Controlled readability of Seveso II company safety documents,the design of a new KPI

Companies often use a substantial quantity of safety-related documents such as the front gate safety flyer, emergency evacuation instructions, work permits, safety procedures, work instructions and policy statements. In many cases the personnel magazines and message board notes also contain safety information. The authors and readers may not be in the same department, premises or cultural group. Both authors and readers are diverse groups when it comes to reading, writing and language skills. Previous research has found that Seveso II companies produce documents that are difficult for their workforce and visitors to understand. Authors do not write systematically to match the reader’s skill level. This may be due in part to the quality and effectiveness of layout guidance, expert linguistic advice and document appraisal systems. These do not in general provide the immediate support needed. Layout suggestions are of limited effectiveness, and availability and usability limits the value of expert advice and appraisal systems. So, without useful feedback, many authors cannot write sufficiently readable documents; to overcome this threshold, they need a quick document readability assessment tool. With such a tool, readability can become a controlled property of safety documents. Large companies may use hundreds or thousands of documents containing safety information. This paper presents a practical approach for the transition to, and monitoring of, controlled readability for all documents related to safety. A new Key Performance Indicator design on readability is proposed.     

Risk measures constituting a risk metrics which enables improved decision making: Value-at-Risk

In this work, a novel approach is proposed for expressing the risks of process plants consisting of a large number of scenarios, in the form of a risk metrics of leading indicators to prevent potential high profile industry accidents. The methodology includes: 1) risk estimation of a portfolio by CPQRA (or QRA), 2) monetization of the tangible risks with the inclusion of the lost time of production, 3) estimation of the maximum portfolio loss using Value-at-Risk approach, 4) inclusion of intangible risks using FN-curve and, 5) generation of F$-curve of tangible risks. The proposed methodology can particularly help in understanding the stakes at risk by performing the overall cost-benefit analysis, for identifying the most risky scenarios and identifying critical equipments to enable better risk-informed decision making in order to adopt appropriate risk mitigation measures. This work establishes the groundwork for developing measures for understanding and comparing the large number of risk values derived from QRA studies for large portfolios. It will aid in less subjective decision making as it enables the decision maker to choose the most preferred portfolio option among alternatives. Decisions made with the accurate understanding of the consequences of risks can significantly reduce potential work-related fatalities, property losses and save millions of dollars.     

Safer management of process changes in chemical reactors

Nowadays many chemical industries are SMEs where multi-purpose batch or semi-batch reactors are commonly used. Vent sizing for realistic runaway scenario is not an easy task for such enterprises since they have usually few resources and use multi-purpose reactors with fast process turnovers. As a consequence these batch and semi-batch reactors are usually equipped with emergency relief systems sized once forever when the reactor is designed. This can lead to a large underestimation of the vent area in case of runaway reactions occurring when processes different from the ones considered for originally sizing the vent are carried out.The approach proposed in this work aims to identify the maximum reactor load leading to safe conditions even in case of runaway phenomena to be handled with the emergency relief system already installed (or even with a smaller vent area). This approach allows avoiding the change of the emergency relief system with a larger vent area (as required every time a new more hazardous process has to be carried out on existing reactors) at the price of lower plant productivity.     

Improving construction site safety through leader-based verbal safety communication

Background

The construction industry is one of the most injury-prone industries, in which production is usually prioritized over safety in daily on-site communication. Workers have an informal and oral culture of risk, in which safety is rarely openly expressed. This paper tests the effect of increasing leader-based on-site verbal safety communication on the level of safety and safety climate at construction sites. Method: A pre-post intervention-control design with five construction work gangs is carried out. Foremen in two intervention groups are coached and given bi-weekly feedback about their daily verbal safety communications with their workers. Foremen-worker verbal safety exchanges (experience sampling method, n = 1,693 interviews), construction site safety level (correct vs. incorrect, n = 22,077 single observations), and safety climate (seven dimensions, n = 105 questionnaires) are measured over a period of up to 42 weeks. Results: Baseline measurements in the two intervention and three control groups reveal that foremen speak with their workers several times a day. Workers perceive safety as part of their verbal communication with their foremen in only 6-16% of exchanges, and the levels of safety at the sites range from 70-87% (correct observations). Measurements from baseline to follow-up in the two intervention groups reveal that safety communication between foremen and workers increases significantly in one of the groups (factor 7.1 increase), and a significant yet smaller increase is found when the two intervention groups are combined (factor 4.6). Significant increases in the level of safety are seen in both intervention groups (7% and 12% increases, respectively), particularly in regards to 'access ways' and 'railings and coverings' (39% and 84% increases, respectively). Increases in safety climate are seen in only one of the intervention groups with respect to their 'attention to safety.' No significant trend changes are seen in the three control groups on any of the three measures. Conclusions: Coaching construction site foremen to include safety in their daily verbal exchanges with workers has a significantly positive and lasting effect on the level of safety, which is a proximal estimate for work-related accidents. It is recommended that future studies include coaching and feedback at all organizational levels and for all involved parties in the construction process. Building client regulations could assign the task of coaching to the client appointed safety coordinators or a manager/supervisor, and studies should measure longitudinal effects of coaching by following foremen and their work gangs from site to site.     

Estimation of chemical concentration due to fugitive emissions during chemical process design

Fugitive emissions are not an environmental concern alone, but are also a health concern. From occupational health standpoint, fugitive emissions are the main sources of origin of the continuous exposure to workers. Operating plants regularly measure release and concentration levels through a plant-monitoring program. However, for processes which are still ‘on paper’, predictive estimation methods are required. Therefore, three methods for estimating concentration of the fugitive emissions are presented for the process development and design phases of petrochemical processes. The methods estimate the fugitive emission rates and plant plot dimensions resulting to fugitive emission concentrations. The methods were developed for the type and amount of information available in three process design stages; conceptual design, preliminary process design, and detailed process design. The methods are applied on a real benzene plant; the estimated benzene concentrations are compared to the actual concentration measured at the plant. The results show that as the information mounts up during design, the concentration estimate becomes more accurate. The results indicate that the methods presented provide simple estimates of fugitive emission-based concentrations during the design stages.     

Persistence and mobility of 2,4-D in unsaturated soil zone under winter wheat crop in sub-tropical region of India

The present study was undertaken to determine the persistence and mobility of 2,4-dichlorophenoxy acetic acid (2,4-D) in unsaturated soil zone under real field conditions for the wheat crop in Roorkee, India. Three experimental plots were chosen in the agricultural field itself to represent the real field conditions in the study area and the potential movement and persistence of herbicide 2,4-D was investigated under three different irrigation treatments. The presence of herbicide along with soil water content was determined in soil at different depths at a temporal scale. The movement of the herbicide was also simulated numerically by solving the coupled soil water content movement and mass transport equations using HYDRUS-1D. The measured soil water content trends and the 2,4-D concentration profiles showed a good agreement with the numerically simulated results. The maximum effect of the herbicide was primarily retained up to 15 cm of the soil profile. The current existing dosage of 0.5 kg ha⁻¹ of pesticide was found to be safe to avoid soil contamination as no residue of 2,4-D was traced at the end of the wheat crop season in any of the plots. Higher concentrations of 2,4-D were also simulated numerically and the simulated results showed that the safe dosage of pesticide application would depend on irrigation treatments.     

A GFP-based bacterial biosensor with chromosomally integrated sensing cassette for quantitative detection of Hg(II) in environment

A mercury biosensor was constructed by integrating biosensor genetic elements into E. coli JM109 chromosome in a single copy number, using the attP/attB recombination mechanism of λphage. The genetic elements used include a regulatory protein gene (merR) along with operator/promoter (O/P) derived from the mercury resistance operon from pDU1358 plasmid of Serratia marcescens. The expression of reporter gene gfp is also controlled by merR/O/P. Integration of the construct into the chromosome was done to increase the stability and precision of the biosensor. This biosensor could detect Hg(II) ions in the concentration range of 100-1700 nmol/L, and manifest the result as the expression of GFP. The GFP expression was significantly different (P ≤ 0.05) for each concentration of inducing Hg(II) ions in the detection range, which reduces the chances of misinterpretation of results. A model using regression method was also derived for the quantification of the concentration of Hg(II) in water samples.     

考虑pH值和挥发性脂肪酸影响的填埋城市固废厌氧降解模型

建立了描述填埋城市固体废弃物降解过程和行为的2阶段厌氧降解机理模型.模型考虑了含水率、挥发性脂肪酸(VFA)和pH值等主要环境因素的作用.为了适用于不同渗滤液酸化水平下的降解,单独考虑了pH值和分子态VFA对甲烷菌繁殖的影响.建立了气相高CO2分压下的渗滤液pH值计算方程,并给出了降解环境中CO2分压的计算方法.通过对一固废降解试验的模拟验证了模型的有效性.最后,采用所建立的pH值计算方程揭示了填埋环境下高CO2分压对渗滤液pH值影响显著,渗滤液pH值与VFA间缺乏不同酸化水平下的一致对应关系和高酸化水平下pH值对VFA浓度变化不敏感、分子态VFA抑制作用明显等规律.     

Investigation of physico-chemical properties and microbial community during poultry manure co-composting process

Co-composting of poultry manure and rubber wood sawdust was performed with the ratio of 2:1(V/V) for a period of 60 days. An investigation was carried out to study the extracellular enzymatic activities and structural degradation utilizing Fourier transform infrared spectroscopy(FT-IR), thermogravimetry and differential thermal analysis(TG/DTA)and scanning electron microscopy(SEM). The microbial succession was also determined by using denaturing gel gradient electrophoresis(DGGE). The compost was able to reach its highest temperature of 71°C at day 3 and stabilized between 30 and 40°C for 8 weeks.CMCase, FPase and β-glucosidase acted synergistically in order to degrade the cellulosic substrate. The xylanase activities increased gradually during the composting and reached the peak value of 11.637 U/g on day 35, followed by a sharp decline. Both Li P and Mn P activities reached their peak values on day 35 with 0.431 and 0.132 U/g respectively. The FT-IR spectra revealed an increase in aromaticity and a decrease in aliphatic compounds such as carbohydrates as decomposition proceeded. TGA/DTG data exhibited significant changes in weight loss in compost samples, indicating degradation of organic matter. SEM micrographs showed higher amounts of parenchyma exposed on the surface of rubber wood sawdust at day 60, showing significant degradation. DGGE and 16 S r DNA analyses showed that Burkholderia sp., Pandoraea sp., and Pseudomonas sp. were present throughout the composting process. Ornithinibacillus sp. and Castellaniella ginsengisoli were only found in the initial stage of the composting, while different strains of Burkholderia sp. also occurred in the later stage of composting.