蒸汽抑制熄灭酒精池火有效性的模拟实验研究

蒸汽灭火系统在酒类作业场所有着广阔的应用前景.通过全淹没和局部保护实验对蒸汽抑制熄灭酒精池火的有效性进行了研究.实验结果表明,全淹方式难以有效控火,但是布局合理的局部保护方式能够有效熄灭酒精池火.蒸汽灭火过程中稀释O2浓度的灭火机理起到的作用较小,蒸汽的火焰拉伸效果是其主导灭火机理.     

Experimental study on flue gas purifying of MSW incineration using in-pipe jet adsorption techniques

This paper presents the experimental research process and results about flue gas purifying of municipal solid wastes (MSW) incineration using in-pipe jet adsorption techniques. MSW incineration was carried out in a fluidized bed test rig, and the flue gas purifying was carried out in an in-pipe jet adsorption test rig. The experimental results are as follows: when the feedstock of activated carbon is 1.6g/Nm(3), the desulfurization efficiency is 83%, the denitrification efficiency is 41%, and the dechlorination efficiency is 27%. The order of purifying effect of the three kinds of adsorbents on acidic gases from MSW incineration is activated carbon>activated bauxite>kaolin. Comparison of adsorption capabilities of the three kinds of adsorbents to heavy metals shows that activated carbon is the best additive to remove Cd, Pb and Cu, kaolin is inferior, and activated bauxite is the worst one. However, activated bauxite is the best additive to remove Hg, and it can remove Cd effectively. PAHs in fly ash are dominated by three-, four-, and five-ringed PAHs, and PAHs in the flue gas mainly include three- and four-ringed PAHs. When the injected quantity of additive is constant, the order of cleaning effect on PAHs is kaolin>activated carbon>activated bauxite. These three kinds of adsorbents have different purifying effects on acidic gases, heavy metals and PAHs in the flue gas from MSW incineration. In general, activated carbon has a better adsorption capability.     

Sorbents for CO2 capture from high carbon fly ashes

Fly ashes with high-unburned-carbon content, referred to as fly ash carbons, are an increasing problem for the utility industry, since they cannot be marketed as a cement extender and, therefore, have to be disposed. Previous work has explored the potential development of amine-enriched fly ash carbons for CO(2) capture. However, their performance was lower than that of commercially available sorbents, probably because the samples investigated were not activated prior to impregnation and, therefore, had a very low surface area. Accordingly, the work described here focuses on the development of activated fly ash derived sorbents for CO(2) capture. The samples were steam activated at 850 degrees C, resulting in a significant increase of the surface area (1075m(2)/g). The activated samples were impregnated with different amine compounds, and the resultant samples were tested for CO(2) capture at different temperatures. The CO(2) adsorption of the parent and activated samples is typical of a physical adsorption process. The impregnation process results in a decrease of the surface areas, indicating a blocking of the porosity. The highest adsorption capacity at 30 and 70 degrees C for the amine impregnated activated carbons was probably due to a combination of physical adsorption inherent from the parent sample and chemical adsorption of the loaded amine groups. The CO(2) adsorption capacities for the activated amine impregnated samples are higher than those previously published for fly ash carbons without activation (68.6 vs. 45mg CO(2)/g sorbent).     

上海市地震局图书馆数据库的管理软件

用SQLServer 7.0分布式数据库管理系统管理图书数据 ,并利用ASP(AcrtiveServerPages)网页设计技术、及IIS4 0信息服务建立局域网内部Intranet网 ,通过浏览器的形式管理和使用数据图书数据。     

海安地电台极区金属管道干扰的测试和分析

1999年 6月 5～ 8日海安地震台地电N6 0°E测向为ρs 值异常升幅 2 % ,而N30°W、N70°W两测向 ρs 值均处于正常年变化形态。经勘查、测试分析 ,确定为新埋设的地下自来水金属管道干扰所致。     

新疆油田气井压井液研究与回收利用

针对新疆克拉美丽气田火山岩气藏固相堵塞、滤液侵入等潜在伤害因素,研制了GCP无固相气井压井液体系。该体系具有无毒、无刺激性、可生物降解、能有效抑制粘土膨胀、低滤失、不与储层中钙、镁等二价离子反应形成无机沉淀以及低腐蚀等特点,可有效保护储层和油、套管。通过循环替液将气井钻井、完井作业使用的泥浆中固相成分和岩屑带出井筒,用过的压井液经过固相清除处理可实现回收再利用,在减少对储层环境污染的同时,降低了压井液使用成本,为在新疆油田公司大规模应用奠定了良好的基础。     

整装沙漠油田废水零排放的研究探索

文章介绍了陆梁油田通过对采出水处理工艺进行优化,并将其应用于油田水处理厂罐内喷淋除气技术等工艺;污水回收工艺作业废液处理采用二段式自然除油沉降原理进行预处理;利用反应吸附技术进行废液二次处理,生活污水一元化处理等工艺,对油田废水进行处理回注。年节约费用671.8万元,实现废水零排放,达到了环境保护和经济效益双赢的目的,为沙漠油田污水处理提供借鉴。     

各类VOCs在蜂窝陶瓷型La0.8Sr0.2MnO3催化剂上的催化燃烧性能

以涂有CeO2-ZrO2固溶体的堇青石蜂窝状陶瓷为载体,用浸渍法制备堇青石蜂窝陶瓷型整体La0.8Sr0.2MnO3催化剂,测试了该催化剂催化燃烧各类VOCs的特性。研究表明,VOCs催化燃烧的难易程度为：含氯烃〉烷烃〉酸〉芳烃〉酮〉酯〉醇〉醛。La0.8Sr0.2MnO3催化剂对含氧有机化合物具有较好的催化活性,完全燃烧温度均在280℃之内。通过关联VOCs的理化性质,发现VOCs在La0.8Sr0.2MnO3催化剂上的反应活性与VOCs分子中最弱C—H键键能和VOCs分子极性密切联系。     

Temporal,spatial characteristics and uncertainty of biogenic VOC emissions in the Pearl River Delta region,China

Using the Global Biosphere Emissions and Interactions System model (GloBEIS), 3 × 3 km gridded and hourly biogenic volatile organic compound (BVOC) emissions in the Pearl River Delta (PRD) were estimated for the year 2006. The study used newly available land cover database, observed meteorological data, and recent measurements of emission rates for tree species in China. The results show that the total BVOC emission in the PRD region in 2006 was 296 kt (2.2 × 10¹¹ gC), of which isoprene contributes about 25% (73 kt, 6.4 × 10¹⁰ gC), monoterpenes about 34% (102 kt, 8.9 × 10¹⁰ gC), and other VOCs (OVOC) about 41% (121 kt, 6.8 × 10¹⁰ gC). BVOC emissions in the PRD region exhibit a marked seasonal pattern with the peak emission in July and the lowest emission in January, and are mainly distributed over the outlying areas of the PRD region, where the economy and land use are less developed. The uncertainties in BVOC emission estimates were quantified using Monte Carlo simulation; the results indicate high uncertainties in isoprene emission estimates, with a relative error of ?82 to +177%, ranging from 12.4 to 186.4 kt; ?41 to +58% uncertainty for monoterpenes emissions, ranging from 67.7 to 181.9 kt; and ?26 to +30% uncertainty in OVOC emissions, ranging from 88.8 to 156.2 kt on the 95% confidence intervals. The key uncertainty sources include emission factors and the model empirical coefficients α, C_T1, C_L, and E_opt for estimating isoprene emission, and emission factors and foliar density for estimating monoterpenes and OVOC emissions. This implies that determining these empirical coefficient values properly and conducting more field measurements of emission rates of tree species are key approaches for reducing uncertainties in BVOC emission estimates. Improving future BVOC emission inventory work in the PRD region requires giving priority to research on shrub land, coniferous forests, and irrigated cropland and pasture.     

常州市大气PM_(2.5)中水溶性离子组成及来源

于2013年3月~2014年4月采集常州市郊区、工业区、居民区和背景点的春季、秋季大气PM_(2.5)样品,用离子色谱法分析其中水溶性离子成分,对其组成、分布特征及来源等进行研究。结果表明:SO_4~(2–)、NO_3~–和NH_4~+是常州市PM_(2.5)中的主要水溶性离子,3种离子在PM_(2.5)中占比为18%~33%。不同功能区之间水溶性离子的占比和差异较小,常州背景点可能受到周边城市污染输送的影响。在PM_(2.5)中,NH_4~+与SO_4~(2–)和NO_3~–主要以(NH_4)_2SO_4和NH_NO_3存在;硫转化率(SOR)和氮转化率(NOR)是衡量二次无机粒子转化的有效手段,常州市各功能区的SOR均大于NOR;春季SOR0.25,NOR0.1,满足发生强烈光化学氧化反应的条件。