Modification of CeO2-ZrO2 catalyst by potassium for NOx-assisted soot oxidation

Potassium-modified ceria-zirconia catalyst was synthesized by wetness impregnation method.The ageing treatment was performed in static air at 800°C for 20 hr to evaluate the thermal stability of the catalyst.The catalysts were characterized by X-ray diffraction,BET surface area,oxygen storage capacity,NOx-temperature programmed desorption and soot-temperature programmed oxidation measurements.By introduction of potassium,the maximum soot oxidation rate temperature(Tm) of the ceria-zirconia based catalyst de...     

吉林西部退化草原土壤盐渍化特征分析

对吉林西部退化草原六种常见植被类型下的土壤(0～20 cm)盐渍化特征进行了分析。采用国际上通用的土壤饱和浸提液电导率(ECe)、碱化度(ESP)和pH分别表征土壤的盐度、钠质化和酸碱程度。土壤盐度分为轻度、中度、重度和极度四个等级,对应的变化范围分别为:2～4、4～8、8～16、>16 dS m-1;土壤钠质化程度分为轻度、中度、重度和极度四个等级,对应的ESP范围分别为:5～10%、10～20%、20～40%、>40%;土壤酸碱性分为酸性、中性和碱性三种,对应pH范围分别为<6.5,6.5～8.5、>8.5。结果表明,植被类型对土壤盐度具有很好的指示作用,按土壤盐度由高到低排列,植被类型的顺序依次为:无植被(碱斑)、碱蓬(Suaeda glauca)、碱茅(Puccinellia tenuiflora)、虎尾草(Chloris virgata)、芦苇(Phragmites australis)、羊草(Leymus chinensis)。碱斑地、碱蓬地、碱茅地和虎尾草地的盐渍土类型均为盐化钠质土(ECe>2 dS m-1,ESP>5%),其中碱斑地和碱蓬地土壤盐化程度为极度(26.54≤ECe≤176.80 dS/m)、钠质化程度为极度(50.22≤ESP≤94.54%);碱茅和虎尾草植被下土壤盐度分别为10.70≤ECe≤27.62 dS m-1和6.86≤ECe≤13.88 dS m-1,钠质化程度分别为30.97≤ESP≤60.26%和16.21≤ESP≤58.11%;芦苇地的盐化程度为1.56≤ECe≤3.37 dS/m,钠质化程度为轻度(7.82≤ESP≤15.88%);羊草地的土壤盐度和钠质化程度分别2.43≤ECe≤6.66 dS m-1和1.43≤ESP≤8.34%。就土壤pH而言,羊草地为中性(7.44≤pH≤8.23),芦苇地为中性和/或碱性(8.18≤pH≤10.02),虎尾草地、碱茅地、碱蓬地和碱斑地均为碱性(8.83≤pH≤10.63)。     

颜料,油墨废水物化,生化法综合治理技术

本文详细阐述了颜料油墨废水的物化,生化法综合治理技术在其在工程 的实际应用,针对该行业废水的特点,该技术可以有效去除水中的悬浮物,有机物,色度及有毒有害物质使出水达标排放。该工程于１９９８年正式投产运行,成为国内首例成功运转达标的颜料,油墨废水治理工程。     

地壳内部流体与金成矿关系的研究现状与进展

大量的证据显示 ,在金的成矿作用过程中 ,地壳内部流体扮演着十分重要的角色。流体不仅可以通过与含金原岩的相互作用实现对金的萃取 ,同时还参与成矿物质运移以及金的最终沉淀并富集成矿这一整个成矿作用过程。因此 ,加强对流体与成矿的相互关系研究已成为研究金成矿学的重要内容。     

基于API方法的城市大气污染评价

收集了2006年《重点城市空气质量日报》中中国86个重点城市空气质量主要分析指标——空气污染指数（API）、首要污染物、空气质量级别,并对数据进行统计分析。结果表明：（1）总体来说,中国城市大气质量良好;（2）城市大气污染以煤烟型污染为主,大气中以TSP、SO2和NOx作为首要污染物出现的频率依次递减;（3）城市大气污染最严重的季节是冬季,最轻的季节是夏季;（4）城市大气环境质量表现出从北到南、从沿海至内陆逐步变差的趋势。     

Chemical deactivation of V2O5-WO3/TiO2 SCR catalyst by combined effect of potassium and chloride

V₂O₅-WO₃/TiO₂ catalyst was poisoned by impregnation with NH₄Cl, KOH and KCl solution, respectively. The catalysts were characterized by X-ray diffraction (XRD), inductively coupled plasma (ICP), N₂ physisorption, Raman, UV-vis, NH₃ adsorption, temperature-programmed reduction of hydrogen (H₂-TPR), temperature-programmed oxidation of ammonia (NH₃-TPO) and selective catalytic reduction of NO _x with ammonia (NH₃-SCR). The deactivation effects of poisoning agents follow the sequence of KCl>KOH?NH₄Cl. The addition of ammonia chloride enlarges the pore size of the titania support, and promotes the formation of highly dispersed V = O vanadyl which improves the oxidation of ammonia and the high-temperature SCR activity. K⁺ ions are suggested to interact with vanadium and tungsten species chemically, resulting in a poor redox property of catalyst. More importantly, potassium can reduce the Brønsted acidity of catalysts and decrease the stability of Brønsted acid sites significantly. The more severe deactivation of the KCl-treated catalyst can be mainly ascribed to the higher amount of potassium resided on catalyst.     

降解菌djl-6多菌灵水解酶的提取及性质

以往对多菌灵降解菌Rhodococcus qingshengii sp.nov.djl-6的降解途径研究显示,该菌株首先通过多菌灵水解酶将多菌灵水解成二氨基苯并咪唑,从而对多菌灵进行脱毒.为开发酶制剂并有效应用于环境中残留污染物多菌灵的降解,比较了不同提取方法(高压细胞破碎、超声波破碎和添加溶菌酶破碎)对多菌灵水解酶提取效率的影响,并对其酶学特性进行了初步研究.结果表明,djl-6菌株在LB培养基中培养72~84 h,生长量和产酶量均达到最大值.采用超声波破碎提取酶的效率较高(蛋白浓度为7.92 mg/mL),但酶活损失较大(比酶活只有1.2 U/μg protein).多菌灵水解酶属于一种胞内组成型酶.该酶水解多菌灵的最适pH值为7.0,最适温度为30℃,Zn2+和K+对酶活有一定的抑制作用.     

丹江口水库早春真核浮游植物群落结构特征及其与环境因子的关系

采用高通量测序技术研究了2019年早春（2月）丹江口水库浮游植物群落结构特征及其与环境因子的关系.结果显示：①本次调查共检测到浮游植物6门57属,主要包括绿藻门、硅藻门、金藻门、甲藻门、隐藻门等,其中,绿藻种类（47种）>硅藻（24种）>金藻（17种）,硅藻相对丰度（58.8%）>绿藻（27.2%）>金藻（11.8%）,各采样点浮游植物群落结构总体相似;②浮游植物优势种为硅藻门的冠盘藻（Stephanodiscus suzukii）、变异直链藻（Melosira varians）,绿藻门的葡萄藻（Botryococcus braunii）、索囊藻（Choricystis sp.）,以及金藻类的近囊胞藻一种（Paraphysomonas sp.）;③Shannon-Wiener多样性指数为1.76~2.52,Pielou均匀度为0.28~0.38,依据多样性指数水质评判标准判断水质整体处于β-中污带;水质符合Ⅱ类标准,但总氮（TN）除外,浓度为0.93~1.21 mg·L^-1;④相关性分析表明,香农-威纳指数（H''）与Pielou均匀度指数（J）、Simpson多样性指数显著相关（p<0.01）;冗余分析表明,pH、NH₄⁺-N和NO₂^--N是影响丹江口水库早春季节浮游植物群落结构最主要的环境因子.总体而言,丹江口水库水质较好,但早春季节冠盘藻（Stephanodiscus suzukii）的大量繁殖使丹江口水库发生水华的风险增加,因此,要加强对丹江口水库水质的检测和防范意识.     

Effect of water vapor on NH3-NO/NO2 SCR performance of fresh and aged MnOx-NbOx-CeO2 catalysts

A MnOx–NbOx–CeO2 catalyst for low temperature selective catalytic reduction(SCR) of NOx with NH3 was prepared by a sol–gel method, and characterized by NH3–NO/NO2 SCR catalytic activity, NO/NH3 oxidation activity, NOx/NH3 TPD, XRD, BET, H2-TPR and in-situ Diffuse Reflectance Infrared Fourier Transform Spectroscopy(DRIFTS). The results indicate that the Mn Ox–Nb Ox–CeO2 catalyst shows excellent low temperature NH3-SCR activity in the temperature range of 150–300℃. Water vapor inhibits the low temperature activity of the catalyst in standard SCR due to the inhibition of NOx adsorption. As the NO2 content increases in the feed, water vapor does not affect the activity in NO2 SCR. Meanwhile, water vapor significantly enhances the N2 selectivity of the fresh and the aged catalysts due to its inhibition of the decomposition of NH4NO3 into N2O.     

Evidence for contact sex recognition pheromone of the Asian longhorned beetle,<Emphasis Type="Italic"> Anoplophora glabripennis</Emphasis> (Coleoptera: Cerambycidae)

Field observations of the Asian longhorned beetle (Anoplophora glabripennis) mating behavior in China suggested that a female-produced contact pheromone was almost certainly involved in sex recognition. Gas chromatography–mass spectrometry (GC-MS) analysis of A. glabripennis adults' whole body cuticular extracts indicates that a series of long-chain hydrocarbons comprise the cuticular waxes of both sexes. Although for the most part the GC profiles are similar for the two sexes, five monounsaturated compounds were consistently more abundant in samples from females than in those from males. These compounds were identified as (Z)-9-tricosene, (Z)-9-pentacosene, (Z)-7-pentacosene, (Z)-9-heptacosene, and (Z)-7-heptacosene in the approximate ratio of 1:2:2:8:1, respectively. Antennal and palpi contact to a polypropylene micro-centrifuge tube coated with a synthetic mixture of the five compounds stimulated copulatory behavior in males.Electronic Supplementary Material  Supplementary material is available for this article if you access the article at . A link in the frame on the left on that page takes you directly to the supplementary material.