Application of fuzzy sets and cognitive maps to incorporate social science scenarios in integrated assessment modelsA case study of urbanization in Ujung Pandang, Indonesia

Decision–support systems in the field of integrated water management could benefit considerably from social science knowledge, as many environmental changes are human-induced. Unfortunately the adequate incorporation of qualitative social science concepts in a quantitative modeling framework is not straightforward. The applicability of fuzzy set theory and fuzzy cognitive maps for the integration of qualitative scenarios in a decision–support system was examined for the urbanization of the coastal city of Ujung Pandang, Indonesia. The results indicate that both techniques are useful tools for the design of integrated models based on a combination of concepts from the natural and social sciences. This revised version was published online in July 2006 with corrections to the Cover Date.     

Collaborative study to improve the quality control of rare earth element determinations in environmental matrices

In order to control the quality of rare earth determinations in environmental matrices, the Standards, Measurements and Testing Programme (formerly Community Bureau of Reference, BCR) of the European Commission has started a project, the final aim of which is to certify four types of matrices (tuna muscle, mussel tissue, aquatic plant and estuarine sediment) for their contents of a range of rare earth elements (Sc, Y and the lanthanides: La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb and Lu). The elements U and Th were added to the study. The first part of this project consisted of an interlaboratory study which aimed to test the feasibility of preparation of environmental reference materials and to detect and remove most of the pitfalls observed in rare earth determinations. This paper presents the preparation of the four matrices for the intercomparison study and for the candidate reference material. The main results are presented of the interlaboratory study that was carried out prior to the certification campaign. This collaborative trial is the first attempt ever carried out at this scale to evaluate the state-of-the-art of rare earth determinations in the environment. Its impact on the improvement of chemical measurements will have positive effects on the comparability of data necessary for environmental monitoring.     

Performance of amine-multilayered solid sorbents for CO2 removal: Effect of fabrication variables

The emission of fossil fuel carbon dioxide (CO₂) to the atmosphere is implicated as the predominant cause of global climate change; therefore, advanced CO₂ capture technologies are of the utmost importance. In this study, innovative amine-multilayered sorbents were fabricated using layer-by-layer (LbL) nanoassembly technology via alternate deposition of a CO₂-adsorbing amine polymer (e.g. polyethylenimine or PEI) and an oppositely-charged polymer (e.g. polystyrene sulfonate or PSS). We found that the developed sorbents could be used for CO₂ capture and that LbL nanoassembly allows us to engineer their CO₂ capture performance through the fabrication variables (e.g. deposition polymers, deposition media, and number of bilayers). PEI/PSS was found to be the best polymer combination for developing sorbents with relatively high CO₂ capture capacity. The amine-multilayered solid sorbents possessed fine microstructures and may have similar polymer deposition within and on the surface of solid sorbents. These amine-multilayered sorbents had much faster CO₂ desorption rates compared to sorbents prepared using the current PEI-impregnation approach. Such fast CO₂ desorption could make sorbents a good option for CO₂ removal from power plants and even the atmosphere.     

A harvest failure approach to assess the threat from an invasive species

We present the idea of using potential infringements on annual allowable harvest targets as an approach to estimate threats from invasive species to the forest products sector. The approach uses present-day harvest levels as a reference level to estimate when and where the impact of a nonnative forest pest could become economically damaging. We use a generic model that simulates spread and damage by nonnative invasive species, basic harvest and forest growth through time. The concept is illustrated with a case study of a new nonnative invasive pest, Sirex noctilio Fabricius on pine resources in eastern Canada. Impacts of invasion on wood supply, in particular, the point at which present-day harvest levels are not attainable, were identified for 77 non-overlapping geographical regions that delimit the primary wood supply areas around large mills and wood processing facilities in eastern Canada. The results identify the minimum area of a pest outbreak that could trigger harvest shortages (approximately 12.5–14 M ha of pine forests in Ontario and Quebec). Beyond this level, the amount of host resource available for harvesting in any given year declines rapidly. The failure to sustain broad-scale harvest targets may be an attractive and intuitive indicator for policy makers and regulators interested in developing control and “slow-the-spread” programs for non-native forest pests.     

Putting the cart before the horse: Water governance and IWRM

Water governance has emerged as perhaps the most important topic of the international water community in the 21^st century, and achieving “good” water governance is now a focus of both policy discourse and innumerable development projects. Somewhat surprisingly in light of this attention, there is widespread confusion about the meaning of the term “water governance”. This paper reviews the history of the term's use and misuse to reveal how the concept is frequently inflated to include issues that go well beyond governance. Further, it highlights how calls to improve water governance often espouse predetermined goals that should instead be the very function of water governance to define. To help overcome this confusion, the paper suggests a more refined definition of water governance and related qualities of good water governance that are consistent with broader notions of the concepts. In light of the substantial resources allocated in its name, this paper's findings show there is significant potential to strengthen efforts at improving water governance.     

An unconventional method for the recovery of caustic soda from spent Al-rich pickling solutions

This work presents an unconventional procedure for the recovery of spent Al-rich caustic soda solutions from the pickling of dies for the production of aluminium extrusions. Caustic soda was regenerated at roughly 70%, by precipitating aluminate, after addition of a silica source, in the form of zeolite A, a microporous material that is widely used in many technological sectors. It was shown that the process is reliable and can be repeated for several cycles, provided the concentration of the caustic soda solution is suitably restored. The by-product obtained, zeolite A, proved to be a high-grade material with performance as a cation exchanger and physical sorbent that is certainly comparable to that reported in literature (e.g., cation exchange capacity equal to 5.14 meq g(-1) vs. 5.48 meq g(-1) and water vapour adsorption capacity of 26.5% vs. 27.6% at 16 torr and 298 K). The economics of the process, although not examined yet, would appear generally favourable, considering that zeolite A is a valuable by-product which widely covers the costs for the recovery of the spent solutions. There are, therefore, significant prospects for the use of zeolite A, particularly as a builder in detergent formulation.     

Ethnobotany and ecological perspectives on the management and use of plant species for a traditional fishing trap, southern coast of São Paulo, Brazil

The cerco-fixo is an artisanal fishing trap widely used by traditional communities in the estuarine region of the southern coast of the state of São Paulo, Brazil. The primary goal of the study was to investigate, through ethnobotanical and ecological approaches, the use of plant species by traditional fishermen to build the cerco-fixo at Cardoso Island State Park and Cananéia Island. Ethnobotanical data were collected through interviews, direct observation, plant collection and identification, and document analysis. An ecological evaluation was also done comparing five 20 × 20 m plots in a managed area to five 20 × 20m plots in an unmanaged area, both within arboreal sandy soil vegetation called restinga arbórea, found within the Brazilian Atlantic Forest domain. This study involved 34 fishermen living at Cardoso and Cananéia Islands. The fishermen know more than 90 Atlantic Forest plant species that can be used to build the cerco-fixo. Tree species from the family Myrtaceae were the most quoted in the interviews. With respect to the ecological evaluation, the cluster analyses showed greater heterogeneity in terms of floristic composition (i.e. greater floristic dissimilarity) within the plots of the managed area. The analyses of diversity showed a slightly higher species richness and slightly lower values for Shannon, Simpson, Hurlbert’s PIE and Evenness indices in the managed area (59 species; H′ = 3.28; 1/D = 10.77; E = 0.80; Hurlbert’s PIE = 0.91) compared to the unmanaged area (54 species; H′ = 3.39; 1/D = 20.21; E = 0.85; Hurlbert’s PIE = 0.95). The Hutcheson’s t test showed no significant difference between both areas’ Shannon diversity indices (t: −1.04; p: 0.30). These results are attributed to the greater dominance of the palm species Euterpe edulis Mart. in the managed area (28.2% of the trees sampled at this area; n = 118), which equals twice the percentage of individuals of the same species found for the unmanaged area (14.6% of the sampled trees; n = 48). We discuss the impact of the fishermen’s harvesting practices in the managed area with an emphasis on three main points: (1) the harvesting practices are likely not contributing to a decrease in diversity in the managed area; (2) the greater heterogeneity in terms of floristic composition found for the managed area may reflect a mosaic pattern created by the opening of small tree-gaps distributed across this area over the course of more than 50 years; (3) the disturbance promoted by the fishermen’s harvesting practices can be compared to natural disturbances of low impact that create mosaic patterns in tropical forests. This study emphasizes the prominence of the human dimension in ecological processes and the importance of considering the perspectives of local people when discussing the conservation of the natural environments in which these people live.     

Permanent shallow subsoil CO2 flux chambers for monitoring of onshore CO2 geological storage sites

Public concern over the possibility of migration of stored CO₂ to the surface with resulting damage to vegetation or hazard to humans and animals is a matter which will need to be addressed to be able to satisfy likely regulatory requirements for onshore CO₂ storage in a number of jurisdictions. While soil CO₂ concentration is readily measured continuously and in situ with current technology, the measurement of CO₂ flux at depths below the soil A horizon may be a more sensitive and meaningful technique for early detection of a near surface CO₂ plume. We describe a system for the continuous measurement of soil CO₂ flux at a depth of approximately 1.3 m and present results from three instruments deployed at the Otway Basin Pilot Project in Victoria, Australia and one development system deployed at Sutton, near the Australian Capital Canberra.     

Contamination of soil and the medicinal plant <Emphasis Type="Italic">Phyllanthus niruri</Emphasis> Linn. with cadmium in ceramic industrial areas

Phyllanthus niruri is a plant that is used to prevent calcium oxalate crystallisation and to block the stone formation in urolithiasis. Contaminants in the environment can be readily taken up by medicinal plants due to their ability to absorb chemicals into their tissues. If contaminated plants are ingested, they have the potential to negatively affect human and environmental health. The aim of this study was to assess contamination in the soil and the medicinal plant P. niruri by cadmium (Cd) in ceramic industrial areas of Monte Carmelo, Brazil. Soil samples and plant samples (divided in root, shoot and leaves) were collected from a contaminated monitoring site and from a rural area (which was used as a reference site for comparative purposes). The Cd concentrations of the samples were analysed with an atomic absorption spectrometer. P. niruri was found to be sensitive to soil contamination by Cd that was attributed to ceramic industrial emissions. The results revealed that Cd bioaccumulation in the roots and shoots of P. niruri was associated with a significant increase (p?<?0.05) in the concentration of active lignan compounds (phyllanthin and hypophyllanthin) in the leaves. The identification of high concentrations of Cd and active lignan compounds suggests a risk of contamination of the site and the risk of a high dose of Cd to people exposed at the site.