Use of Oxidation Onset Temperature Measurements for Evaluating the Oxidative Degradation of Isotatic Polypropylene

The widespread use of polymeric materials in many applications requires polymers that are weather resistant. The aim of this study is to examine the usefulness of oxidation onset temperature measurements as a tool for evaluating oxidative degradation of isotatic polypropylene. Differential scanning calorimetry was used to measure the oxidation onset temperature in formulations of isotatic polypropylene containing different concentrations of light and thermal stabilizers after aging in a Weather-Ometer. Oxidation onset temperature gave better results than oxidation induction time for evaluating the degradation of isotatic polypropylene during aging in a Weather-Ometer. However, both tests showed a poor correlation with the appearance of cracks seen by optical microscopy.     

MULTIVARIATE ANALYSIS OF WATER QUALITY AND PHYSICAL CHARACTERISTICS OF SELECTED WATERSHEDS IN PUERTO RICO1

ABSTRACT: Multivariate analyses were used to develop equations that could predict certain water quality (WQ) conditions for unmonitored watersheds in Puerto Rico based on their physical characteristics. Long term WQ data were used to represent the WQ of 15 watersheds in Puerto Rico. A factor analysis (FA) was performed to reduce the number of chemical constituents. Cluster analysis (CA) was used to group watersheds with similar WQ characteristics. Finally, a discriminant analysis (DA) was performed to relate the WQ clusters to different physical parameters and generate predicting equations. The FA identified six factors (77 percent of variation explained): nutrients, dissolved ions, sodium and chloride, silicacious geology, red ox conditions, and discharge. From the FA, specific conductance, sodium, phosphorous, silica, and dissolved oxygen were selected to represent the WQ characteristics in the CA. The CA determined five groups of watersheds (forested, urban polluted, mixed urban/rural, forested plutonic, and limestone) with similar WQ properties. From the five WQ clusters, two categories can be observed: forested and urban watersheds. The DA found that changes in forest cover, percent of limestone, mean annual rainfall, and watershed shape factor were the most important physical features affecting the WQ of watersheds in Puerto Rico.     

Importance of legislation for maintaining forests on private properties in the Brazilian Cerrado

Environment, Development and Sustainability - This paper evaluates compliance with environmental laws in the municipality of Sorriso and the impact of changing legislation on vegetation. To verify...     

Production of irrigation water from bioremediation of acid mine drainage: comparing the performance of two representative systems

The ability of two active bioremediation systems, based on the activity of sulphate-reducing bacteria, for the production of irrigation water from acid mine drainage (AMD), was compared. System I consisted of a packed bed reactor containing calcite tailing followed by an anaerobic packed bed bioreactor. System II consisted of a settler, fed with AMD and treated water recycle, and a sulphidogenic anaerobic packed bed bioreactor, fed with clarified settler effluent. Although efficient in terms of pH neutralisation and metals removal, system I did not allow continuous production of suitable irrigation water, since the concentration of sulphate in the effluent frequently exceeds the maximum recommended value by local legislation. On the other hand, in system II very high sulphate reduction (>99.0%) was achieved during the whole experiment, being the values in the effluent much lower than legislated limits for irrigation water. System II, not requiring the addition of any neutralising agent, can also be advantageous from an economical perspective.     

Artificial lakes as a climate change adaptation strategy in drylands: evaluating the trade-off on non-target ecosystem services

Drylands are very susceptible to the effects of climate change due to water stress. One possible climate change adaptation measure is the construction of lakes to increase water availability for drinking and irrigation (food production) and decrease fire risk. These lakes can also increase local biodiversity and human well-being. However, other non-target services such as carbon (C) storage, water purification, and sediment retention might also change. Our main aim was to evaluate the trade-offs on non-targeted ecosystem services due to lakes construction in drylands. This was done using the Integrated Valuation of Ecosystem Services and Tradeoffs (InVEST) modeling tools, comparing a Mediterranean area located in southwest (SW) Europe, with and without artificial lakes. Results showed that the construction of artificial lakes caused an increase of 9.4% in C storage. However, the consequent increase in agricultural area decreased water purification and sediment retention services. This could diminish the life span of the lakes changing the initial beneficial cost-benefit analysis on lakes as adaptation measures to climate change. As a global measure for mitigation and adaptation to climate change strategy, we consider lake construction in drylands to be positive since it can store C in sediments and reduces the vulnerability to water scarcity. However, as a general recommendation and when built to support or increase agriculture in semi-arid landscapes, we consider that lakes should be complemented with additional measures to reduce soil erosion and nutrient leaching such as (i) locate agricultural areas outside the lakes water basin, (ii) afforestation surrounding the lakes, and (iii) adopt the best local agriculture practices to prevent and control soil erosion and nutrient leaching.