Synthesis and characterization of chitosan-supported Fe2O3 nanohybrids for rapid sonophotocatalytic degradation of 2,4,6-trichlorophenol

Environmental Science and Pollution Research - The present study reports the design of heterogeneous photocatalytic system using Fe2O3 with chitosan (CS) as a matrix for the sonophotocatalytic...     

Ag@MnxOy: an effective catalyst for photo-degradation of rhodamine B dye

Environmental Chemistry Letters - Water pollution by the textile industry is a major issue. Therefore, there is a need for methods to remove organic dyes from industrial effluents. Various...     

Urban noise assessment and its nonauditory health effects on the residents of Chiniot and Jhang,Punjab, Pakistan

Environmental Science and Pollution Research - Elevated noise level is an emerging global problem. Therefore, the present work is conducted that can improve, increase, and integrate the already...     

From Environmental Ethics to Nature Conservation Policy: Natura 2000 and the Burden of Proof

Natura 2000 is a network of natural sites whose aim is to preserve species and habitats of relevance in the European Union. The policy underlying Natura 2000 has faced widespread opposition from land users and received extensive support from environmentalists. This paper addresses the ethical framework for Natura 2000 and the probable moral assumptions of its main stakeholders. Arguments for and against Natura 2000 were analyzed and classified according to “strong” or “weak” versions of the three main theories of environmental ethics – anthropocentrism, biocentrism, and ecocentrism. Weak (intergenerational) anthropocentrism was found to underlie the Natura 2000 network itself and the positions of environmentalists, while strong (traditional) anthropocentrism pervaded the positions of economic developers. Land users seemed to fall somewhere between weak and strong anthropocentrism. The paper discusses the relation between ethics and different attitudes towards Natura 2000, highlighting some of the implications for the network’s ongoing implementation. It is shown that Natura 2000 achieves a strong reversal of the burden of proof from conservation to economic development and land use change under anthropocentrism. It is argued that the alleged theoretical divide between anthropocentrism and non-anthropocentrism in relation to the burden of proof does not seem to hold in practice. Finally, it is predicted that the weak versions of anthropocentrism, biocentrism, and ecocentrism, are likely to converge extensively in respect to nature conservation policy measures.“Charting the depths of law and policy disputes yield an understanding of ethical differences.” Paul B. Thompson (2002, p. 189).     

Tumor necrosis factor-alpha,prostaglandin-E2 and interleukin-1β targeted anti-arthritic potential of fluvoxamine: drug repurposing

Environmental Science and Pollution Research - Fluvoxamine, a selective serotonin re uptake inhibitor, is used to treat depression. The aim of present study was to evaluate fluvoxamine in acute...     

Optimization of COVID-19 face mask waste fibers and silica fume as a balanced mechanical ameliorator of fat clay using response surface methodology

Environmental Science and Pollution Research - The balanced amelioration of mechanical characteristics of fat clay with an additive refers to the attainment of high strength without compromising...     

Ligand-less in situ surfactant-based solid phase extraction for preconcentration of silver from natural water samples prior to its determination by atomic absorption spectroscopy

A simple and rapid ligand-less in situ surfactant-based solid phase extraction method for preconcentration of silver from water samples is developed. In this method, a cationic surfactant containing a proper alkyl group (n-dodecyltrimethylammonium bromide) is dissolved in the aqueous sample and then a proper ion-pairing agent (ClO₄^?) is added. Due to the interaction between surfactant and ion-pairing agent, solid particles are formed and used for adsorption of silver carbonate. After centrifugation, the sediment is dissolved in 2.0 mL 1 M HNO₃ in ethanol and then aspirated directly into the flame atomic absorption spectrometer. Variables affecting the extraction efficiencies such as pH, concentrations of surfactant and CO₃^2?, ion pair concentration, and extraction time, are optimized. Under such conditions, the calibration curve is linear from 3 to 700 μg L^?1. Detection limit is 1.1 μg L^?1 with an enrichment factor of 37. The relative standard deviation for eight replicate measurements of 100 μg L^?1 is 2.1%. The method has been applied for the determination of silver in water samples.     

Magnetic particles precipitated onto wheat husk for removal of methyl blue from aqueous solution

Magnetic particles prepared via co-precipitation and impregnated onto wheat husk (MN-WH) were used for the removal of methyl blue (MB) from aqueous solution. Experiments were conducted in a batch mode for optimization regarding pH, contact time, adsorbent dose, initial dye concentrations, and temperature. Maximum adsorption (98%) was achieved at pH 5. The adsorption data were fitted into pseudo-first, pseudo-second, intraparticle diffusion, and Elovich equation revealing that adsorption followed pseudo-second-order kinetics. The four most common isotherm models, i.e. the Langmuir, Freundlich, Tempkin, and Dubinin–Radushkevich (D–R), were used to evaluate the data, with the best fit to a Langmuir isotherm (R² = 0.996), followed by a Freundlich isotherm (R² = 0.995), indicating monolayer adsorption of MB on the surface of MN-WH. Thermodynamic parameters calculated from the Van't Hoff equation revealed that the adsorption is exothermic (ΔHº = ?19.7 kJ mol^?1).     

Coastal scenic assessment: unlocking the potential for coastal tourism in rural Pakistan via Mediterranean developed techniques

Originally developed within the Mediterranean, a tested coastal management and planning tool was applied outside the region to evaluate its international scope, with particular reference to a less developed country. Seven coastal sites in Pakistan were investigated for their scenic values through a 26 item checklist grouped as physical and human parameters analysed though weighted parameters and fuzzy logic matrices. With respect to a five-class evaluation system, results indicated: Jiwani, Miani Hor and Pasni-Astola Island as extremely attractive natural sites with very high landscape value (classified as Class 1 sites); Mubarak village as an attractive natural site with high landscape value (classified as a Class 2 site); Kaka pir village, Harjana village and Keti Bandar as having little outstanding landscape features or with urban environment and classified as Class 3 sites. Rural and/or urban environmental influences were observed to be critical factors which influenced major human parameters that ultimately affect sites’ scenic classification. However, notwithstanding natural attraction, unless political and social development barriers are tackled in conjunction with recognising areas that possess inherent tourism potential, economic potential is unlikely to be realised.