinylbenzene/Carboxen/polydimethylsiloxane (DVB/CAR/PDMS) fiber was the most appropriate one among the three selected commercial fibers, and the optimal extraction temperature, time, and salt concentration were 70 °C, 30 min, and 0.25 g/mL, respectively. The developed method was validated and showed good linearity (R ²?>?0.989), low limit of detection (LOD, 0.002–0.5 μg/L), and excellent recoveries (76–126 %) with low relative standard deviation (RSD, 0.7–12.9 %). The developed method was finally applied to two surface water samples and some of these target compounds were detected. All these detected compounds were below their odor thresholds, except for 2,4,6-TCAS and 2,4,6-TBAS wherein their concentrations were near their odor thresholds. However, in the two surface water samples, these detected compounds contributed to a certain amount of estrogenicity, which seemed to suggest that more attention should be paid to the issue of estrogenicity rather than to the odor problem.     

Profile of Methane Concentrations in Soil and Atmosphere in Alpine Steppe Ecosystem on Tibetan Plateau

The methane concentration profile from -1.5m depth in soil to 32m height in air was measured in alpine steppe located in the permafrost area. Methane concentrations showed widely variations both in air and in soil during the study period. The mean concentrations in atmosphere were all higher than those in soil, and the highest methane concentration was found in air at the height of 16m with the lowest concentration occurring at the depth of 1.5m in soil. The variations of atmospheric methane concentrations did not show any clear pattern both temporally and spatially, although they exhibited a more steadystable state than those in soil. During the seasonal variations, the methane concentrations at different depths in soil were significantly correlated （R^2〉0.6） with each other comparing to the weak correlations （R^2〈0.2） between the atmospheric concentra- tions at different heights. Mean methane concentrations in soil significantly decreased with depth. This was the compositive influence of the decreasing production rates and the increasing methane oxidation rates, which was caused by the descent soil moisture with depth. Although the methane concentrations at all depths varied widely during the growing season, they showed very distinct temporal variations in the non-growing season. It was indicated from the literatures that methane oxidation rates were positively correlated with soil temperature. The higher methane concentrations in soil during the winter were determined by the lower methane oxidation rates with decreasing soil temperatures, whereas methane production rates had no reaction to the lower temperature. Relations between methane contribution and other environmental factors were not discussed in this paper for lacking of data, which impulse us to carry out further and more detailed studies in this unique area.     

A Review of Environmental Sociology and the Sociology of Natural Resources： Insights for the Development of Environmental Sociology in China

Environmental sociology and the sociology of natural resources are two key subdisciplines of the sociological study on the interactions between nature and human society. Previous discussion on the relationships of these two fields has largely focused on their distinctions and synthesis in western （particularly American） academia. Environmental sociology emerged as an important sociological subdiscipline in China in the early 1990s and is under vigorous disciplinary construction at present. By contrast, the sociology of natural resources is still a novel term for most Chinese researchers. This article provides a systematic review of recent literature on the relationships between environmental and natural resource sociologies, which should provide important implications for the further development of environmental sociology in China.     

浸提分离法提取皂素清洁工艺研究

提出一种通过溶剂提取将游离皂苷与淀粉、纤维等成分分离,从源头上减少用水量、耗酸量和污染物排放量的皂素清洁生产工艺。首先对溶剂提取条件进行优化,得出最佳工艺条件为：90%（体积比）乙醇溶液,料液比1∶7,沸腾回流提取3 h,重复提取3次。然后通过气质联用（GC/MS）分析了皂素废水的有机物组成。研究结果表明,清洁工艺皂素产率为1.51%（降低3.82%）,用酸量比传统工艺减少了71%,头道液COD浓度降低了46%,每100 g原料排放的COD总量下降了84%;皂素废水的有机物污染物主要为糠醛及其衍生物,清洁工艺废水的有机物含量更低,更易降解。     

基于生态安全的DAT-IAT城市污水处理工艺改进研究

通过正交试验,得到了DAT-IAT工艺和A/DAT-IAT工艺处理城市污水的常规指标去除和生态毒理指标削减的最优运行条件。结果表明,在正交试验的同一工艺中,COD去除最优运行条件的出水COD值优于生态毒性削减最优运行条件的出水COD值,但前者出水的生态毒性较大。由于厌氧池的水解酸化作用,A/DAT-IAT工艺对COD和生态毒性的处理效果均优于DAT-IAT工艺,并且回流总能耗低于DAT-IAT工艺,但是出水COD仍不达标。为了降低进入工艺的COD的总量,以絮凝沉淀做为预处理工艺,并采用Al残留量最小的絮凝剂投药量以降低出水中残留Al带来的生态风险。结果表明,在COD去除最优运行条件下,具有絮凝预处理的工艺对COD的去除效果优于没有絮凝预处理的工艺。絮凝-A/DAT-IAT工艺在COD去除最优运行条件下出水COD为104.46 mg/L,满足排放标准。在毒性削减最优运行条件下,具有絮凝预处理的工艺的出水生态毒性有所上升,但是污染物的总量得到了大幅削减。絮凝-A/DAT-IAT工艺与DAT-IAT工艺相比,在污染物去除效率得到大幅增加的同时,生态毒性得到有效控制,生态安全得到了有效的保障。     

六自由度气锤振动技术与电磁斜面振动技术比较

六自由度气锤振动与电磁斜面振动是两种模拟产品三轴振动的振动技术。由于两种振动技术的机理不同,其对样品的振动影响也会有区别。本文研究讨论两种不同振动技术的不同特点,以及对不同产品的振动效果别,我们可以根据样品特点和测试需求,选择更合适的震动技术。     

累托石对水中染料碱性桃红的吸附

采用累托石作为水中碱性桃红的吸附剂.考察了振荡时间、pH值、累托石用量、碱性桃红初始浓度等因素对吸附效果的影响.测定了吸附等温线,对吸附动力学规律进行了数学模拟.结果表明,振荡时间、累托石用量、碱性桃红初始浓度等因素对吸附效果有重要影响.对于初始质量浓度为50 mg/L的碱性桃红水溶液,最适宜吸附条件为:振荡时间30 min,累托石用量200 mg/100 mL,pH值为6.累托石对水中碱性桃红的吸附等温线呈"S"型,等温吸附规律可用Freundlich模式较好地描述,吸附动力学规律可用Bangham公式模拟.     

企业安全管理中的潜流文化现象与应对方略

简介潜流安全文化的内涵,阐述潜流安全文化的隐蔽性、离散性、传承性和不稳定性的特点,剖析潜流安全文化形成的根源,提出应对潜流安全文化的扬长避短、因势利导、强化沟通、扩大参与、落实承诺和深化激励的方略。通过对企业安全管理中的潜流文化现象与应对方略的分析,得出以下结论:企业潜流安全文化是客观存在的,同时企业管理者是可以对企业潜流安全文化进行有效管理的;认识和管理企业安全管理中的潜流文化现象,可以有力推动企业安全文化建设工作的顺利开展。     

过氯乙烯滤膜采样-酸消解-钼蓝光度法测定磷酸雾

建立了过氯乙烯滤膜采样 -酸消解 -钼蓝分光光度法测定磷化车间磷酸雾的监测方法。实验室模拟采样的捕集效率为 95 7%～ 99 1 %。单个实验室对含 5μg和 1 5μg样品进行多次测定 ,其相对标准差小于 5% ,样品加标回收率为 98 2 %～ 1 0 0 5% ,方法检测限为 0 0 0 7mg/m3。对标样测定 ,结果均在给定值范围内。用该法与等离子发射光谱法(ICP)对 5个样品进行比对测定 ,结果均令人满意。     

中国21世纪城市供水新概念--分质供水

结合我国城市一直使用的统一给水方式已与当前水资源紧缺,用水多样化,人们饮用水质质化的状况极不适应的情况,提出对传统的给水方式进行改革的最适宜方式是分质供水。