膨润土的羟基铝改性及对染料工业废水的处理研究

通过对膨润土的羟基铝改性实验大大提高了膨润土对染料废水的处理效率。实验结果表明:改性膨润土对变色酸有很好的去除效果,对H酸有较好的去除效果,对T酸处理效果一般,对吐氏酸几乎没有效果。     

关于中国土地资源人口承载力问题的思考

土地资源的人口承载力问题也就是生存空间问题,它关系到人类未来的生存与发展问题,历来受学术界的注目。20世纪70年代联合国粮农组织(FAO)曾主持了一项大型的发展中地区土地资源人口承载力问题的研究,80年代后期,中国科学院—国家计委自然资源综合考察委员会也主持了一项大型的中国土地资源生产能力及人口承载量研究。相应地还有一系列有关中国未来的生存与发展和人口承载力问题的探讨。本文从中国人地关系变化的角度介入这一讨论,分析中国远期的土地资源是否超载的问题。     

环境资源的量化模型及估算指标体系

本文依据区划环境标准，提出了环境资源的成本概念－环境成本。     

近断层强震速度脉冲效应及连续梁桥减隔震特性分析

应用非线性时程分析的方法 ,对于减、隔震连续桥梁在近场地震作用下的有效性和响应特性 ,作了深入的研究。通过有代表性的脉冲型近场强震记录时程分析 ,提出了用速度脉冲峰值及其周期之积来表示速度脉冲能量的方法 ,计算表明近场地震速度脉冲波能近似表征地震动破坏能力的大小 ,它和桥梁结构承受的地震响应大体成正比例关系。铅芯橡胶隔震支座在近场地震作用下仍然适用 ,但对于个别脉冲型强震记录效果不够明显 ,支座参数有必要进行优化。     

Towards zero discharge of chromium-containing leather waste through improved alkali hydrolysis

The treatment of chromium-containing leather waste (CCLW), the major solid waste generated at the post-tanning operations of leather processing, has the potential to generate value-added leather chemicals. Various alkali and enzymatic hydrolysis were compared, and calcium oxide was found to be important for effective (but still incomplete) hydrolysis. Three possible reasons are given for the incomplete hydrolysis under alkaline conditions. Data for 19 amino acids are presented for four different treatment products. On the basis of the results, a novel three-step CCLW treatment process is proposed. The gelatin extracted in the first step is chemically modified to produce leather finishing agents. The collagen hydrolysates isolated in the second step are used as proteinic retanning agents by chemical modification. The remaining chrome cake is further hydrolyzed with acids in the third step, and the obtained chromium-containing protein hydrolysates could be used for the preparation of chromium-containing retanning agents for leather industry. The proposed three-step process provides a feasible zero discharge process for the treatment of CCLW.     

Mineralogical compositions of aquifer matrix as necessary initial conditions in reactive contaminant transport models

Mineralogical compositions and their spatial distributions are important initial conditions for reactive transport modeling. However, popular Kd-based "reactive" transport models only require contaminant concentrations in the pore fluids as initial conditions, and minerals implicitly represent infinite sources and sinks in these models. That situation results in a general neglect of mineralogical characterization in site investigations. This study uses a coupled multi-component reactive mass transport model to predict the natural attenuation of a ground water plume at a uranium mill tailings site in western USA. Numerous ground water geochemistry data are available at this site, but mineralogical data are sketchy. Even given the well-defined pore fluid chemistry, variations of secondary mineral species and mineral abundances in the aquifer resulted in significantly different modeling outcomes. Results show that the amount of calcite in the aquifer determines the distances of plume migration. The possible presence of jurbanite, an aluminum sulfate phase, can store acidity temporarily but cause more severe contamination on a later date. The surfaces of iron oxyhydroxides can store significant amounts of sulfate and protons and serve as a second source for prolonged contamination. These simulations under field conditions illustrate that mineralogical compositions are an essential requirement for accurate prediction of contaminant fate and transport.     

Influence of temperature and time on phosphorus removal in swine manure during batch aeration

This study was conducted to investigate the effects of temperature and time on the mechanisms of phosphorus removal in swine manure during aeration. Removal of soluble orthophosphates significantly increased with aeration time and temperature. Successive significant ortho-P removals were observed between days one and nine but no significant additional removals were recorded thereafter. Removals were significantly higher at temperatures of 20 and 25 degrees C than at temperatures of 5, 10, and 15 degrees C and ranged between 22.9 to 31.0%. Insoluble inorganic phosphorus also changed significantly with aeration time and temperature and with a similar trend as soluble orthophosphates. The pH of the manure explained 92 and 87% of the content of insoluble inorganic phosphorus at lower temperatures (5, 10, 15 degrees C) and at higher temperatures (20, and 25 degrees C), respectively. Organic phosphorus and aerobes growth patterns were similar to that of soluble orthophosphates removal. The rapid growth of aerobes was most probably the principal factor behind a rapid soluble ortho-P removal above 15 degrees C. The contribution of inorganic phosphates to the removal of soluble orthophosphates was approximately 61% while that due to organic P was approximately 35%. Precipitation was found to be the principal mechanism governing removal of soluble ortho-P in swine manure during aeration treatments.     

基于优势隐含周期分析的气象灾害预报

建立了优势因子和优势隐含周期的概念,并提出了多因子逐步回归周期分析的新方法。该方法既能增长预报期,又能充分利用物理因子的重要信息,同时在计算过程中还能挑选出起显著作用的优势因子和优势隐含周期,对预报气象要素的变化趋势效果较好,有一定的实用价值,是气象灾害预报的一条比较有效的途径。     

首都大学生的自然灾害认知调查与减灾教育建议

2006年国际减灾日的主题是"减灾始于学校",了解学生的灾害认知水平有助于减灾教育工作的有效开展。以北京5所高校的大学生为调查对象,通过问卷方式调查大学生对自然灾害的关注程度、防灾意识、灾害理论知识、应急行为知识以及对减灾教育的看法。问卷统计结果表明:大学生总体的灾害认知水平较低,现行减灾教育方式和内容与学生的期望有较大偏差。在此基础上,提出了减灾教育内容要将学生"该知道的"与"想知道的"相结合,通过演练演习等方式提高学生的防灾应急实际技能等减灾教育建议。     

Occurrence of perfluorosulfonates and other perfluorochemicals in dust from selected homes in the city of Ottawa, Canada

A series of perfluorinated compounds (PFCs) including perfluorooctane sulfonate (PFOS) and perfluorooctanoic acid (PFOA) have been recently measured in a variety of environmental samples and biological matrices. In order to better understand the human exposure routes of these chemicals, levels of PFOS, PFOA, perfluorobutane sulfonate (PFBS), perfluorohexane sulfonate (PFHS) and perfluorooctane sulfonamide (PFOSA) in house dust samples were investigated. The data revealed a correlation between the concentrations of PFCs and the percentage of carpeting in the house; older houses tended to have less carpeting, hence lower levels of these perfluorinated compounds in their dust.