阳极溶出伏安法、石墨炉原子吸收法测定海水中总铬的方法比较研究

铬是海洋水体中的痕量重金属之一,海水的高盐基体对铬的测定有严重的干扰,而且海水中同时存在Cr(Ⅲ)和Cr(Ⅵ),两种不同价态给测定也带来了一定难度。文章从Cr(Ⅲ)的氧化率、方法检出限、精密度、实际样品加标等方面对过氧化氢氧化-阳极溶出伏安法与传统的MIBK萃取-无火焰原子吸收分光光度法进行了比较研究,发现两种方法在测试结果上无显著差异,但是过氧化氢氧化-阳极溶出伏安法具有更高的精密度,更低的检出限,且对Cr(Ⅲ)的回收率略有提升。     

A view from the countryside

Guest Editorial

A view from the countryside     

A study on the interactions among several plant secondary compounds and aphids

The research, focused on the specific interactions among seven plant secondary compounds and aphids, was carried out and the preliminary results showed: (1) "T-typed tube method" was regarded as the best method compared with others designed to observe the interactions. (2) Cabbage aphid was able to be attracted by laurolene while it was not susceptible to α-pinene, β-pinene and diamylene. (3) Gossypol, a major secondary substance in cotton, was able to be implicated as feeding attractant to cotton aphid. (4) Rutin might be implicated repellent to cotton aphid.     

污染物在地下水毛细饱水带的运移规律浅释

分析了毛细饱水带的水动力学特性，指出在地下水污染研究中，污染物在毛细饱和水带和潜水怪具有相同的水平运动规律，并以实例分析说明该带对污染物运移的重要性。建议在研究和一非饱和条件地下水及污染物运动问题时把毛细饱水带与潜水含水层统一为饱马毛细饱水带顶面作为饱水面。     

青铜峡铝厂氟污染对广武乡玉米影响的调查分析

监测了青铜峡铝厂东南方向４．５ｋｍ的广武乡玉米叶，得知含氟量为４３．９４－１６６．１ｍｇ／ｋｇ，对照样品树新林场玉米叶的含氟均值为１３．１５ｍｇ／ｋｇ，广武乡的玉米受到了严重的氟污染，农作物减产严重。     

River water quality and pollution sources in the Pearl River Delta, China

Some physicochemical parameters were determined for thirty field water samples collected from different water channels in the Pearl River Delta Economic Zone river system. The analytical results were compared with the environmental quality standards for surface water. Using the SPSS software, statistical analyses were performed to determine the main pollutants of the river water. The main purpose of the present research is to investigate the river water quality and to determine the main pollutants and pollution sources. Furthermore, the research provides some approaches for protecting and improving river water quality. The results indicate that the predominant pollutants are ammonium, phosphorus, and organic compounds. The wastewater discharged from households in urban and rural areas, industrial facilities, and non-point sources from agricultural areas are the main sources of pollution in river water in the Pearl River Delta Economic Zone.     

连续采样与五日法采样效果及费用的对比分析

通过对连续采样与五日法采样五种方法监测结果及所需费用的比较，得出连续采样方法监测结果更具有代表性，合理性，一次性投资大，但运行费用并不高的结论。     

Faculty position announcement

Faculty position announcement     

The organic composition of diesel particulate matter, diesel fuel and engine oil of a non-road diesel generator

Diesel-powered equipment is known to emit significant quantities of fine particulate matter to the atmosphere. Numerous organic compounds can be adsorbed onto the surfaces of these inhalable particles, among which polycyclic aromatic hydrocarbons (PAHs) are considered potential occupational carcinogens. Guidelines have been established by various agencies regarding diesel emissions and various control technologies are under development. The purpose of this study is to identify, quantify and compare the organic compounds in diesel particulate matter (DPM) with the diesel fuel and engine oil used in a non-road diesel generator. Approximately 90 organic compounds were quantified (with molecular weight ranging from 120 to 350), which include alkanes, PAHs, alkylated PAHs, alkylbenzenes and alkanoic acids. The low sulfur diesel fuel contains 61% alkanes and 7.1% of PAHs. The identifiable portion of the engine oil contains mainly the alkanoic and benzoic acids. The composition of DPM suggests that they may be originated from unburned diesel fuel, engine oil evaporation and combustion generated products. Compared with diesel fuel, DPM contains fewer fractions of alkanes and more PAH compounds, with the shift toward higher molecular weight ones. The enrichment of compounds with higher molecular weight in DPM may be combustion related (pyrogenic).     

Response of the Ascorbate-Peroxidase of Selenastrum capricornutum to Copper and Lead in Stormwaters

The green alga Selenastrum capricornutum expresses a uniqueascorbate peroxidase, that responds to copper and lead. Attemptswere made to test if this peroxidase could be used to monitor thelevels of copper and lead in natural waters. When S.capricornutum was exposed to a stormwater sample, the specificactivity of the peroxidase in the cell extract was commensuratewith the combined copper and lead contents in the sample. Theperoxidase responses were also correlated with the 96 hr biomasstoxicity assay of S. capricornutum. However, unlike thebiomass toxicity assay, the peroxidase activity was not affectedby the anions in the samples. The use of this peroxidase can beused as a marker for testing heavy metal toxicity in the water.