Improved source assessment of Si, Al and related mineral components to PM10 based on a daily sampling procedure

Samples obtained from an industrialized valley in the East Alpine region were collected daily for a half year and analyzed using X-ray fluorescence to examine the elements Si,Al,Fe,Ca,Mg,Na,K,Zn,P,S and Cl.Some factors affecting the changes of these elements were considered,including time,elemental correlations,weekday,weekend and seasonal changes.Diagnostic analysis provided an insight into a decoupling behavior that occursin siliceous and carbonates minerals.A decrease in Si and Al and an increase in carbonates,Na,K,Zn and P were observed during the cold season.However,a consistently high correlation of Si and Al was observed in all seasons.It was established that such high levels originated from street surface abrasion.The increase in variability and absolute levels of carbonates during the cold season was demonstrated by adding carbonates to the street surface as gritting material to increase the grip on snowy surfaces.A marked increase in Na and Cl was observed in winter which may have been caused by thaw salt that is widely used in winter in Austria.This was associated with a significant increase in K,Zn,and P in the cold season that was the result of domestic space heating with wood.PM10 levels in December were 12 μg/m3 and were higher than levels detected in July.It was established that such high levels originated from mineral oxides,wood smoke,and inorganic ionic material(s).     

Preparation of rare-earth metal complex oxide catalysts for catalytic wet air oxidation

Catalytic wet air oxidation (CWAO) is one of the most promising technologies for pollution abatement. Developing catalysts with high activity and stability is crucial for the application of the CWAO process. The Mn/Ce complex oxide catalysts for CWAO of high concentration phenol-containing wastewater were prepared by coprecipitation. The catalyst preparation conditions were optimized by using an orthogonal layout method and single-factor experimental analysis. The Mn/Ce serial catalysts were characterized by Brunauer-Emmett-Teller (BET) analysis and the metal cation leaching was measured by inductively coupled plasma torch-atomic emission spectrometry (ICP-AES). The results show that the catalysts have high catalytic activities even at a low temperature (80°C) and low oxygen partial pressure (0.5 MPa) in a batch reactor. The metallic ion leaching is comparatively low (Mn<6.577 mg/L and Ce<0.6910 mg/L, respectively) in the CWAO process. The phenol, COD_Cr, and TOC removal efficiencies in the solution exceed 98.5% using the optimal catalyst (named CSP). The new catalyst would have a promising application in CWAO treatment of high concentration organic wastewater. Translated from Techniques and Equipment for Environmental Pollution Control, 2005, 6(2): 40–44 [译自: 环境污染治理技术与设备]     

环境空气自动监测车仪器路况试验分析

利用环境空气自动监测车对辖区内空气自动站进行巡检及应急监测中,越来越显示其灵活、可移动的优势,但在长距离行驶后是否因路况影响仪器的正常运行,对监测车仪器能否达到监测质量控制对仪器性能指标的要求,成为最为关心的问题,作者在各级路况开展了系统试验。通过试验得出,路况对监测车仪器影响不大,性能指标可以满足要求。     

地表UV-B辐射增强对土壤-冬小麦系统呼吸速率和N2O排放的影响

通过室外盆栽实验,用静态箱-气相色谱法测定土壤-冬小麦系统的呼吸速率和N₂O排放通量,研究了UV-B辐射增强20%对土壤-冬小麦系统的呼吸速率和N₂O排放的影响.结果表明,相同的气象条件和田间管理下,UV-B辐射增强处理对呼吸速率和N₂O排放的季节变化模式无明显影响.在返青期,UV-B辐射增强显著降低了土壤-冬小麦系统的呼吸速率,但对N₂O的排放通量没有产生显著影响;在拔节孕穗期,UV-B辐射增强处理显著降低了土壤-冬小麦系统的呼吸速率和N₂O的排放通量;在抽穗-成熟期,UV-B辐射增强处理对土壤-冬小麦系统的呼吸速率和N₂O的排放没有显著影响.返青-齐穗期,UV-B增强处理显著降低土壤-冬小麦系统的N₂O累积排放量;但从齐穗开始至小麦成熟,UV-B增强处理对土壤-冬小麦系统的N₂O累积排放量没有显著影响.     

北京市PM5.0可吸入颗粒物反演及其时空分布分析

分析城市可吸入颗粒物的空间特征及影响因素对于制定更为有效的可吸入颗粒物污染控制政策具有重要的现实意义.本研究在实际采样和遥感数据处理基础上,构造差值植被指数(DVI),通过建立TM影像与对应PM5.0颗粒物实测值之间的相关关系模型,对北京市2008~2010年3 a的PM5.0的分布进行了反演计算和精度分析;研究了NDBI和NDMI对PM5.0浓度的影响,进一步揭示了北京五环区域范围内可吸入颗粒物的时空分布特征.结果表明,采用DVI反演PM5.0分布的方法可行,反演精度在可接受范围内;整体上研究区2008年PM5.0颗粒物污染最轻,西南三环和四环以及东南三四环之间为颗粒物污染的高值区,西北五环附近颗粒物污染较轻;NDBI(归一化建筑指数)、NDMI(归一化水汽指数)与PM5.0可吸入颗粒物的分布分别呈现显著的负相关和正相关关系,且二者对PM5.0的影响相近.     

填埋场中铁的生物化学循环对反硝化的影响

在模拟填埋体系中,以填埋场稳定的垃圾为接种物,通过控制有机物和硝氮负荷,研究了铁的生物化学循环对反硝化的影响.结果表明,垃圾填埋场内蕴藏着能实现铁的厌氧氧化还原并同步还原硝氮的复合功能菌群.通过改变有机物和硝氮的负荷,可使得填埋场内持续进行着铁的氧化还原循环和同步氮素转化.从氮素转化产物来看,铁的循环体系中氨氮浓度比传统的反硝化体系低4 mmol·L-1.填埋场内铁的生物化学循环过程对于原位脱氮具有极大贡献.     

机场植被管理与鸟击灾害防范的研究

鸟击灾害是航空“A”类灾难,机场鸟击灾害的根源在于机场生境对鸟类的吸引,减少机场生境中吸引鸟类的生态因子是解决机场鸟击威胁的根本方法。本文通过对南充高坪机场植被和鸟类进行调查,统计分析两者之间的关系,以寻找最适宜的机场植被管理措施。结果显示：植被为鸟类提供食物和栖息场所,植食性鸟类数量与植被的种类和季节变动规律基本吻合,同时植物的繁茂滋生大量昆虫,使肉食性鸟类数量增多。对飞行区植被进行处理,设法控制机场内鸟类的食物来源,对于减少飞行区鸟类的数量非常重要。建议采取的措施有碾压、割草和农药喷洒、挖除高草丛、使用除草剂、草坪植物种类的调控。     

基于BN的FTA在通用航空风险评价中的应用

针对事故树分析法(FTA)在风险评价中的局限性,采用以事故树为基础建立的贝叶斯网络(BN)风险模型,对通用航空中的两机空中相撞事故进行分析和推理,对事故模型进行改进和修正时,注重基事件的多态性和事件间的逻辑合理性。根据贝叶斯推理得出的数据,找到了事故的主要致因。结果表明,基于BN的FTA既能向前预测顶事件的发生概率,又能向后诊断基本事件的后验概率,可以更好地对通用航空风险进行评价。     

消防服用织物热防护性能测试分析与研究

热防护性能(Thermal protective performance—TPP)是阻燃型服装或织物隔热防护性能重要指标。本文在已研制的一种模拟人体皮肤及体形的高温"圆筒仪"上进行了改进,并用其测试阻燃服装织物的热防护性能。用膜电偶测量模拟皮肤器表面温升率,并结合烧伤积分模型的评价方法来计算达到二级烧伤的防热时间。与其它一维平面测试装置相比,本装置可较为准确评估实际服装热收缩特征对服装热防护性能的影响。     

江苏宿迁地震台短水准测量场地改造的探讨

地震前兆数据观测中,经常会遇到各种干扰,有的干扰可以很快排除,但有的是无法排除的.目前我们的短水准受到铺路影响就属于后一种情形,它直接影响到我们测量场地的生存.为了让观测数据得以延续,我们努力寻找解决问题的办法,最后采用把观测点平移再对比观测的方法来解决问题.